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Investigation of Some Properties of 4-Amino-2-Methyl-Quinoline and CdS Nano Composite Thin Films for Production of Diodes

Year 2024, Volume: 24 Issue: 06, 1297 - 1304

Abstract

The aim of this study is to produce a diode, which is a basic electronic circuit element, and analyze its physical characterization. In this study, a diode was produced from CdS and C10H10N2 films, and its structural, optical, and electrical properties were investigated. First, a thin CdS film was deposited on an ITO substrate using the CBD method. Then, a C10H10N2 film was coated on this CdS film by the spin coating method. The CdS film has n-type semiconductor properties, whereas the C10H10N2 film has p-type semiconductor properties. XRD, SEM, AFM, UV-Vis spectroscopy, and IV measurements were performed on the produced films. According to the XRD result, a sharp peak at 27.07° was observed in the hexagonal phase of CdS. At this angle, a grain size of 33.3 nm was calculated according to the XRD result. Based on the SEM and AFM measurement results, it was determined that the film surface was uniform and dotted. According to the UV-Vis results, in addition to the d→d* transition, π→π* and n→π* transitions were also observed. From the I-V diagram, it was seen that the heterojunction structure of the CdS/C10H10N2 films had a diode property. The value of rectification factor was calculated as 2.91x102 from the I-V data. In addition, the ideality factor was calculated as 1.93 using the traditional method.

References

  • Assili, K., Selmi, W., Alouani, K., & Vilanova, X. (2019). Computational study and characteristics of In2S3 thin films: effects of substrate nature and deposition temperature. Semiconductor Science and Technology, 34(4). https://doi.org/10.1088/1361-6641/ab0446
  • Aybek A. Ş., R. H. (2018). Some Physical Properties of FTO/n-CdS/Au Structure. Chalcogenide Letters, 15, 583-590. Braun, D. E., Gelbrich, T., Kahlenberg, V., & Griesser, U. J. (2015). Solid state forms of 4-aminoquinaldine - From void structures with and without solvent inclusion to close packing. CrystEngComm, 17(12), 2504-2516. https://doi.org/10.1039/C5CE00118H
  • Cazaux, J. (2004). About the Mechanisms of Charging in EPMA, SEM, and ESEM with Their Time Evolution. Microscopy and Microanalysis, 10, 670-684. https://doi.org/10.1017/S1431927604040619
  • Demir, H. Ö., Meral, K., Aydoğan, Ş., Bozgeyik, M. S., & Bayır, E. (2015). Synthesis, characterization and diode application of poly(4-(1-(2-phenylhydrazono)ethyl)phenol). Journal of Materials Chemistry C, 3(22), 5803-5810. https://doi.org/10.1039/c5tc00857c
  • Demir, R. (2010). The study on some physical properties of CdS thin films obtained by chemical bath deposition method (Publication Number 269644) [Doctorate, Anadolu University, TURKEY]. Council of Higher Education Thesis Center. Demir, R., & Gode, F. (2015). Structural, optical and electrical properties of nanocrystalline CdS thin films grown by chemical bath deposition method. Chalcogenide Letters, 12, 43-50. Demir, R., & Göde, F. (2018). Preparation and Characterization of Polycrystalline CdS Thin Films Deposited by Chemical Bath Deposition. Materials Focus, 7(3), 351-355. https://doi.org/10.1166/mat.2018.1525
  • Demir, R., Okur, S., & Şeker, M. (2012). Electrical Characterization of CdS Nanoparticles for Humidity Sensing Applications. Industrial & Engineering Chemistry Research, 51(8), 3309-3313. https://doi.org/10.1021/ie201509a
  • Durmuş, H., & Karataş, Ş. (2019). The analysis of the electrical characteristics and interface state densities of Re/n-type Si Schottky barrier diodes at room temperature. International Journal of Electronics, 106, 507-520. https://doi.org/https://doi.org/10.1080/00207217.2018.1545145
  • Farag, A. A. M., Yahia, I. S., & Fadel, M. (2009). Electrical and photovoltaic characteristics of Al/n-CdS Schottky diode. International Journal of Hydrogen Energy, 34(11), 4906-4913. https://doi.org/10.1016/j.ijhydene.2009.03.034
  • Güllü, Ö., Aydoğan, Ş., & Türüt, A. (2008). Fabrication and electrical characteristics of Schottky diode based on organic material. Microelectronic Engineering, 85, 1647-1651. https://doi.org/10.1016/j.mee.2008.04.003 Kaleli, M., Parlak, M., & Erçelebi, Ç. (2011). Studies on device properties of an n-AgIn5Se8/p-Si heterojunction diode. Semiconductor Science and Technology, 26(105013), 1-7. https://doi.org/http://dx.doi.org/10.1088/0268-1242/26/10/105013
  • Karataş, Ş. (2010). Effect of series resistance on the electrical characteristics and interface state energy distributions of Sn/p-Si (MS) Schottky diodes Microelectronic Engineering, 87, 1935-1940. https://doi.org/10.1016/j.mee.2009.11.168
  • Karataş, Ş., Altındal, Ş., Türüt, A., & Çakar, M. (2007). Electrical transport characteristics of Sn/p-Si schottky contacts revealed from I–V–T and C–V–T measurements. Physica B, 392, 43-50. https://doi.org/doi:10.1016/j.physb.2006.10.039
  • Kaya, İ., Kolcu, F., Demiral, G., Ergül, H., & Kiliç, E. (2015). Synthesis and characterization of imine polymers of aromatic aldehydes with 4-amino-2-methylquinoline via oxidative polycondensation. Designed Monomers and Polymers, 18(1), 89-104. https://doi.org/10.1080/15685551.2014.971395
  • Nallathambi, P., Lal, S. K., Boopalakrishnan, G., Kumar, A., Umamaheswari, C., Gogoi, R., Yadav, S. K., Gupta, A., Meshram, N. M., & Ilangovan, R. (2018). Scanning Electron Microscopy and PCR based methods for detection of False Smut [Ustilaginoidea virens (Cooke) Takahashi] Chlamydospores associated with Rice (Oryza sativa) seeds. Vegetos, 31(1), 20-27. https://doi.org/http://dx.doi.org/10.5958/2229-4473.2018.00003.4
  • Olusola, O. I., Salim, H. I., & Dharmadasa, I. M. (2016). One-sided rectifying p–n junction diodes fabricated from n-CdS and p-ZnTe:Te semiconductors. Mater. Res. Express, 3(095904), 1-15. https://doi.org/10.1088/2053-1591/3/9/095904
  • Ramaiah Subba Kodigala, P. R. D., Hill A.E., Tomlinson R.D., Bhatnagar A.K. (2001). Structural and optical investigations on CdS thin films grown by chemical bath technique. Materials Chemistry and Physics, 68, 22-30. Reddy, T. S., & Kumar, M. C. S. (2016). Effect of substrate temperature on the physical properties of co-evaporated Sn2S3 thin films. Ceramics International, 42(10), 12262-12269. https://doi.org/10.1016/j.ceramint.2016.04.172
  • Rocha, F. S., Gomes, A. J., Lunardi, C. N., Kaliaguine, S., & Patience, G. S. (2018). Experimental Methods in Chemical Engineering: Ultraviolet Visible Spectroscopy—UV-Vis. The Canadian Journal of Chemical Engineering, 96, 2512-2517. https://doi.org/10.1002/cjce.23344
  • Yakuphanoglu, F. (2007). Electrical characterization and interface state density properties of the ITO/C-70/Au Schottky diode. Journal of Physical Chemistry C, 111(3), 1505-1507. https://doi.org/10.1021/jp066912q

Diyot Üretimi İçin 4-Amino-2-Metil-Kinolin ve CdS Nano Kompozit İnce Filmlerin Bazı Özelliklerinin İncelenmesi

Year 2024, Volume: 24 Issue: 06, 1297 - 1304

Abstract

Bu çalışmanın amacı elektronik temel devre elemanı olan bir diyot üretmek ve bununla ilgili olarak fiziksel karakterizasyonunu araştırmaktır. Yapılan bu çalışmada CdS ve C10H10N2 filmlerinden bir diyot üretilerek yapısal, optik ve elektriksel özellikleri incelendi. İlk olarak ITO alttaş üzerine CBD yöntemiyle CdS ince filmi üretildi. Daha sonra bu CdS filmin üzerine spin coating yöntemiyle C10H10N2 filmi kaplandı. CdS filmi n-tipi ve C10H10N2 filmi ise p-tipi yarı iletken özelliğine sahiptir. Üretilen filmlerin XRD, SEM, AFM, UV-Vis Spektroskopi ve IV ölçümleri alındı. XRD sonucuna göre CdS’in heksagonal fazda 27,07° de keskin bir pik gözlendi. Bu açıdan tanecik büyüklüğü XRD sonucuna göre 33,3 nm olarak hesaplandı. SEM ve AFM ölçüm sonuçlarına göre düzenli ve boşluklu bir film yüzeyinin olduğu gözlendi. UV-Vis sonucuna göre d→d* geçişinin yanısıra π→π* ve n→π* geçişleri de gözlendi. I-V grafiğinden CdS/C10H10N2 filmlerinin hetero junction yapısının diyot özelliğine sahip olduğu gözlendi. I-V verilerinden düzeltme faktörünün değeri 2.91x102 olarak hesaplandı ve ilgili grafiği çizildi. Ayrıca idealite faktörü geleneksel yöntemle 1,93 olarak hesaplandı.

References

  • Assili, K., Selmi, W., Alouani, K., & Vilanova, X. (2019). Computational study and characteristics of In2S3 thin films: effects of substrate nature and deposition temperature. Semiconductor Science and Technology, 34(4). https://doi.org/10.1088/1361-6641/ab0446
  • Aybek A. Ş., R. H. (2018). Some Physical Properties of FTO/n-CdS/Au Structure. Chalcogenide Letters, 15, 583-590. Braun, D. E., Gelbrich, T., Kahlenberg, V., & Griesser, U. J. (2015). Solid state forms of 4-aminoquinaldine - From void structures with and without solvent inclusion to close packing. CrystEngComm, 17(12), 2504-2516. https://doi.org/10.1039/C5CE00118H
  • Cazaux, J. (2004). About the Mechanisms of Charging in EPMA, SEM, and ESEM with Their Time Evolution. Microscopy and Microanalysis, 10, 670-684. https://doi.org/10.1017/S1431927604040619
  • Demir, H. Ö., Meral, K., Aydoğan, Ş., Bozgeyik, M. S., & Bayır, E. (2015). Synthesis, characterization and diode application of poly(4-(1-(2-phenylhydrazono)ethyl)phenol). Journal of Materials Chemistry C, 3(22), 5803-5810. https://doi.org/10.1039/c5tc00857c
  • Demir, R. (2010). The study on some physical properties of CdS thin films obtained by chemical bath deposition method (Publication Number 269644) [Doctorate, Anadolu University, TURKEY]. Council of Higher Education Thesis Center. Demir, R., & Gode, F. (2015). Structural, optical and electrical properties of nanocrystalline CdS thin films grown by chemical bath deposition method. Chalcogenide Letters, 12, 43-50. Demir, R., & Göde, F. (2018). Preparation and Characterization of Polycrystalline CdS Thin Films Deposited by Chemical Bath Deposition. Materials Focus, 7(3), 351-355. https://doi.org/10.1166/mat.2018.1525
  • Demir, R., Okur, S., & Şeker, M. (2012). Electrical Characterization of CdS Nanoparticles for Humidity Sensing Applications. Industrial & Engineering Chemistry Research, 51(8), 3309-3313. https://doi.org/10.1021/ie201509a
  • Durmuş, H., & Karataş, Ş. (2019). The analysis of the electrical characteristics and interface state densities of Re/n-type Si Schottky barrier diodes at room temperature. International Journal of Electronics, 106, 507-520. https://doi.org/https://doi.org/10.1080/00207217.2018.1545145
  • Farag, A. A. M., Yahia, I. S., & Fadel, M. (2009). Electrical and photovoltaic characteristics of Al/n-CdS Schottky diode. International Journal of Hydrogen Energy, 34(11), 4906-4913. https://doi.org/10.1016/j.ijhydene.2009.03.034
  • Güllü, Ö., Aydoğan, Ş., & Türüt, A. (2008). Fabrication and electrical characteristics of Schottky diode based on organic material. Microelectronic Engineering, 85, 1647-1651. https://doi.org/10.1016/j.mee.2008.04.003 Kaleli, M., Parlak, M., & Erçelebi, Ç. (2011). Studies on device properties of an n-AgIn5Se8/p-Si heterojunction diode. Semiconductor Science and Technology, 26(105013), 1-7. https://doi.org/http://dx.doi.org/10.1088/0268-1242/26/10/105013
  • Karataş, Ş. (2010). Effect of series resistance on the electrical characteristics and interface state energy distributions of Sn/p-Si (MS) Schottky diodes Microelectronic Engineering, 87, 1935-1940. https://doi.org/10.1016/j.mee.2009.11.168
  • Karataş, Ş., Altındal, Ş., Türüt, A., & Çakar, M. (2007). Electrical transport characteristics of Sn/p-Si schottky contacts revealed from I–V–T and C–V–T measurements. Physica B, 392, 43-50. https://doi.org/doi:10.1016/j.physb.2006.10.039
  • Kaya, İ., Kolcu, F., Demiral, G., Ergül, H., & Kiliç, E. (2015). Synthesis and characterization of imine polymers of aromatic aldehydes with 4-amino-2-methylquinoline via oxidative polycondensation. Designed Monomers and Polymers, 18(1), 89-104. https://doi.org/10.1080/15685551.2014.971395
  • Nallathambi, P., Lal, S. K., Boopalakrishnan, G., Kumar, A., Umamaheswari, C., Gogoi, R., Yadav, S. K., Gupta, A., Meshram, N. M., & Ilangovan, R. (2018). Scanning Electron Microscopy and PCR based methods for detection of False Smut [Ustilaginoidea virens (Cooke) Takahashi] Chlamydospores associated with Rice (Oryza sativa) seeds. Vegetos, 31(1), 20-27. https://doi.org/http://dx.doi.org/10.5958/2229-4473.2018.00003.4
  • Olusola, O. I., Salim, H. I., & Dharmadasa, I. M. (2016). One-sided rectifying p–n junction diodes fabricated from n-CdS and p-ZnTe:Te semiconductors. Mater. Res. Express, 3(095904), 1-15. https://doi.org/10.1088/2053-1591/3/9/095904
  • Ramaiah Subba Kodigala, P. R. D., Hill A.E., Tomlinson R.D., Bhatnagar A.K. (2001). Structural and optical investigations on CdS thin films grown by chemical bath technique. Materials Chemistry and Physics, 68, 22-30. Reddy, T. S., & Kumar, M. C. S. (2016). Effect of substrate temperature on the physical properties of co-evaporated Sn2S3 thin films. Ceramics International, 42(10), 12262-12269. https://doi.org/10.1016/j.ceramint.2016.04.172
  • Rocha, F. S., Gomes, A. J., Lunardi, C. N., Kaliaguine, S., & Patience, G. S. (2018). Experimental Methods in Chemical Engineering: Ultraviolet Visible Spectroscopy—UV-Vis. The Canadian Journal of Chemical Engineering, 96, 2512-2517. https://doi.org/10.1002/cjce.23344
  • Yakuphanoglu, F. (2007). Electrical characterization and interface state density properties of the ITO/C-70/Au Schottky diode. Journal of Physical Chemistry C, 111(3), 1505-1507. https://doi.org/10.1021/jp066912q
There are 17 citations in total.

Details

Primary Language English
Subjects Photonics, Optoelectronics and Optical Communications
Journal Section Articles
Authors

Ramazan Demir 0000-0003-4130-4927

İsmet Kaya 0000-0002-9813-2962

Early Pub Date November 11, 2024
Publication Date
Submission Date September 21, 2023
Published in Issue Year 2024 Volume: 24 Issue: 06

Cite

APA Demir, R., & Kaya, İ. (2024). Investigation of Some Properties of 4-Amino-2-Methyl-Quinoline and CdS Nano Composite Thin Films for Production of Diodes. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, 24(06), 1297-1304.
AMA Demir R, Kaya İ. Investigation of Some Properties of 4-Amino-2-Methyl-Quinoline and CdS Nano Composite Thin Films for Production of Diodes. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. November 2024;24(06):1297-1304.
Chicago Demir, Ramazan, and İsmet Kaya. “Investigation of Some Properties of 4-Amino-2-Methyl-Quinoline and CdS Nano Composite Thin Films for Production of Diodes”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 24, no. 06 (November 2024): 1297-1304.
EndNote Demir R, Kaya İ (November 1, 2024) Investigation of Some Properties of 4-Amino-2-Methyl-Quinoline and CdS Nano Composite Thin Films for Production of Diodes. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 24 06 1297–1304.
IEEE R. Demir and İ. Kaya, “Investigation of Some Properties of 4-Amino-2-Methyl-Quinoline and CdS Nano Composite Thin Films for Production of Diodes”, Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, vol. 24, no. 06, pp. 1297–1304, 2024.
ISNAD Demir, Ramazan - Kaya, İsmet. “Investigation of Some Properties of 4-Amino-2-Methyl-Quinoline and CdS Nano Composite Thin Films for Production of Diodes”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 24/06 (November 2024), 1297-1304.
JAMA Demir R, Kaya İ. Investigation of Some Properties of 4-Amino-2-Methyl-Quinoline and CdS Nano Composite Thin Films for Production of Diodes. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. 2024;24:1297–1304.
MLA Demir, Ramazan and İsmet Kaya. “Investigation of Some Properties of 4-Amino-2-Methyl-Quinoline and CdS Nano Composite Thin Films for Production of Diodes”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, vol. 24, no. 06, 2024, pp. 1297-04.
Vancouver Demir R, Kaya İ. Investigation of Some Properties of 4-Amino-2-Methyl-Quinoline and CdS Nano Composite Thin Films for Production of Diodes. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. 2024;24(06):1297-304.