Modification Technique Influence on the Adsorption Capability of Organobentonites for Reactive and Direct Dyes

Year 2024, Volume: 13 Issue: 2, 425 - 431, 29.06.2024

Seniha Morsümbül , Emriye Perrin Akçakoca Kumbasar , Saadet Yapar

https://doi.org/10.17798/bitlisfen.1419729

Abstract

In this study, the adsorption of reactive and direct dyes from synthetic textile wastewater using organobentonites modified by two different routes was studied. Except for the drying step, the synthesis conditions were the same, and organobentonites were synthesized by employing a cationic surfactant at a level corresponding to the entire cation exchange capacity of bentonite under microwave irradiation. In the final step, the samples were dried using either a freeze dryer or an air dryer. The structural characteristics of the organobentonites were determined via XRD and FTIR analyses. The obtained equilibrium data indicated that the adsorption process fitted to the Langmuir isotherm model for both dyes. Although the results indicated that both organobentonites adsorbed two of the dyes, the freeze-dried sample could serve as a more effective adsorbent for removing reactive and direct dyes from wastewater.

Keywords

Textile dyes, decolorization, adsorption, organo-bentonite, drying.

Supporting Institution

Project no. 109M752 of The Scientific and Technical Research Council of Turkey (TUBITAK); Project no. DPT-2007 K 120780 of the T.R. Prime Ministry State Planning Organization; Project no. 10MUH034 of Ege University’s scientific research projects

Project Number

Project no. 109M752 of The Scientific and Technical Research Council of Turkey (TUBITAK); Project no. DPT-2007 K 120780 of the T.R. Prime Ministry State Planning Organization; Project no. 10MUH034 of Ege University’s scientific research projects

Thanks

The authors gratefully acknowledge the financial support for this research received through Project no. 109M752 of The Scientific and Technical Research Council of Turkey (TUBITAK); through Project no. DPT-2007 K 120780 of the T.R. Prime Ministry State Planning Organization; and through Project no. 10MUH034 of Ege University’s scientific research projects.

References

• [1] D. López-Rodríguez, B. Micó-Vicent, J. Jordán-Núñez, M. Bonet-Aracil, and E. Bou-Belda, “Uses of nanoclays and adsorbents for dye recovery: a textile industry review”, Applied Sciences vol. 11, no. 23, pp. 1-27, 2021.
• [2] A. K. Dhar, H. A. Himu, M. Bhattacharjee, M.G. Mostufa, and F. Parvin, “Insights on applications of bentonite clays for the removal of dyes and heavy metals from wastewater: a review”, Environmental Science and Pollution Research, vol. 30, no. 3, pp. 5440-5474, 2023.
• [3] M. El-habacha, Y. Miyah, S. Lagdali, G. Mahmoudy, A. Dabagh, M. Chiban, F. Sinan, S. Iaich, and M. Zerbet, “General overview to understand the adsorption mechanism of textile dyes and heavy metals on the surface of different clay materials”, Arabian Journal of Chemistry, vol. 16, no. 11, pp. 1-24, 2023.
• [4] S. Barakan and V. Aghazadeh, “The advantages of clay mineral modification methods for enhancing adsorption efficiency in wastewater treatment: a review”, Environmental Science and Pollution Research, vol. 28, no.3, pp. 2572-2599, 2021.
• [5] R.A Schoonheydta and C.T. Johnston, “Surface and Interface Chemistry of Clay Minerals” in Handbook of Clay Science. Elsevier, 2006, ch. 3, pp. 87-113.
• [6] G. Lagalya, M. Ogawab, and I. Dekany, “Clay Mineral Organic Interactions” in Handbook of Clay Science. Elsevier, 2006, ch. 7.3, pp. 309-377.
• [7] J. V. F. L. Cavalcanti, C. C. da Fonseca, G. M. da Silva, I. T. Santiago, L. L. Tenório, M. Sobrinho, and O. S. Baraúna, “Adsorption of textile dye and textile effluent using organoclay from Northeast of Brazil”, Cerâmica, vol. 67, pp. 277-283, 2021.
• [8] Z. Baouch, B. Kamel Ismet, and B. Bouras, “Adsorption of different dyes from aqueous solutions using organo-clay composites”, Physical Chemistry Research, vol. 8, no. 4, pp. 767-787, 2020.
• [9] B. M. Al-Sakkaf, S. Nasreen, and N. Ejaz, “Ultrasonic assisted application of organoclay as a sorbent for treatment of textile wastewater”, Russian Journal of Physical Chemistry A, vol. 95, no. 8, pp. 1712-1719, 2021.
• [10] Y. Zhu, Y. Cui, Y. Peng, R. Dai, H. Chen, and Y. Wang, “Preparation of CTAB intercalated bentonite for ultrafast adsorption of anionic dyes and mechanism study”, Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 658, pp. 1-11, 2023.
• [11] N. Choi, Y. Son, T.H. Kim, Y. Park, and Y. Hwang, Y, “Adsorption behaviors of modified clays prepared with structurally different surfactants for anionic dyes removal”, Environmental Engineering Research, vol. 28, no. 2, pp. 1-10, 2022.
• [12] A. Oussalah and A. Boukerroui, “Removal of cationic dye using alginate–organobentonite composite beads”, Euro-Mediterranean Journal for Environmental Integration, vol. 5, no.3, pp. 1-10, 2020.
• [13] N. Daas and H. Zaghouane-Boudiaf, “Synthesis and characterization of porous bentonite adsorbent and its application to remove methylene blue dye from aqueous solutions”, Desalin. Water Treat, vol. 249, pp. 271-280, 2022.
• [14] Y. Son, Y. Kim, S. Bae, T.H. Kim, and Y. Hwang, “Investigation of chromate adsorption efficacy on organo-bentonite as potential in-situ adsorbent for groundwater remediation”, Journal of Environmental Chemical Engineering, vol. 10, no 6, pp. 1-10, 2022.
• [15] N. Khodabakhshloo, B. Biswas, F. Moore, J. Du, and R. Naidu, “Organically functionalized bentonite for the removal of perfluorooctane sulfonate, phenanthrene and copper mixtures from wastewater”, Applied Clay Science, vol. 200, pp. 1-11, 2021.
• [16] A. Marszałek, G. Kamińska, and N.F.A. Salam, “Simultaneous adsorption of organic and inorganic micropollutants from rainwater by bentonite and bentonite‑carbon nanotubes composites”, Journal of Water Process Engineering, vol. 46, pp. 1-18, 2022.
• [17] N. Yılmaz and S. Yapar, “Adsorption properties of tetradecyl- and hexadecyl trimethylammonium bentonites” Applied Clay Science, vol. 27, pp. 223-228, 2004.
• [18] Ç. Akduman, S. Morsümbül, and E.P. Akçakoca Kumbasar, “The Removal of Reactive Red 141 From Wastewater: A Study of Dye Adsorption Capability of Water-Stable Electrospun Polyvinyl Alcohol Nanofibers”, Autex Research Journal, vol. 21, no. 1, pp. 20-31, 2021.
• [19] N. Junnarkar, D. Srinivas Murty, N.S. Bhatt, and D. Madamwar, D, “Decolorization of diazo dye Direct Red 81 by a novel bacterial consortium”, World Journal of Microbiology & Biotechnolgy, vol. 22, pp. 163–168, 2006.
• [20] S. Elemen, E .P. Akçakoca Kumbasar, and S. Yapar, “Modeling the adsorption of textile dye on organoclay using an artificial neural network”, Dyes and Pigments, vol. 95, no.1, pp. 102-111, 2012.
• [21] L.K. Wang and D.F. Langley, “Determining cationic surfactant concentration”, Industrial Engineering Chemical Product Research Development, vol. 14, no.3, pp. 210–213, 1975.
• [22] B.H. Hameed, A.A Ahmad, and N. Aziz, “Isotherms, kinetics and thermodynamics of acid dye adsorption on activated palm ash”, Chemical Engineering Journal, vol. 133, pp. 195-203, 2007.
• [23] G. Özdemir, and S. Yapar, “Preparation and characterization of copper and zinc adsorbed cetylpyridinium and Nlauroylsarcosinate intercalated montmorillonites and their antibacterial activity”, Colloids and Surfaces B: Biointerfaces, vol. 188, pp. 1-8, 2020.
• [24] S. Yapar, G. Özdemir, A.M.F. Solarte, and R.M.T. Sánchez, “Surface and interface properties of lauroyl sarcosinate-adsorbed CP+-montmorillonite”, Clays and Clay Minerals, vol. 63, pp. 110–118, 2015.
• [25] Z. Li, W.T. Jiang, and H. Hong, “An FTIR investigation of hexadecyltrimethylammonium intercalation into rectorite”, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, vol. 71, pp. 1525-1534, 2008.
• [26] I. Calabrese, G. Cavallaro, G. Lazzara, M. Merli, L. Sciascia, and M.L. Turco Liveri, “Preparation and characterization of bio-organoclays using nonionic surfactant”, Adsorption, vol. 22, pp. 105–116, 2016.
• [27] Y. Xi, Z. Ding, H. He, and R.L. Frost, “Infrared spectroscopy of organoclays synthesized with the surfactant octadecyltrimethylammonium bromide”, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, vol. 61, pp. 515-525, 2005.
• [28] Z. Aksu and J.A. Yener, “Comparative adsorption/biosorption study of mono-chlorinated phenols onto various sorbents”, Waste Management, vol.21, pp. 695-702, 2001.