The nanobiocomposites synthesis from biomass and its characterization

Year 2018, Volume: 3 Issue: 2, 93 - 102, 05.07.2018

Yapıncak Göncü Emir Zafer Hoşgün Nuran Ay , Berrin Bozan

https://doi.org/10.30728/boron.376517

Abstract

This
study was conducted to evaluate the suitability of using hexagonal boron
nitride (hBN) as reinforcement in natural fibres obtained from hazelnut shell
(F) and poppy straw (H). Raw materials were treated with alkali to enrich the
cellulose content by removing lignin and hemicellulose. The nanobiocomposite
synthesis was performed with 4% and 8% of hBN. Lignin, cellulose and
hemicelluloses contents of biomass were determined. Cellulose content was
almost increased 3-fold and 2-fold after pretreatment of hazelnut shell (FCell)
and poppy straw (HCell), respectively. Strong bands at 812 and 1380cm-1
corresponding to hBN were observed in the FTIR. SEM images showed that hBN is
retained on the pretreated natural fibres. Adsorbed hBN on the structure was
highest in the microcrystalline cellulose (Cell) (91.5%), followed by FCell
(80.5%) and HCell (50.5%). Nanobiocomposites containing lignocellulose and hBN
may be recommended for use in polymer matrix structures where thermal
properties need to be altered.

Keywords

Biomass, Boron Nitride, Cellulose, Lignocellulose, nanobiocomposite

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