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AN EXAMPLE TO SEPIOLITE FORMATION IN VOLCANIC BELTS BY HYDROTHERMAL ALTERATION: KIBRISCIK (BOLU) SEPIOLITE OCCURRENCE

Year 1993, Volume: 115 Issue: 115, 49 - 68, 01.08.1993

Abstract

Geological, mineralogical and chemical properties of a sepiolite occurrence, located in the south of Kıbrıscık
township of Bolu Province, northcentral Turkey, have been investigated in detail, and new mineralogical data have been
obtained. Differing from the sedimentary sepiolite deposits, mostly associated with the carbonate/evaporite sequences, Kıbrıscık
sepiolite occurs in the Köroğlu (Gallatian) Volcanic Belt, and has formed by the hydrothermal alteration of the vitric tuff unit of
Middle Miocene aged Deveören Volcanites. The mineral, which shows a similar XRD pattern to sepiolite, gives DTA and IR
patterns with close resemblance to those of palygorskite, in addition to its chemical composition with rather high alumina
content. There are indications of monoclinal symmetry, determined by XRD, and it is thought to be possible that the material
represents a new mineral phase.

References

  • Abe, H. and Aoki, H., 1976, Experiments on the interac- tion between Na2CO3-NaHCO3 solution and cli- noptilolite, with reference to anatomization around Kuroko-type mineral deposits: Chem. Geol., 17, 89-100.
  • Barth-Wirsching, U. and Höller, H., 1989, Experimental studies on zeolite formation conditions: Eur. J. Mineral., 1,489-506.
  • Blumenthal, M., 1948, Bolu civari ile Aşağı Kızılırmak mecrası arasında Kuzey Anadolu silsilelerinin jeolojisi: MTA Pub., Serie B, No. 13, 265 s.
  • Bowen, N.L. and Tuttle, O.F., 1962, The system MgO- SiO2-H2O: Bull. Geol. Soc. Am., 60, 439.
  • Brauner, K. and Preisinger, A., 1956, Struktur und Enste- hung des Sepioliths: Tschermaks Miner. Petrog. Mitt., 6, 120-140.
  • Brindley, G.W., 1959, X-ray and electron diffraction data for sepiolite: Am. Mineral., 44, 495-500.
  • Brindley, G.W., and Pedro, G., 1972, Report of the AIPEA Nomenclature Committee: AIPEA Newsletter, 4, 3-4.
  • Caillere, S. and Henin, S., 1957, The sepiolite and paly- gorskite minerals [In The Differential Thermal In- vestigation of Clays", R.C. Mackenzie (ed)], Min- eral. Soc., London.pp 231-247.
  • Chaput, E., 1931, Notice explicative de la carte geolo- gique au 1:135 000 de la region d'Angara (Anka- ra): Bull. Fac. Sci., Univ. İstanbul, 7/3, pp 1-46.
  • Coombs, D.S.; Ellis, A.D.; Fyle, W.S. and Taylor, A.M., 1959, The zeolite fades, with comments on the in- terpretation of hydrothermal synthesis: Geochim. Cosmochim Acta, 17, 53-107.
  • Crovisier, J.L.; Eberhart, J.P.; Juteau, T. and Ehret, G., 1983, Transmission electron microscopy of basal- tic glass alteration in seawater at 80°C: Fortschr. Mineral., 61,48-49.
  • Echle, W., 1974, Zur Minteralogie und Petrogenese jung- tertiarer tuffitischer Sedimente im Neogen- Becken nordlich Mihalıççık (Westanatolien, Türkei): N. Jb. Miner. Abb., 121, 43-84.
  • Erol, O., 1952, Ankara kuzeyinde Mire ve Aydos Dağları bölgesinin jeolojisi hakkında ön rapor: MTA Rep., 2457 ( unpublished), Ankara.
  • , 1954, Köroğlu-lşık dağları volkanik kütlesinin orta bölümleri ile Beypazarı-Ayaş arasındaki Neojen havzasının jeolojisi hakkında rapor: MTA Rep., 2279, ( unpublished), Ankara.
  • Foster, M., 1960, Interpretation of the composition of tri- octahedral micas: US Geol. Surv. Prof. Pap., 354- B, 11-50.
  • Gard, J.A. and Follet, E.A., 1968, A structural scheme for palygorskite: Clay Minerals, 7, pp 367-369.
  • Hast, N., 1956, A reaction between silica and some mag- nesium compounds at room temperatures and at +37°C: Arkiv Kemi 9, pp 343-360.
  • Hayashi, H.; Otsuka, R. and Imai, N., 1969, Infrared study of sepiolite and palygorskite on heating, Am. Min- eral., 53, pp 1613-1624.
  • Holland, L, 1966, The Properties of glass surfaces: Chapman and Hall, London, 546 p.
  • Holler, H. and Wirsching, U., 1978, Experiments on the formation of zeolites by hydrothermal alteration of volcanic glass: L.B. Sand and F.A. Mumpton, ed., Natural Zeolites: Occurence, Properties, Use da, Pergamon Press, Elmsford, New York, 329-336.
  • Imai, N.; Otsuka, R.; Kashide, H. and Hayashi, R., 1969, Dehydration of palygorskite and sepiolite from Ku- zuu District, Tochigi Pref., Central Japan: Proc. Int'l Clay Conf., Tokyo, 1, pp 99-108.
  • İrkeç, T., 1991, Bolu-Kıbrıscık sepiyolitinin mineralojik ve kimyasal özellikleri ve Eskişehir-Sivrihisar sedi- manter sepiyoliti ile karşılaştırılması, Proc. 5th Nat. Clay Symp. (Eskişehir-Turkey), (M. Zor, ed.), pp 3-17.
  • , 1992, Kıbrıscık (Bolu) sepiyolit oluşumlarının min- eralojik-kimyasalözelliklerive kökenine yaklaşım M. Sc. Thesis, Ankara Univ., Fac. of Sci., Ankara, 200p.
  • and Kinkoğlu, M., 1989, 88-22b3 No.lu Bolu- Ankara Kaolin aramaları projesi kapsamında 1988 arazi sezonunda Zonguldak-Bolu-Ankara y6relerinde yapılan çalışmalara ilişkin ön etüd ra- poru, MTA Rep., 8536 (unpublished), Ankara.
  • Larsen, G.; Plum, K.H. and Förster, H., 1991, Zeolites and other hydrothermal alteration products of syn- thetic glasses, Eur. J. Mineral., 3, 933-941.
  • Leonhard, R., 1903, Geologische Skizze des Galatischen Andesit-gebites nördlisch von Ankara, N. Jb. Min. B., 16, pp 99-109.
  • Martin Vivaldi, J. L and Fenoll, P., 1970, Palygorskites and sepiolites (Hormites) [In "Differential Thermal Analysis" R.C. Mackenzie (ed)], Academic Press, London, I, pp 553-573.
  • Mifsud, A.; Rautureau, M. and Fornes, V., 1978, Etude de I'eau dans la palygorskite a I'aide des analyses thermiques, CCM, 13, pp367-374.
  • Milch, L., 1903, Die Ergussgesteine des Galatischen An- desitgebietes, N. Jb. Min. B., 16, pp 110-165.
  • Nagata, H., Shimoda, S. and Sudo, T., 1974, On dehy- dration of bound water of sepiolite, CCM, 22, pp 285-293.
  • Nagy, B. and Bradley, W.F., 1955, The structural schema of sepiolite, Am.. Mineral., 40, pp 885-892.
  • Otsuka, R., Hayashi, H. and Shimoda, S., 1968, Infrared absorption spectra of sepiolite and palygorskite: Memoirs of the School of Sci. & Eng. (Waseda Uni.), 32, pp13-24.
  • Preisinger, A., 1959, X-ray study of the structure of sepio- lite, CCM, 6, pp 61-67.
  • Rautureau, M., 1974, Analyse structurale de la sepiolite par microdiffraction electronique, These Universite d'Orleans, 89 p. ( unpublished).
  • and Tchoubar, C., 1974, Precisions concernant I'analyse structurale de la sepiolite par microdif- fraction electronique, C.R. Acad. Sci. Paris, 278 B, pp 25-28.
  • ; and Mering, J., 1972, Analyse structurale de la sepiolite par microdiffraction electronique, C.R. Acad. Sci. Paris, 274 C, pp 269-271.
  • Rogers, L.E.; Quirk, J. and Norrish, K., 1956, Occurrence of an aluminum-sepiolite in a soil having unusual water relationships, J. Soil Sci., 7, pp 177-184.
  • Rondot, J., 1956,1/100 000 lik 39/2 (güney kısmı) ve 39/4 no.lu paftaların jeolojisi (Seben-Nallıhan-Beypazarı ilçeleri), MTA Rep., 2517 ( unpublished), Ankara.
  • Scholze, H., 1988, Glas-Natur, Struktur, Eigenschaften: Springer Verlag, Berlin, 407 p.
  • Serna, C., Ahlrichs, J.L. and Serratosa, J.M. 1975, Fold- ing in sepiolite crystals, CCM, 23, pp 452-457.
  • Stchepinsky, V., 1942, Beypazarı-Nallıhan-Bolu-Gerede bölgesi jeolojisi hakkında rapor, MTA Rep., 1363 (unpublished), Ankara.
  • Thomassin, J.H., 1983, Early mineralogical evolution at the surface of volcanic glass during seawater al- teration, Experimental data, Fortschr. Mineral., 61, pp206-207.
  • ; Boutonnat, F.; Touray, J.C. and Baillif, P., 1989, Geochemical role of the water/rock ratio during the experimental alteration of a synthetic basaltic glass at 50°C. An XPS and STEM investigation, Eur. J. Mineral., 1, pp 261-274.
  • Touray, J.C. and Thomassin, J.H., 1984, Bilans et meca- nismes d'interaction des verres basaltiques et de I'eau de mer en coditions hydrothermales, Sympo- sium de I'USCV, Bruxelles, Rivista della Stazione rimentale del Vetro, 14, pp 111 -116.
  • Türkecan, A., Hepşen, N., Papak, I., Akbaş, B., Dinçel, A., Karataş, S., Özgür, İ., Akay, E., Bedi, Y., Se- vin, M., Mutlu, G., Sevin, D., Ünay, E. and Saraç, G., 1991, Seben-Gerede (Bolu)-Güdül-Beypazarı (Ankara) ve Çerkeş-Orta-Kurşunlu (Çankırı) yörelerinin (Köroğlu Dağları) jeolojisi ve volkanik kayaçların petrolojisi, MTA Rep., 9193 (unpub- lished), Ankara.
  • Weaver, C.E. and Pollard, L, 1973, The Chemistry of Clay Minerals, Elsevier, Amsterdam, 213 p.
  • White, A.F., 1983, Surface chemistry and dissolution ki- netics of glassy rocks at 25°C, Geochim. Cos- mochim. Acta, 47,pp 805-815.
  • Wirsching, U., 1976, Experiments on the hydrothermal al- teration processes of rhyolitic glass in dosed and open system, N. Jb. Miner. Mh., 5, pp 203-213.
  • Wollast, R.; Mackenzie, F. and Bricker, O., 1968, Experi- mental precipitation and genesis of sepiolite at earth-surface conditions: Am. Mineralogist 53, pp 1645-1661.
  • Yücel, A.M., Rauterau, M., Tchoubar, D. and Tchoubar, C., 1981, Calculation of the X-ray powder reflec- tion profiles of very small needle-like crystals, II. Quantitative results on Eskişehir sepiolite fibers: J. Appl. Clays, 14, pp 431-454.
  • Zvyagin, B.B., -1967, Electron Diffraction Analysis of Clay Mineral Structures, Plenum Press, New York, 122 p.
Year 1993, Volume: 115 Issue: 115, 49 - 68, 01.08.1993

Abstract


References

  • Abe, H. and Aoki, H., 1976, Experiments on the interac- tion between Na2CO3-NaHCO3 solution and cli- noptilolite, with reference to anatomization around Kuroko-type mineral deposits: Chem. Geol., 17, 89-100.
  • Barth-Wirsching, U. and Höller, H., 1989, Experimental studies on zeolite formation conditions: Eur. J. Mineral., 1,489-506.
  • Blumenthal, M., 1948, Bolu civari ile Aşağı Kızılırmak mecrası arasında Kuzey Anadolu silsilelerinin jeolojisi: MTA Pub., Serie B, No. 13, 265 s.
  • Bowen, N.L. and Tuttle, O.F., 1962, The system MgO- SiO2-H2O: Bull. Geol. Soc. Am., 60, 439.
  • Brauner, K. and Preisinger, A., 1956, Struktur und Enste- hung des Sepioliths: Tschermaks Miner. Petrog. Mitt., 6, 120-140.
  • Brindley, G.W., 1959, X-ray and electron diffraction data for sepiolite: Am. Mineral., 44, 495-500.
  • Brindley, G.W., and Pedro, G., 1972, Report of the AIPEA Nomenclature Committee: AIPEA Newsletter, 4, 3-4.
  • Caillere, S. and Henin, S., 1957, The sepiolite and paly- gorskite minerals [In The Differential Thermal In- vestigation of Clays", R.C. Mackenzie (ed)], Min- eral. Soc., London.pp 231-247.
  • Chaput, E., 1931, Notice explicative de la carte geolo- gique au 1:135 000 de la region d'Angara (Anka- ra): Bull. Fac. Sci., Univ. İstanbul, 7/3, pp 1-46.
  • Coombs, D.S.; Ellis, A.D.; Fyle, W.S. and Taylor, A.M., 1959, The zeolite fades, with comments on the in- terpretation of hydrothermal synthesis: Geochim. Cosmochim Acta, 17, 53-107.
  • Crovisier, J.L.; Eberhart, J.P.; Juteau, T. and Ehret, G., 1983, Transmission electron microscopy of basal- tic glass alteration in seawater at 80°C: Fortschr. Mineral., 61,48-49.
  • Echle, W., 1974, Zur Minteralogie und Petrogenese jung- tertiarer tuffitischer Sedimente im Neogen- Becken nordlich Mihalıççık (Westanatolien, Türkei): N. Jb. Miner. Abb., 121, 43-84.
  • Erol, O., 1952, Ankara kuzeyinde Mire ve Aydos Dağları bölgesinin jeolojisi hakkında ön rapor: MTA Rep., 2457 ( unpublished), Ankara.
  • , 1954, Köroğlu-lşık dağları volkanik kütlesinin orta bölümleri ile Beypazarı-Ayaş arasındaki Neojen havzasının jeolojisi hakkında rapor: MTA Rep., 2279, ( unpublished), Ankara.
  • Foster, M., 1960, Interpretation of the composition of tri- octahedral micas: US Geol. Surv. Prof. Pap., 354- B, 11-50.
  • Gard, J.A. and Follet, E.A., 1968, A structural scheme for palygorskite: Clay Minerals, 7, pp 367-369.
  • Hast, N., 1956, A reaction between silica and some mag- nesium compounds at room temperatures and at +37°C: Arkiv Kemi 9, pp 343-360.
  • Hayashi, H.; Otsuka, R. and Imai, N., 1969, Infrared study of sepiolite and palygorskite on heating, Am. Min- eral., 53, pp 1613-1624.
  • Holland, L, 1966, The Properties of glass surfaces: Chapman and Hall, London, 546 p.
  • Holler, H. and Wirsching, U., 1978, Experiments on the formation of zeolites by hydrothermal alteration of volcanic glass: L.B. Sand and F.A. Mumpton, ed., Natural Zeolites: Occurence, Properties, Use da, Pergamon Press, Elmsford, New York, 329-336.
  • Imai, N.; Otsuka, R.; Kashide, H. and Hayashi, R., 1969, Dehydration of palygorskite and sepiolite from Ku- zuu District, Tochigi Pref., Central Japan: Proc. Int'l Clay Conf., Tokyo, 1, pp 99-108.
  • İrkeç, T., 1991, Bolu-Kıbrıscık sepiyolitinin mineralojik ve kimyasal özellikleri ve Eskişehir-Sivrihisar sedi- manter sepiyoliti ile karşılaştırılması, Proc. 5th Nat. Clay Symp. (Eskişehir-Turkey), (M. Zor, ed.), pp 3-17.
  • , 1992, Kıbrıscık (Bolu) sepiyolit oluşumlarının min- eralojik-kimyasalözelliklerive kökenine yaklaşım M. Sc. Thesis, Ankara Univ., Fac. of Sci., Ankara, 200p.
  • and Kinkoğlu, M., 1989, 88-22b3 No.lu Bolu- Ankara Kaolin aramaları projesi kapsamında 1988 arazi sezonunda Zonguldak-Bolu-Ankara y6relerinde yapılan çalışmalara ilişkin ön etüd ra- poru, MTA Rep., 8536 (unpublished), Ankara.
  • Larsen, G.; Plum, K.H. and Förster, H., 1991, Zeolites and other hydrothermal alteration products of syn- thetic glasses, Eur. J. Mineral., 3, 933-941.
  • Leonhard, R., 1903, Geologische Skizze des Galatischen Andesit-gebites nördlisch von Ankara, N. Jb. Min. B., 16, pp 99-109.
  • Martin Vivaldi, J. L and Fenoll, P., 1970, Palygorskites and sepiolites (Hormites) [In "Differential Thermal Analysis" R.C. Mackenzie (ed)], Academic Press, London, I, pp 553-573.
  • Mifsud, A.; Rautureau, M. and Fornes, V., 1978, Etude de I'eau dans la palygorskite a I'aide des analyses thermiques, CCM, 13, pp367-374.
  • Milch, L., 1903, Die Ergussgesteine des Galatischen An- desitgebietes, N. Jb. Min. B., 16, pp 110-165.
  • Nagata, H., Shimoda, S. and Sudo, T., 1974, On dehy- dration of bound water of sepiolite, CCM, 22, pp 285-293.
  • Nagy, B. and Bradley, W.F., 1955, The structural schema of sepiolite, Am.. Mineral., 40, pp 885-892.
  • Otsuka, R., Hayashi, H. and Shimoda, S., 1968, Infrared absorption spectra of sepiolite and palygorskite: Memoirs of the School of Sci. & Eng. (Waseda Uni.), 32, pp13-24.
  • Preisinger, A., 1959, X-ray study of the structure of sepio- lite, CCM, 6, pp 61-67.
  • Rautureau, M., 1974, Analyse structurale de la sepiolite par microdiffraction electronique, These Universite d'Orleans, 89 p. ( unpublished).
  • and Tchoubar, C., 1974, Precisions concernant I'analyse structurale de la sepiolite par microdif- fraction electronique, C.R. Acad. Sci. Paris, 278 B, pp 25-28.
  • ; and Mering, J., 1972, Analyse structurale de la sepiolite par microdiffraction electronique, C.R. Acad. Sci. Paris, 274 C, pp 269-271.
  • Rogers, L.E.; Quirk, J. and Norrish, K., 1956, Occurrence of an aluminum-sepiolite in a soil having unusual water relationships, J. Soil Sci., 7, pp 177-184.
  • Rondot, J., 1956,1/100 000 lik 39/2 (güney kısmı) ve 39/4 no.lu paftaların jeolojisi (Seben-Nallıhan-Beypazarı ilçeleri), MTA Rep., 2517 ( unpublished), Ankara.
  • Scholze, H., 1988, Glas-Natur, Struktur, Eigenschaften: Springer Verlag, Berlin, 407 p.
  • Serna, C., Ahlrichs, J.L. and Serratosa, J.M. 1975, Fold- ing in sepiolite crystals, CCM, 23, pp 452-457.
  • Stchepinsky, V., 1942, Beypazarı-Nallıhan-Bolu-Gerede bölgesi jeolojisi hakkında rapor, MTA Rep., 1363 (unpublished), Ankara.
  • Thomassin, J.H., 1983, Early mineralogical evolution at the surface of volcanic glass during seawater al- teration, Experimental data, Fortschr. Mineral., 61, pp206-207.
  • ; Boutonnat, F.; Touray, J.C. and Baillif, P., 1989, Geochemical role of the water/rock ratio during the experimental alteration of a synthetic basaltic glass at 50°C. An XPS and STEM investigation, Eur. J. Mineral., 1, pp 261-274.
  • Touray, J.C. and Thomassin, J.H., 1984, Bilans et meca- nismes d'interaction des verres basaltiques et de I'eau de mer en coditions hydrothermales, Sympo- sium de I'USCV, Bruxelles, Rivista della Stazione rimentale del Vetro, 14, pp 111 -116.
  • Türkecan, A., Hepşen, N., Papak, I., Akbaş, B., Dinçel, A., Karataş, S., Özgür, İ., Akay, E., Bedi, Y., Se- vin, M., Mutlu, G., Sevin, D., Ünay, E. and Saraç, G., 1991, Seben-Gerede (Bolu)-Güdül-Beypazarı (Ankara) ve Çerkeş-Orta-Kurşunlu (Çankırı) yörelerinin (Köroğlu Dağları) jeolojisi ve volkanik kayaçların petrolojisi, MTA Rep., 9193 (unpub- lished), Ankara.
  • Weaver, C.E. and Pollard, L, 1973, The Chemistry of Clay Minerals, Elsevier, Amsterdam, 213 p.
  • White, A.F., 1983, Surface chemistry and dissolution ki- netics of glassy rocks at 25°C, Geochim. Cos- mochim. Acta, 47,pp 805-815.
  • Wirsching, U., 1976, Experiments on the hydrothermal al- teration processes of rhyolitic glass in dosed and open system, N. Jb. Miner. Mh., 5, pp 203-213.
  • Wollast, R.; Mackenzie, F. and Bricker, O., 1968, Experi- mental precipitation and genesis of sepiolite at earth-surface conditions: Am. Mineralogist 53, pp 1645-1661.
  • Yücel, A.M., Rauterau, M., Tchoubar, D. and Tchoubar, C., 1981, Calculation of the X-ray powder reflec- tion profiles of very small needle-like crystals, II. Quantitative results on Eskişehir sepiolite fibers: J. Appl. Clays, 14, pp 431-454.
  • Zvyagin, B.B., -1967, Electron Diffraction Analysis of Clay Mineral Structures, Plenum Press, New York, 122 p.
There are 51 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Articles
Authors

Taner Irkeç This is me

Taner Ünlü

Publication Date August 1, 1993
Published in Issue Year 1993 Volume: 115 Issue: 115

Cite

APA Irkeç, T., & Ünlü, T. (1993). AN EXAMPLE TO SEPIOLITE FORMATION IN VOLCANIC BELTS BY HYDROTHERMAL ALTERATION: KIBRISCIK (BOLU) SEPIOLITE OCCURRENCE. Bulletin of the Mineral Research and Exploration, 115(115), 49-68.
AMA Irkeç T, Ünlü T. AN EXAMPLE TO SEPIOLITE FORMATION IN VOLCANIC BELTS BY HYDROTHERMAL ALTERATION: KIBRISCIK (BOLU) SEPIOLITE OCCURRENCE. Bull.Min.Res.Exp. August 1993;115(115):49-68.
Chicago Irkeç, Taner, and Taner Ünlü. “AN EXAMPLE TO SEPIOLITE FORMATION IN VOLCANIC BELTS BY HYDROTHERMAL ALTERATION: KIBRISCIK (BOLU) SEPIOLITE OCCURRENCE”. Bulletin of the Mineral Research and Exploration 115, no. 115 (August 1993): 49-68.
EndNote Irkeç T, Ünlü T (August 1, 1993) AN EXAMPLE TO SEPIOLITE FORMATION IN VOLCANIC BELTS BY HYDROTHERMAL ALTERATION: KIBRISCIK (BOLU) SEPIOLITE OCCURRENCE. Bulletin of the Mineral Research and Exploration 115 115 49–68.
IEEE T. Irkeç and T. Ünlü, “AN EXAMPLE TO SEPIOLITE FORMATION IN VOLCANIC BELTS BY HYDROTHERMAL ALTERATION: KIBRISCIK (BOLU) SEPIOLITE OCCURRENCE”, Bull.Min.Res.Exp., vol. 115, no. 115, pp. 49–68, 1993.
ISNAD Irkeç, Taner - Ünlü, Taner. “AN EXAMPLE TO SEPIOLITE FORMATION IN VOLCANIC BELTS BY HYDROTHERMAL ALTERATION: KIBRISCIK (BOLU) SEPIOLITE OCCURRENCE”. Bulletin of the Mineral Research and Exploration 115/115 (August 1993), 49-68.
JAMA Irkeç T, Ünlü T. AN EXAMPLE TO SEPIOLITE FORMATION IN VOLCANIC BELTS BY HYDROTHERMAL ALTERATION: KIBRISCIK (BOLU) SEPIOLITE OCCURRENCE. Bull.Min.Res.Exp. 1993;115:49–68.
MLA Irkeç, Taner and Taner Ünlü. “AN EXAMPLE TO SEPIOLITE FORMATION IN VOLCANIC BELTS BY HYDROTHERMAL ALTERATION: KIBRISCIK (BOLU) SEPIOLITE OCCURRENCE”. Bulletin of the Mineral Research and Exploration, vol. 115, no. 115, 1993, pp. 49-68.
Vancouver Irkeç T, Ünlü T. AN EXAMPLE TO SEPIOLITE FORMATION IN VOLCANIC BELTS BY HYDROTHERMAL ALTERATION: KIBRISCIK (BOLU) SEPIOLITE OCCURRENCE. Bull.Min.Res.Exp. 1993;115(115):49-68.

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