Synthesis and Crystal Structure of 4,5,12,13Tetraaza-Dibenzo[b,k]Chrysene

Year 2015, , 339 - 344, 23.12.2015

Famil Valiyev

https://doi.org/10.18466/cbujos.03944

Abstract

New synthetic methodology of fused aromatic hydrocarbons with nitrogen heterocyclic of 4,5,12,13-Tetraaza-dibenzo[b,k]chrysene(4) were designed and synthesized by chemical methods. Compound 4 fully characterized by ¹H NMR, ¹³C NMR, EI-mass spectral, elemental and single crystal X-ray analysis. Molecules of 4 are completely planar and form face-to-face π-stacking. Shortest distances between fused rings of π- π interactions are 3.346 Å. Compound (4) is a potential candidate for high mobility single crystal organic field effect transistors (OFET’s).

 

Keywords

4, 5, 12, 13-Tetraaza-dibenzo[b, k]chrysene, heterocyclic aromatic hydrocarbons, organic semiconductors, crystal structure

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