Adsorptive Removal of Tartrazine Dye by Poly(N-vinylimidazole-ethylene glycol dimethacrylate) And Poly(2-hydroxyethyl methacrylate-ethylene glycol dimethacrylate) Polymers

Year 2021, Volume: 17 Issue: 4, 397 - 404, 29.12.2021

Ayşe Dinçer , Tülin Aydemir

Abstract

Poly(N-vinylimidazole-ethylene glycol dimethacrylate (poly(N-VI-EGDMA)) and poly(2-hydroxyethyl methacrylate-ethylene glycol dimethacrylate (poly(HEMA-EGDMA)) were synthesized as adsorbents for adsorptive removal of tartrazine dye from aqueous solutions. To achieve maximum tartrazine adsorption, some parameters were examined and pH was found to be an important factor on adsorption poly(N-VI-EGDMA). As the temperature increased, removal amount of tartrazine was increased. The experimental capacities were found as 265.5 mg/g and 45.15 mg/g for poly(N-VI-EGDMA) and poly(HEMA-EGDMA), respectively. The experimental data well correlated with Freundlich isotherm. The estimated ∆Hº values were found as 12.76 kJ/mol and 10.40 kJ/mol for poly(N-VI-EGDMA) and poly(HEMA-EGDMA), respectively. Adsorption was demonstrated to be endothermic in nature. The characterization of these polymers were done by using FTIR, TGA and SEM analysis.

Keywords

Adsorption isotherms, dye removal, poly(N-vinylimidazole-ethylene glycol dimethacrylate, poly(2-hydroxyethyl methacrylate-ethylene glycol dimethacrylate, tartrazine.

References

• [1] El-Sayed BA, Mohamed WAA, Galal HR, Abd El-Bary HM, Ahmed MAM.2019. Photocatalytic study of some synthesized MWCNTs/TiO2 nanocomposites used in the treatment of industrial hazard materials. Egypt J Pet;28:247–52.
• [2] Singh PK, Singh RL. 2017. Bio-removal of Azo Dyes: A Review. Int J Appl Sci Biotechnol;5:108–26.
• [3] Saxena M, Sharma N, Saxena R. 2020. Highly efficient and rapid removal of a toxic dye: Adsorption kinetics, isotherm, and mechanism studies on functionalized multiwalled carbon nanotubes. Surfaces and Interfaces;21:100639.
• [4] Fatima B, Siddiqui SI, Ahmed R, Chaudhry SA.2019. Green synthesis of f-CdWO4 for photocatalytic degradation and adsorptive removal of Bismarck Brown R dye from water. Water Resour Ind;22:100119.
• [5] Liu H, Zhang J, Lu M, Liang L, Zhang H, Wei J. 2020. Biosynthesis based membrane filtration coupled with iron nanoparticles reduction process in removal of dyes. Chem Eng J ;387:124202.
• [6] Hisada M, Tomizawa Y, Kawase Y.2019. Removal kinetics of cationic azo-dye from aqueous solution by poly-γ-glutamic acid biosorbent: Contributions of adsorption and complexation/precipitation to Basic Orange 2 removal. J Environ Chem Eng;7:103157.
• [7] Hussain S, Kamran M, Khan SA, Shaheen K, Shah Z, Suo H, et al. 2021. Adsorption, kinetics and thermodynamics studies of methyl orange dye sequestration through chitosan composites films. Int J Biol Macromol;168:383–94. https://doi.org/10.1016/j.ijbiomac.2020.12.054.
• [8] Kong Q, Wang X, Lou T.2020. Preparation of millimeter-sized chitosan/carboxymethyl cellulose hollow capsule and its dye adsorption properties. Carbohydr Polym;244:116481.
• [9] Morais da Silva PM, Camparotto NG, Figueiredo Neves T de, Grego Lira KT, Mastelaro VR, Siqueira Franco Picone C, et al. 2020. Effective removal of basic dye onto sustainable chitosan beads: Batch and fixed-bed column adsorption, beads stability and mechanism. Sustain Chem Pharm;18:100348.
• [10] Xu MY, Jiang HL, Xie ZW, Li ZT, Xu D, He FA.2020. Highly efficient selective adsorption of anionic dyes by modified β-cyclodextrin polymers. J Taiwan Inst Chem Eng;108:114–28.
• [11] Basu A, Suresh Kumar G.2015. Thermodynamics of the interaction of the food additive tartrazine with serum albumins: A microcalorimetric investigation. Food Chem;175:137–42.
• [12] Vidal M, Garcia-Arrona R, Bordagaray A, Ostra M, Albizu G.2018. Simultaneous determination of color additives tartrazine and allura red in food products by digital image analysis. Talanta;184:58–64.
• [13] Amsaraj R, Mutturi S.2020. Real-coded GA coupled to PLS for rapid detection and quantification of tartrazine in tea using FT-IR spectroscopy. Lwt; 2020:110583.
• [14] Drzeżdżon J, Jacewicz D, Sielicka A, Chmurzyński L.2019. A review of new approaches to analytical methods to determine the structure and morphology of polymers. TrAC - Trends Anal Chem;118:470–6. https://doi.org/10.1016/j.trac.2019.06.013.
• [15] Ng HM, Saidi NM, Omar FS, Ramesh K, Ramesh S, Bashir S.2018. Thermogravimetric Analysis of Polymers. Encycl Polym Sci Technol 2018:1–29.
• [16] Ahmad MA, Ahmad Puad NA, Bello OS.2014. Kinetic, equilibrium and thermodynamic studies of synthetic dye removal using pomegranate peel activated carbon prepared by microwave-induced KOH activation. Water Resour Ind;6:18–35.
• [17] Yan YZ, Nagappan S, Yoo JM, Nechikkattu R, Park SS, Ha CS. 2020. Polyethyleneimine-grafted polysilsesquioxane hollow spheres for the highly efficient removal of anionic dyes and selective adsorption of Cr(VI). J Environ Chem Eng 2020:104814. https://doi.org/10.1016/j.jece.2020.104814
• [18] Alrobei H, Prashanth MK, Manjunatha CR, Kumar CBP, Chitrabanu CP, Shivaramu PD, et al. Adsorption of anionic dye on eco-friendly synthesised reduced graphene oxide anchored with lanthanum aluminate: Isotherms, kinetics and statistical error analysis. Ceram Int 2020.
• [19] Bensalah H, Younssi SA, Ouammou M, Gurlo A, Bekheet MF.2020. Azo dye adsorption on an industrial waste-transformed hydroxyapatite adsorbent: Kinetics, isotherms, mechanism and regeneration studies. J Environ Chem Eng;8:103807.
• [20] Chen H, Deng X, Ding G, Qiao Y.2019. The synthesis, adsorption mechanism and application of polyethyleneimine functionalized magnetic nanoparticles for the analysis of synthetic colorants in candies and beverages. Food Chem;293:340–7.
• [21] Ghaedi M, Sadeghian B, Pebdani AA, Sahraei R, Daneshfar A, Duran C. 2012. Kinetics, thermodynamics and equilibrium evaluation of direct yellow 12 removal by adsorption onto silver nanoparticles loaded activated carbon. Chem Eng J;187:133–41.