Research Article
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Grafen Nanopartiküllerinin Dokuma Aramid/Epoksi Kompozitlerinin Mekanik Özelliklerine Etkisi

Year 2025, Volume: 13 Issue: 1, 402 - 411, 30.01.2025
https://doi.org/10.29130/dubited.1542336

Abstract

Bu çalışmada aramid fiber /epoksi kompozitlere ilave edilen grafen miktarının bu kompozitlerin mekanik özelliklerine etkisi incelenmiştir. Çalışmada epoksi matris içerisine dört farklı oranda grafen
nanopartiküller ilave edilerek mekanik yöntemle karıştırıldıktan sonra el yatırma ve vakum infüzyon
yöntemleri kullanılarak 5 katlı aramid epoksi grafen kompozit plakalar elde edilmiştir. Elde edilen bu kompozit plakalardan eğme testi için ASTM 790 ve çekme testi için ASTM D3039 standartlara göre numuneler kesilerek üç nokta eğme ve çekme testleri yapılmıştır. Mikro yapı incelemeleri makro
mikroskop altında yapılmıştır. Yapılan çalışmalar sonrasında üretilen kompozitlerin mikro yapılarında
aglomerasyonun oluştuğu gözlemlenmiştir. Aramid epoksi kompozite ilave edilen grafenin eğilme dayanımı ve eğilme modülünü arttırdığı %1 grafen ilave edilen numunelerde en yüksek eğilme gerilmesi
gözlenmiştir. Katkısız numunelere göre bu numunede eğilme mukavemeti yaklaşık %64 oranında artmıştır. Ayrıca çekme testleri sonrasında en yüksek çekme dayanımının katkısız numunelerde olduğu, %0.25 den daha fazla grafen ilave edilen numunelerde ise grafenin yapıda oluşturduğu aglomerasyona bağlı olarak çekme dayanımının düştüğü tespit edilmiştir.

Project Number

KBÜBAP-21-YL-010

References

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  • [4] T.P. Sathishkumar, S. Satheeshkumar, and J. Naveen, “Glass fiber-reinforced polymer composites–A review,” Journal of Reinforced Plastics and Composites, vol. 33, no. 13, pp. 1258-1275, 2014. doi:10.1177/0731684414530790.
  • [5] T.K. Das, P. Ghosh, and N.-C. Das, “Preparation, development, outcomes, and application versatility of carbon fiber-based polymer composites: A review,” Advanced Composites and Hybrid Materials, vol. 2, no. 2, pp. 214-233, 2019. doi:10.1007/s42114-018-0072-z.
  • [6] B. Zhang, L. Jia, M. Tian, N. Ning, L. Zhang, and W. Wang, “Surface and interface modification of aramid fiber and its reinforcement for polymer composites: A review,” European Polymer Journal, vol. 147, p. 110352, 2021. doi:10.1016/j.eurpolymj.2021.110352.
  • [7] G. Mittal, K.Y. Rhee, V. Mišković-Stanković, and D. Hui, “Reinforcements in multi-scale polymer composites: Processing, properties, and applications,” Composites Part B: Engineering, vol. 138, pp. 122-139, 2018. doi:10.1016/j.compositesb.2017.11.028.
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  • [13] A.H.I. Mourad, N. Cherupurakal, F. Hafeez, I. Barsoum, F.A. Genena, M.S. Al Mansoori, and L.-A. Al Marzooqi, “Impact strengthening of laminated kevlar/epoxy composites by nanoparticle reinforcement,” Polymers, vol. 12, no. 12, p. 2814, 2020. doi:10.3390/polym12122814.
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  • [15] V.G.S. Veerakumar, B.P. Shanmugavel, and S. Harish, “On the influence of the functionalization of graphene nanoplatelets and glass fiber on the mechanical properties of GFRP composites,” Applied Composite Materials, vol. 28, no. 4, pp. 1127-1152, 2021. doi:10.1007/s10443-021-09908-9.
  • [16] A. Namdev, A. Telang, and R. Purohit, “Effect of graphene nano platelets on mechanical and physical properties of carbon fibre/epoxy hybrid composites,” Advanced Materials and Processing Technologies, vol. 8, pp. 1168-1181, 2022. doi:10.1080/2374068X.2021.1939557.
  • [17] A. Kumar, K. Sharma, and A.R. Dixit, “Effects of various functional groups in graphene on the tensile and flexural properties of epoxy nanocomposites: A comparative study,” Fullerenes, Nanotubes and Carbon Nanostructures, vol. 30, no. 11, pp. 1123-1133,2022. doi:10.1080/1536383X.2022.2077332.
  • [18] A.F. Ávila, L.D.O. Peixoto, A. S. Neto, J.D. Ávila Junior, and M.G.R. Carvalho, “Bending investigation on carbon fiber/epoxy composites nano-modified by graphene,” Journal of the Brazilian Society of Mechanical Sciences and Engineering, vol. 34, pp. 269-275, 2012.
  • [19] M. Alsaadi, B. Younus, A. Erklig, M. Bulut, O. Bozkurt, and B. Sulaiman, “Effect of Graphene Nano-Platelets on Mechanical and Impact Characteristics of Carbon/Kevlar Reinforced Epoxy Hybrid Nanocomposites,” Proceedings of the Institution of Mechanical Engineers, Part C: Journal of Mechanical Engineering Science, vol. 235, no. 23, pp. 7139-7151, 2012. doi:10.1177/09544062211016883.
  • [20] S. Fu, Z. Sun, P. Huang, Y. Li, and N. Hu, “Some basic aspects of polymer nanocomposites: A critical review,” Nano Materials Science, vol. 1, no. 1, pp. 2-30, 2019. doi:10.1016/j.nanoms.02.006.

THE EFFECT OF GRAPHENE NANOPARTICLES ON THE MECHANICAL PROPERTIES OF WOVEN ARAMID/EPOXY COMPOSITES

Year 2025, Volume: 13 Issue: 1, 402 - 411, 30.01.2025
https://doi.org/10.29130/dubited.1542336

Abstract

In this study, the effect of the amount of graphene added to aramid fiber/epoxy composites on the mechanical properties of these composites was investigated. In the study, graphene nanoparticles were added to the epoxy matrix at four different rates and mixed by mechanical methods, and then 5-layer aramid epoxy graphene composite plates were obtained using hand lay-up and vacuum infusion methods. Samples were cut from these composite plates according to ASTM 790 for bending test and ASTM D3039 for tensile test and three-point bending and tensile tests were performed. Microstructure examinations were carried out under a macro microscope. After the studies, it was observed that agglomeration occurred in the microstructures of the produced composites. It was determined that graphene added to the aramid epoxy composite increased the bending strength and bending modulus, the highest bending stress was observed in the samples with 1% graphene added. The flexural strength, which compared to the undoped composite, increased about 64 % in this sample. In addition, the highest tensile strength was measured in the undoped sample, and after the 0.25% graphene addition, the tensile strength decreased due to the agglomeration of graphene that occurred in the structure.

Supporting Institution

The authors are thanks to the financial support for this study from Karabuk University Scientific Research Projects Department (KBÜBAP 21-YL-010)

Project Number

KBÜBAP-21-YL-010

References

  • [1] I. Taraghi, A. Fereidoon, and A. Mohyeddin, “The effect of Mwcnts on the mechanical properties of woven kevlar/epoxy composites,” Steel and Composite Structures, vol. 17, no. 6, pp. 825-834, 2014. doi:10.12989/scs.2014.17.6.825.
  • [2] S.A. Mirsalehi, A.-A. Youzbashi, and A. Sazgar, “Enhancement of out-of-plane mechanical properties of carbon fiber reinforced epoxy resin composite by incorporating the multi-walled carbon nanotubes,” SN Applied Sciences, vol. 3, no. 6, pp. 1-12, 2021. doi:10.1007/s42452-021-04624-2.
  • [3] T. Topkaya, Y.H. Çelik, and E. Kilickap, “Mechanical properties of fiber/graphene epoxy hybrid composites,” Journal of Mechanical Science and Technology, vol. 34, no. 11, pp. 4589-4595, 2020. doi:10.1007/s12206-020-1016-4.
  • [4] T.P. Sathishkumar, S. Satheeshkumar, and J. Naveen, “Glass fiber-reinforced polymer composites–A review,” Journal of Reinforced Plastics and Composites, vol. 33, no. 13, pp. 1258-1275, 2014. doi:10.1177/0731684414530790.
  • [5] T.K. Das, P. Ghosh, and N.-C. Das, “Preparation, development, outcomes, and application versatility of carbon fiber-based polymer composites: A review,” Advanced Composites and Hybrid Materials, vol. 2, no. 2, pp. 214-233, 2019. doi:10.1007/s42114-018-0072-z.
  • [6] B. Zhang, L. Jia, M. Tian, N. Ning, L. Zhang, and W. Wang, “Surface and interface modification of aramid fiber and its reinforcement for polymer composites: A review,” European Polymer Journal, vol. 147, p. 110352, 2021. doi:10.1016/j.eurpolymj.2021.110352.
  • [7] G. Mittal, K.Y. Rhee, V. Mišković-Stanković, and D. Hui, “Reinforcements in multi-scale polymer composites: Processing, properties, and applications,” Composites Part B: Engineering, vol. 138, pp. 122-139, 2018. doi:10.1016/j.compositesb.2017.11.028.
  • [8] S. Prashanth, K.M. Subbaya, K. Nithin, and S. Sachhidananda, “Fiber Reinforced Composites A review,” Journal of Material Science and Engineering, vol. 6, no. 3, pp. 2-6, 2017. doi:10.4172/2169-0022.1000341.
  • [9] Y. Wu, B. Tang, K. Liu, X. Zeng, J. Lu, T. Zhang, and X. Shen, “Enhanced flexural properties of aramid fiber/epoxy composites by graphene oxide,” Nanotechnology Reviews, vol. 8, no. 1, pp. 484-492, 2019. doi:10.1515/ntrev-2019-0043.
  • [10] S. Kumar, D.S. Gupta, I. Singh, and A. Sharma, “Behavior of kevlar/epoxy composite plates under ballistic impact,” Journal of Reinforced Plastics and Composites, vol. 29, no. 13, pp. 2048-2064, 2010. doi:10.1177/0731684409343727.
  • [11] M.E. Islam, T.H. Mahdi, M.V. Hosur, and S. Jeelani, “Characterization of carbon fiber reinforced epoxy composites modified with nanoclay and carbon nanotubes,” Procedia Engineering, vol. 105, pp. 821-828, 2015. doi:10.1016/j.proeng.2015.05.078.
  • [12] M.S. Tareq, S. Zainuddin, E. Woodside, and F. Syed, “Investigation of the flexural and thermomechanical properties of nanoclay/graphene reinforced carbon fiber epoxy composites,” Journal of Materials Research, vol. 34, no. 21, pp. 3678-3687, 2019. doi:10.1557/jmr.2019.302.
  • [13] A.H.I. Mourad, N. Cherupurakal, F. Hafeez, I. Barsoum, F.A. Genena, M.S. Al Mansoori, and L.-A. Al Marzooqi, “Impact strengthening of laminated kevlar/epoxy composites by nanoparticle reinforcement,” Polymers, vol. 12, no. 12, p. 2814, 2020. doi:10.3390/polym12122814.
  • [14] S. Sharma, A.K. Pathak, V.N. Singh, S. Teotia, S.R. Dhakate, and B.P. Singh, “Excellent mechanical properties of long multiwalled carbon nanotube bridged kevlar fabric,” Carbon, vol. 137, pp. 104-117, 2018. doi:10.1016/j.carbon.2018.05.017.
  • [15] V.G.S. Veerakumar, B.P. Shanmugavel, and S. Harish, “On the influence of the functionalization of graphene nanoplatelets and glass fiber on the mechanical properties of GFRP composites,” Applied Composite Materials, vol. 28, no. 4, pp. 1127-1152, 2021. doi:10.1007/s10443-021-09908-9.
  • [16] A. Namdev, A. Telang, and R. Purohit, “Effect of graphene nano platelets on mechanical and physical properties of carbon fibre/epoxy hybrid composites,” Advanced Materials and Processing Technologies, vol. 8, pp. 1168-1181, 2022. doi:10.1080/2374068X.2021.1939557.
  • [17] A. Kumar, K. Sharma, and A.R. Dixit, “Effects of various functional groups in graphene on the tensile and flexural properties of epoxy nanocomposites: A comparative study,” Fullerenes, Nanotubes and Carbon Nanostructures, vol. 30, no. 11, pp. 1123-1133,2022. doi:10.1080/1536383X.2022.2077332.
  • [18] A.F. Ávila, L.D.O. Peixoto, A. S. Neto, J.D. Ávila Junior, and M.G.R. Carvalho, “Bending investigation on carbon fiber/epoxy composites nano-modified by graphene,” Journal of the Brazilian Society of Mechanical Sciences and Engineering, vol. 34, pp. 269-275, 2012.
  • [19] M. Alsaadi, B. Younus, A. Erklig, M. Bulut, O. Bozkurt, and B. Sulaiman, “Effect of Graphene Nano-Platelets on Mechanical and Impact Characteristics of Carbon/Kevlar Reinforced Epoxy Hybrid Nanocomposites,” Proceedings of the Institution of Mechanical Engineers, Part C: Journal of Mechanical Engineering Science, vol. 235, no. 23, pp. 7139-7151, 2012. doi:10.1177/09544062211016883.
  • [20] S. Fu, Z. Sun, P. Huang, Y. Li, and N. Hu, “Some basic aspects of polymer nanocomposites: A critical review,” Nano Materials Science, vol. 1, no. 1, pp. 2-30, 2019. doi:10.1016/j.nanoms.02.006.
There are 20 citations in total.

Details

Primary Language English
Subjects Material Design and Behaviors
Journal Section Articles
Authors

Ömer Şen 0000-0001-6164-4123

Musa Yıldırım 0000-0002-2464-1182

Project Number KBÜBAP-21-YL-010
Publication Date January 30, 2025
Submission Date September 2, 2024
Acceptance Date October 31, 2024
Published in Issue Year 2025 Volume: 13 Issue: 1

Cite

APA Şen, Ö., & Yıldırım, M. (2025). THE EFFECT OF GRAPHENE NANOPARTICLES ON THE MECHANICAL PROPERTIES OF WOVEN ARAMID/EPOXY COMPOSITES. Duzce University Journal of Science and Technology, 13(1), 402-411. https://doi.org/10.29130/dubited.1542336
AMA Şen Ö, Yıldırım M. THE EFFECT OF GRAPHENE NANOPARTICLES ON THE MECHANICAL PROPERTIES OF WOVEN ARAMID/EPOXY COMPOSITES. DUBİTED. January 2025;13(1):402-411. doi:10.29130/dubited.1542336
Chicago Şen, Ömer, and Musa Yıldırım. “THE EFFECT OF GRAPHENE NANOPARTICLES ON THE MECHANICAL PROPERTIES OF WOVEN ARAMID/EPOXY COMPOSITES”. Duzce University Journal of Science and Technology 13, no. 1 (January 2025): 402-11. https://doi.org/10.29130/dubited.1542336.
EndNote Şen Ö, Yıldırım M (January 1, 2025) THE EFFECT OF GRAPHENE NANOPARTICLES ON THE MECHANICAL PROPERTIES OF WOVEN ARAMID/EPOXY COMPOSITES. Duzce University Journal of Science and Technology 13 1 402–411.
IEEE Ö. Şen and M. Yıldırım, “THE EFFECT OF GRAPHENE NANOPARTICLES ON THE MECHANICAL PROPERTIES OF WOVEN ARAMID/EPOXY COMPOSITES”, DUBİTED, vol. 13, no. 1, pp. 402–411, 2025, doi: 10.29130/dubited.1542336.
ISNAD Şen, Ömer - Yıldırım, Musa. “THE EFFECT OF GRAPHENE NANOPARTICLES ON THE MECHANICAL PROPERTIES OF WOVEN ARAMID/EPOXY COMPOSITES”. Duzce University Journal of Science and Technology 13/1 (January 2025), 402-411. https://doi.org/10.29130/dubited.1542336.
JAMA Şen Ö, Yıldırım M. THE EFFECT OF GRAPHENE NANOPARTICLES ON THE MECHANICAL PROPERTIES OF WOVEN ARAMID/EPOXY COMPOSITES. DUBİTED. 2025;13:402–411.
MLA Şen, Ömer and Musa Yıldırım. “THE EFFECT OF GRAPHENE NANOPARTICLES ON THE MECHANICAL PROPERTIES OF WOVEN ARAMID/EPOXY COMPOSITES”. Duzce University Journal of Science and Technology, vol. 13, no. 1, 2025, pp. 402-11, doi:10.29130/dubited.1542336.
Vancouver Şen Ö, Yıldırım M. THE EFFECT OF GRAPHENE NANOPARTICLES ON THE MECHANICAL PROPERTIES OF WOVEN ARAMID/EPOXY COMPOSITES. DUBİTED. 2025;13(1):402-11.