Development of Alkali-Activated Binders from Recycling Regional Tuff and Marble Wastes
Year 2023,
Volume: 10 Issue: 2, 371 - 387, 31.05.2023
İlker Tekin
,
Baraka Cıza
,
H. Süleyman Gökçe
Abstract
The sustainability goals of the developing world have led many industries to recycle their wastes and reduce emitting greenhouse gases. To contribute to these environmental responsibilities, this study has focused on the development of eco-friendly binder materials from regional ground tuff and marble wastes by the activation of Na2SiO3 and NaOH or slaked lime (Ca(OH)2). The results of the study show that alkali-activated composites tend to the expansion, drying shrinkage cracking, leaching and efflorescence. The compressive strength values of the NaOH and Ca(OH)2-activated pastes have reached up to 15 MPa and 9 MPa, respectively. A reduction in the NaOH molarity has improved the compressive strength, dimensional stability and durability of tuff-based alkali-activated pastes.
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Year 2023,
Volume: 10 Issue: 2, 371 - 387, 31.05.2023
İlker Tekin
,
Baraka Cıza
,
H. Süleyman Gökçe
References
- [1]. Sumesh, M., Alengaram, U. J., Jumaat, M. Z., Mo, K.H. and Alnahhal, M. F., “Incorporation of nano-materials in cement composite and geopolymer based paste and mortar – A review”, Constr. Build. Mater., 2017, 148: 62-84.
- [2]. Andrew, R. M., “Global CO2 emissions from cement production, 1928–2017”, Earth Syst. Sci. Data, 2018, 10: 2213-2239.
- [3]. Bhutta, A., Farooq, M., Zanotti, C. and Banthia, N., “Pull-out behavior of different fibers in geopolymer mortars: effects of alkaline solution concentration and curing”, Mater. Struct., 2017, 50: 80.
- [4]. Zhang, P., Zheng, Y., Wang, K. and Zhang, J., “A review on properties of fresh and hardened geopolymer mortar”, Compos. Part B Eng., 2018, 152: 79-95.
- [5]. Ng, C., Alengaram, U. J., Wong, L. S., Mo, K. H., Jumaat, M. Z. and Ramesh, S., “A review on microstructural study and compressive strength of geopolymer mortar, paste and concrete”, Constr. Build. Mater., 2018, 186: 550-576.
- [6]. Kolawole, J. T., Olusola, K. O., Babafemi, A. J., Olalusi, O. B. and Fanijo, E., “Blended cement binders containing bamboo leaf ash and ground clay brick waste for sustainable concrete”, Materialia, 2021, 15: 101045.
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- [20]. Clausi, M., Tarantino, S. C., Magnani, L. L., Riccardi, M. P., Tedeschi, C. and Zema, M., “Metakaolin as a precursor of materials for applications in Cultural Heritage: Geopolymer-based mortars with ornamental stone aggregates”, Appl. Clay Sci., 2016, 132-133: 589-599.
- [21]. Sethi, H., Bansal, P. P. and Sharma, R., “Effect of addition of GGBS and glass powder on the properties of geopolymer concrete”, Iran J. Sci. Technol. Trans. Civ. Eng., 2019, 43: 607–617.
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- [23]. Khater, H. M. and Abd el Gawaad, H. A., “Characterization of alkali activated geopolymer mortar doped with MWCNT”, Constr. Build. Mater., 2016, 102: 329-337.
- [24]. Hanjitsuwan, S., Phoo-ngernkham, T. and Damrongwiriyanupap, N., “Comparative study using Portland cement and calcium carbide residue as a promoter in bottom ash geopolymer mortar”, Constr. Build. Mater., 2017, 133: 128-134.
- [25]. Kim, Y. Y., Lee, B. J., Saraswathy, V. and Kwon, S.-J., “Strength and durability performance of alkali-activated rice husk ash geopolymer mortar”, Sci. World J., 2014, 2014: 209584.
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- [27]. Xie, T. and Ozbakkaloglu, T., “Behavior of low-calcium fly and bottom ash-based geopolymer concrete cured at ambient temperature”, Ceram. Int., 2015, 41: 5945-5958.
- [28]. Adak, D., Sarkar, M. and Mandal, S., “Structural performance of nano-silica modified fly-ash based geopolymer concrete”, Constr. Build. Mater., 2017, 137: 430-439.
- [29]. Assi, L., Ghahari, S., Deaver, E., Leaphart, D. and Ziehl, P., “Improvement of the early and final compressive strength of fly ash-based geopolymer concrete at ambient conditions”, Constr. Build. Mater., 2016, 123: 806-813.
- [30]. Gunasekara, C., Law, D. W. and Setunge, S., “Long term permeation properties of different fly ash geopolymer concretes”, Constr. Build. Mater., 2016, 124: 352-362.
- [31]. Pilehvar, S., Cao, V. D., Szczotok, A. M., Carmona, M., Valentini, L., Lanzón, M., Pamies, R. and Kjøniksen, A.-L., “Physical and mechanical properties of fly ash and slag geopolymer concrete containing different types of micro-encapsulated phase change materials”, Constr. Build. Mater., 2018, 173: 28-39.
- [32]. Nana, A., Epey, N., Rodrique, K. C., Deutou, J. G. N., Djobo, J. N. Y., Tomé, S., Alomayri, T. S., Ngouné, J., Kamseu, E. and Leonelli, C., “Mechanical strength and microstructure of metakaolin/volcanic ash-based geopolymer composites reinforced with reactive silica from rice husk ash (RHA)”, Materialia, 2021, 16: 101083.
- [33]. Sharmin, A., Alengaram, U. J., Jumaat, M. Z., Yusuf, M. O., Kabir, S. M. A. and Bashar, I. I., “Influence of source materials and the role of oxide composition on the performance of ternary blended sustainable geopolymer mortar”, Constr. Build. Mater., 2017, 144: 608-623.
- [34]. Firdous, R., Stephan, D. and Djobo, J. N. Y., “Natural pozzolan based geopolymers: A review on mechanical, microstructural and durability characteristics”, Constr. Build. Mater., 2018, 190: 1251-1263.
- [35]. Liebig, E. and Althaus, E., “Pozzolanic activity of volcanic tuff and suevite: Effects of calcination”, Cem. Concr. Res., 1998, 28: 567-575.
- [36]. Türkmenoğlu, A. G. and Tankut, A., “Use of tuffs from central Turkey as admixture in pozzolanic cements: Assessment of their petrographical properties”, Cem. Concr. Res., 2002, 32: 629-637.
- [37]. Çelik, M. Y. and Sabah, E., “Geological and technical characterisation of Iscehisar (Afyon-Turkey) marble deposits and the impact of marble waste on environmental pollution”, J. Environ. Manage., 2008, 87: 106-116.
- [38]. Tekin, I., “Properties of NaOH activated geopolymer with marble, travertine and volcanic tuff wastes”, Constr. Build. Mater., 2016, 127: 607-617.
- [39]. Arel, H. Ş., “Recyclability of waste marble in concrete production”, J. Clean. Prod., 2016, 131: 179-188.
- [40]. Lim YY, Pham TM, Kumar J., “Sustainable alkali activated concrete with fly ash and waste marble aggregates: Strength and Durability studies”, Constr. and Build. Mater., 2021, 283:122795.
- [41]. Tammam Y, Uysal M, Canpolat O, Kuranlı ÖF., “Effect of Waste Filler Materials and Recycled Waste Aggregates on the Production of Geopolymer Composites”, Arab J Sci Eng., 2022 Sep 9:1-8.
- [42]. Altun, N. E., “Assessment of marble waste utilization as an alternative sorbent to limestone for SO2 control”, Fuel Process. Technol., 2014, 128: 461-470.
- [43]. Xu, H. and van Deventer, J. S. J., “The geopolymerisation of alumino-silicate minerals”, Int. J. Miner. Process, 2000, 59: 247-266.
- [44]. de Vargas, A. S., Dal Molin, D. C. C., Masuero, Â. B., Vilela, A. C. F., Castro-Gomes, J. and de Gutierrez, R. M., “Strength development of alkali-activated fly ash produced with combined NaOH and Ca(OH)2 activators”, Cem. Concr. Compos., 2014, 53: 341-349.
- [45]. Villa, C., Pecina, E. T., Torres, R. and Gómez, L., “Geopolymer synthesis using alkaline activation of natural zeolite”, Constr. Build. Mater., 2010, 24: 2084-2090.
- [46]. Pekgöz, M., Tekin, İ., “The effects of different origins NaOH on the mechanical and microstructural properties of tuff-based alkali-activated pastes”, Turkish Journal of Engineering Research and Education, 2022, 1: 29-37.
- [47]. Djobo, J. N. Y., Elimbi, A., Tchakouté, H. K. and Kumar, S., “Mechanical properties and durability of volcanic ash based geopolymer mortars”, Constr. Build. Mater., 2016, 124: 606-614.
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- [49]. ASTM C191-13, Standard Test Methods for Time of Setting of Hydraulic Cement by Vicat NeedleASTM International, West Conshohocken, PA, (2018).
- [50]. ASTM C109/C109M-02, Standard Test Method for Compressive Strength of Hydraulic Cement Mortars (Using 2-in. or (50-mm) Cube Specimens)ASTM International, West Conshohocken, PA, (2017).
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