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Chemical Migration from Plastic Types of Food Contact Materials

Year 2017, Volume: 1 Issue: 1, 22 - 32, 30.08.2017

Abstract

Foods are exposed to contact
materials during all steps passed from farm to fork. Regulation (EC) No
1935/2004 was set in the European Union (EU) to provide safe FCMs and to
explain the general requirements of the materials. Plastic materials and
articles intended to come into contact with food are regulated by Commission
Regulation (EU) No 10/2011. Annex I of Commission Regulation (EU) No 10/2011
contains the Union list of authorized monomers, additives, polymer production
and other starting substances. There are 885 authorized food contact material
substances in the list. These listed substances called as “Intentionally Added Substances (IAS)” can be used to manufacture
plastic materials, with the restrictions and specifications established in the
list. The contamination of foods due to the release of chemicals from packaging
materials can be originated from the substances used in their formulation  (IAS) but also from interactions between
different ingredients, degradation products or from the presence of impurities
in the raw materials (so called “Non
Intentionally Added Substances-NIAS”).
The components from food contact materials must not migrate
into the foods in unacceptable quantities. Therefore, substances used in the
manufacture of FCMs are regulated with maximum limits that may migrate into
foodstuffs without causing any health concerns. There are two migration limit
set for plastic based materials and articles: Overall Migration Limit and Specific
Migration Limit
(SML). SML are set for individual authorized substances
based on toxicological evaluation. In the scope of this study, plastic type of
food contact materials are classified, and migration concept is explained, the
regulations about FCMs and analysis method on chemicals migrated are reviewed.



 

References

  • Arvanitoyanni I.S., Kotsanopoulos K.V. 2014. Migration phenomenon in food packaging, food–package interactions, mechanisms, types of migrants, testing and relative legislation—a review, Food Bioprocess Technol., 7:21–36.
  • Bach C., Dauchy X., Severin I., Munoz J.F., Etienne S., Chagnon M.C. 2013. Effect of temperature on the release of intentionally and non-intentionally added substances from polyethylene terephthalate (PET) bottles into water: Chemical analysis and potential toxicity, Food Chemistry, 139: 672–680.
  • Biedermann-Brem S.,Grob K.,Fjeldal P. 2008. Release of bisphenol A from polycarbonate baby bottles: mechanisms of formation and investigation of worst case scenarios, European Food Research and Technology, 227: 1053-1060.
  • Brede C., Fjeldal P., Skjevrak I., & Herikstad H. 2003. Increased migration levels of bisphenol A from polycarbonate baby bottles after dishwashing, boiling and brushing, Food Additives and Contaminants, 20(7): 684-689.
  • Carneado S., Hernбndez-Nataren E., Lуpez-Sбnchez J.F., Sahuquillo A. 2016.,Migration of antimony from polyethylene terephthalate used in mineral water bottles, Food Chemistry, 166:544–550.
  • Chapa-Martínez C.A., Hinojosa-Reyes L., Hernández-Ramírez A., Ruiz-Ruiz E., Maya Treviño L., Guzmán-Mar J.L. 2016, An evaluation of the migration of antimony from polyethylene terephthalate (PET) plastic used for bottled drinking water, Science of the Total Environment, 565: 511–518.
  • Çinibulak P. 2010. Gıda Ambalajlarında Migrasyon, Yüksek Lisans Tezi, Namık Kemal Üniversitesi Fen Bilimleri Enstitüsü, Tekirdağ, 2010.
  • Commission Regulation (EU) No 10/2011 of 14 January 2011 on Plastic Materials and Articles İntended to Come into Contact with Food.
  • Dąrowska A., Borcz A. & Nawrocki J. 2003. Aldehyde contamination of mineral water stored in PET bottles, Food Additives & Contaminants, 20(12):1170-1177.
  • Driscoll R.H. & Rahman M.S. 2007. Types of packaging materials used for foods, in Handbook of Food Engineering, 2rd ed, D.R. Heldman and D.B. Lund (ed), Taylor and Francis, pp.917-938.
  • Driscoll R.H., Rahman M.S. 2007. Types of packaging materials used for foods, in M.S. Rahman (ed). Handbook of food preservation, 2nd ed., CRC Press, Baco Racon, pp.919-938.
  • Ehlert K.A., Beumer C.W.E, & Groot M.C.E. 2008. Migration of bisphenol A into water from polycarbonate baby bottles during microwave heating. Food Additives and Contaminants, 25(7): 904-910.
  • EN 1186-1:2002 Part 1: Guide to the Selection of Conditions and test methods for Overall Migration
  • EN 1186-10:2002 Part 10: Test methods for Overall Migration into Olive Oil (modified method for use in cases where incomplete extraction of olive oil occurs)
  • EN 1186-11:2002 Part 11: Test methods for Overall Migration into Mixtures of C- Labelled Synthetic Triglycerides
  • EN 1186-12:2002 Part 12: Test methods for Overall Migration at Low Temperatures
  • EN 1186-13:2002 Part 13: Test methods for Overall Migration at High Temperatures
  • EN 1186-14:2002 Part 14: Test methods for ‘Substitute tests’ for Overall Migration from Plastics İntended to Come into Contact with Fatty Foodstuffs using test Media İso-Octane and 95% Ethanol
  • EN 1186-15:2002 Part 15: Alternative test methods to Migration into Fatty Food Simulants by Rapid Extraction into İso-Octane and/ or 95% Ethanol.
  • EN 1186-2:2002 Part 2: Test methods for Overall Migration into Olive Oil by Total Immersion
  • EN 1186-3:2002 Part 3: Test methods for Overall Migration into Aqueous food Simulants by Total İmmersion
  • EN 1186-4:2002 Part 4: Test methods for Overall Migration into Olive Oil by Cell
  • EN 1186-5:2002 Part 5: Test methods for Overall Migration into Aqueous Food Simulants by Cell
  • EN 1186-6:2002 Part 6: Test methods for Overall Migration into Olive Oil using a Pouch
  • EN 1186-7:2002 Part 7: Test methods for Overall Migration into Aqueous Food Simulants Using a Pouch
  • EN 1186-8:2002 Part 8: Test methods for Overall Migration into Olive Oil by Article Filling
  • EN 1186-9:2002 Part 9: Test methods for Overall Migration into Aqueous Food Simulants by Article Filling
  • EN 13130-1:2004 Materials and Articles in Contact with Foodstuffs — Plastics Substances Subject to Limitation. Part 1: Guide to test methods for the Specific Migration of Substances from Plastics to Foods and Food Simulants and the Determination of Substances in Plastics and the Selection of Conditions of Exposure to Food Stimulants
  • European Commission (EC) 2004. Regulation (EC) No 1935/2004 of the European Parliament and of the Council of 27 October 2004 on materials and Articles Intended to Come into Contact with Food and Repealing Directives 80/590/EEC and 89/109/EEC.
  • European Commission (EC) 2011. Commission Regulation (EU) No 10/2011 of 14 January 2011 on Plastic Materials and Articles İntended to Come into Contact with Food.
  • Fang H., Wang J., Lynch R.A. 2017. Migration of di(2-ethylhexyl)phthalate (DEHP) and di-nbutylphthalate (DBP) from polypropylene food containers, Food Control, 73: 1298-1302.
  • Guart A., Bono-Blay F., Borrell A., Lacorte S. 2014. Effect of bottling and storage on the migration of plastic constituents in Spanish bottled waters, Food Chemistry, 156: 73–80.
  • Heimrich M., Bönsch M., Nickl H., Simat T.J. 2012. Cyclic oligomers in polyamide for food contact material: quantification by HPLC‐CLND and single‐substance calibration, Food Additives and Contaminants., 29(5):846–860.
  • Heimrich M., Nickl H., Bönsch M. and Simat T.J. 2013. Migration of cyclic monomer and oligomers from polyamide 6 and 66 food contact materials into food and food simulants: direct food contact, Packag. Technol. Sci., 28: 123–139.
  • Kassouf A., Maalouly J., Chebib H., Rutledge D.N., Ducruet V. 2013. Chemometric tools to highlight non-intentionally added substances (NIAS) in polyethylene terephthalate (PET), Talanta, 115:928–937.
  • Krochta J.M. 2007. Food Packaging, in Handbook of Food Engineering, 2rd ed, D.R. Heldman and D.B. Lund (ed), Taylor and Francis.
  • Kubwabo C., Kosarac I., Stewart B., Gauthier B.R., Lalonde K., and Lalonde P.J. 2009. Migration of bisphenol A from plastic baby bottles, baby bottle liners and reusable polycarbonate drinking bottles. Food Additives and Contaminants, 26(6): 928-937.
  • Lau O.W., Wong S.K. 2000. Contamination in food from packaging material, J of Chromatography A, 882(1-2):255-270.
  • Lee D.S., Yam K.L., Piergiovanni L. 2008. Food Packaging Science and Technology, CRC Press.
  • Luciano P., Sara L. 2016. Food Packaging Materials, Springer International Publishing.
  • Marć M., Zabiegała B. 2017. An investigation of selected monoaromatic hydrocarbons released from the surface of polystyrene lids used in coffee-to-go cups, Microchemical Journal 11 : S0026-265X(17)30255-2.
  • Marsh K., Bugusu B. 2007. Food packaging—roles, materials, and environmental issues Journal of Food Science., 72(3):39-55.
  • Mieth A., Hoekstra E., Simoneau C. 2016. Guidance for the İdentification of Polymers in Multilayer Films Used in Food Contact Materials: User Guide of Selected Practices to Determine the Nature of Layers, JRC100835, Publications Office of the European Union.
  • Nakaia M., Tsubokuraa M., Suzukia M., Fujishimaa S., Watanabeb Y., Hasegawab Y., Oyamab K., Ogura S. 2014. Genotoxicity of styrene oligomers extracted frompolystyrene intended for use in contact with food ,Toxicology Reports, pp.1175–1180.
  • Ohno K., Azuma Y., Nakano S., Kobayashi T., Hirano S., Nobuhara Y., Yamada T. 2001. Assessment of styrene oligomers eluted from polystyrene-made food containers for estrogenic effects in in vitro assays, Food and Chemical Toxicology, 39: 1233–1241.
  • Regulation (EC) No 1935/2004 of The European Parliament and of the Council of 27 October 2004 on Materials and Articles İntended to Come into Contact with Food and Repealing Directives 80/590/EEC and 89/109/EEC.
  • Robertson G.L. 2012. Food packaging: Principles and Practices, 3rd ed, CRC Press.
  • Selke S. 2005. Food packaging: Plastics (Vol.3), in Handbook of Food Technology and Engineering, Y. Hui (ed), CRC Taylor & Francis, Boca Raton.
  • Simeneau C. 2008. Food Contact Materials (Chapter 21), in Comprehensive Analytical Chemistry. 1st ed., D. Barcelo (ed), Elsevier, Amsterdam.
  • Türk Gıda Kodeksi Gıda ile Temas Eden Plastik Madde ve Malzemeler Tebliği (No: 2013/34)
  • Türk Gıda Kodeksi Gıda İle Temas Eden Plastik Madde ve Malzemelerin Bileşenlerinin Migrasyon Testinde Kullanılan Gıda Benzerleri Listesi Tebliği (No: 2013/35)
  • Türk Gıda Kodeksi Gıda İle Temas Eden Seramik Malzemeler Tebliği (Tebliğ No: 2012/30)
  • Yang., Hu C., Zhong H., Chen X., Chen R., Yam K.L. 2016. Effects of ultraviolet (UV) on degradation of Irgafos 168 and migration of its degradation products from polypropylene films, J. Agric. Food Chem., 64(41):7866–7873.
Year 2017, Volume: 1 Issue: 1, 22 - 32, 30.08.2017

Abstract

References

  • Arvanitoyanni I.S., Kotsanopoulos K.V. 2014. Migration phenomenon in food packaging, food–package interactions, mechanisms, types of migrants, testing and relative legislation—a review, Food Bioprocess Technol., 7:21–36.
  • Bach C., Dauchy X., Severin I., Munoz J.F., Etienne S., Chagnon M.C. 2013. Effect of temperature on the release of intentionally and non-intentionally added substances from polyethylene terephthalate (PET) bottles into water: Chemical analysis and potential toxicity, Food Chemistry, 139: 672–680.
  • Biedermann-Brem S.,Grob K.,Fjeldal P. 2008. Release of bisphenol A from polycarbonate baby bottles: mechanisms of formation and investigation of worst case scenarios, European Food Research and Technology, 227: 1053-1060.
  • Brede C., Fjeldal P., Skjevrak I., & Herikstad H. 2003. Increased migration levels of bisphenol A from polycarbonate baby bottles after dishwashing, boiling and brushing, Food Additives and Contaminants, 20(7): 684-689.
  • Carneado S., Hernбndez-Nataren E., Lуpez-Sбnchez J.F., Sahuquillo A. 2016.,Migration of antimony from polyethylene terephthalate used in mineral water bottles, Food Chemistry, 166:544–550.
  • Chapa-Martínez C.A., Hinojosa-Reyes L., Hernández-Ramírez A., Ruiz-Ruiz E., Maya Treviño L., Guzmán-Mar J.L. 2016, An evaluation of the migration of antimony from polyethylene terephthalate (PET) plastic used for bottled drinking water, Science of the Total Environment, 565: 511–518.
  • Çinibulak P. 2010. Gıda Ambalajlarında Migrasyon, Yüksek Lisans Tezi, Namık Kemal Üniversitesi Fen Bilimleri Enstitüsü, Tekirdağ, 2010.
  • Commission Regulation (EU) No 10/2011 of 14 January 2011 on Plastic Materials and Articles İntended to Come into Contact with Food.
  • Dąrowska A., Borcz A. & Nawrocki J. 2003. Aldehyde contamination of mineral water stored in PET bottles, Food Additives & Contaminants, 20(12):1170-1177.
  • Driscoll R.H. & Rahman M.S. 2007. Types of packaging materials used for foods, in Handbook of Food Engineering, 2rd ed, D.R. Heldman and D.B. Lund (ed), Taylor and Francis, pp.917-938.
  • Driscoll R.H., Rahman M.S. 2007. Types of packaging materials used for foods, in M.S. Rahman (ed). Handbook of food preservation, 2nd ed., CRC Press, Baco Racon, pp.919-938.
  • Ehlert K.A., Beumer C.W.E, & Groot M.C.E. 2008. Migration of bisphenol A into water from polycarbonate baby bottles during microwave heating. Food Additives and Contaminants, 25(7): 904-910.
  • EN 1186-1:2002 Part 1: Guide to the Selection of Conditions and test methods for Overall Migration
  • EN 1186-10:2002 Part 10: Test methods for Overall Migration into Olive Oil (modified method for use in cases where incomplete extraction of olive oil occurs)
  • EN 1186-11:2002 Part 11: Test methods for Overall Migration into Mixtures of C- Labelled Synthetic Triglycerides
  • EN 1186-12:2002 Part 12: Test methods for Overall Migration at Low Temperatures
  • EN 1186-13:2002 Part 13: Test methods for Overall Migration at High Temperatures
  • EN 1186-14:2002 Part 14: Test methods for ‘Substitute tests’ for Overall Migration from Plastics İntended to Come into Contact with Fatty Foodstuffs using test Media İso-Octane and 95% Ethanol
  • EN 1186-15:2002 Part 15: Alternative test methods to Migration into Fatty Food Simulants by Rapid Extraction into İso-Octane and/ or 95% Ethanol.
  • EN 1186-2:2002 Part 2: Test methods for Overall Migration into Olive Oil by Total Immersion
  • EN 1186-3:2002 Part 3: Test methods for Overall Migration into Aqueous food Simulants by Total İmmersion
  • EN 1186-4:2002 Part 4: Test methods for Overall Migration into Olive Oil by Cell
  • EN 1186-5:2002 Part 5: Test methods for Overall Migration into Aqueous Food Simulants by Cell
  • EN 1186-6:2002 Part 6: Test methods for Overall Migration into Olive Oil using a Pouch
  • EN 1186-7:2002 Part 7: Test methods for Overall Migration into Aqueous Food Simulants Using a Pouch
  • EN 1186-8:2002 Part 8: Test methods for Overall Migration into Olive Oil by Article Filling
  • EN 1186-9:2002 Part 9: Test methods for Overall Migration into Aqueous Food Simulants by Article Filling
  • EN 13130-1:2004 Materials and Articles in Contact with Foodstuffs — Plastics Substances Subject to Limitation. Part 1: Guide to test methods for the Specific Migration of Substances from Plastics to Foods and Food Simulants and the Determination of Substances in Plastics and the Selection of Conditions of Exposure to Food Stimulants
  • European Commission (EC) 2004. Regulation (EC) No 1935/2004 of the European Parliament and of the Council of 27 October 2004 on materials and Articles Intended to Come into Contact with Food and Repealing Directives 80/590/EEC and 89/109/EEC.
  • European Commission (EC) 2011. Commission Regulation (EU) No 10/2011 of 14 January 2011 on Plastic Materials and Articles İntended to Come into Contact with Food.
  • Fang H., Wang J., Lynch R.A. 2017. Migration of di(2-ethylhexyl)phthalate (DEHP) and di-nbutylphthalate (DBP) from polypropylene food containers, Food Control, 73: 1298-1302.
  • Guart A., Bono-Blay F., Borrell A., Lacorte S. 2014. Effect of bottling and storage on the migration of plastic constituents in Spanish bottled waters, Food Chemistry, 156: 73–80.
  • Heimrich M., Bönsch M., Nickl H., Simat T.J. 2012. Cyclic oligomers in polyamide for food contact material: quantification by HPLC‐CLND and single‐substance calibration, Food Additives and Contaminants., 29(5):846–860.
  • Heimrich M., Nickl H., Bönsch M. and Simat T.J. 2013. Migration of cyclic monomer and oligomers from polyamide 6 and 66 food contact materials into food and food simulants: direct food contact, Packag. Technol. Sci., 28: 123–139.
  • Kassouf A., Maalouly J., Chebib H., Rutledge D.N., Ducruet V. 2013. Chemometric tools to highlight non-intentionally added substances (NIAS) in polyethylene terephthalate (PET), Talanta, 115:928–937.
  • Krochta J.M. 2007. Food Packaging, in Handbook of Food Engineering, 2rd ed, D.R. Heldman and D.B. Lund (ed), Taylor and Francis.
  • Kubwabo C., Kosarac I., Stewart B., Gauthier B.R., Lalonde K., and Lalonde P.J. 2009. Migration of bisphenol A from plastic baby bottles, baby bottle liners and reusable polycarbonate drinking bottles. Food Additives and Contaminants, 26(6): 928-937.
  • Lau O.W., Wong S.K. 2000. Contamination in food from packaging material, J of Chromatography A, 882(1-2):255-270.
  • Lee D.S., Yam K.L., Piergiovanni L. 2008. Food Packaging Science and Technology, CRC Press.
  • Luciano P., Sara L. 2016. Food Packaging Materials, Springer International Publishing.
  • Marć M., Zabiegała B. 2017. An investigation of selected monoaromatic hydrocarbons released from the surface of polystyrene lids used in coffee-to-go cups, Microchemical Journal 11 : S0026-265X(17)30255-2.
  • Marsh K., Bugusu B. 2007. Food packaging—roles, materials, and environmental issues Journal of Food Science., 72(3):39-55.
  • Mieth A., Hoekstra E., Simoneau C. 2016. Guidance for the İdentification of Polymers in Multilayer Films Used in Food Contact Materials: User Guide of Selected Practices to Determine the Nature of Layers, JRC100835, Publications Office of the European Union.
  • Nakaia M., Tsubokuraa M., Suzukia M., Fujishimaa S., Watanabeb Y., Hasegawab Y., Oyamab K., Ogura S. 2014. Genotoxicity of styrene oligomers extracted frompolystyrene intended for use in contact with food ,Toxicology Reports, pp.1175–1180.
  • Ohno K., Azuma Y., Nakano S., Kobayashi T., Hirano S., Nobuhara Y., Yamada T. 2001. Assessment of styrene oligomers eluted from polystyrene-made food containers for estrogenic effects in in vitro assays, Food and Chemical Toxicology, 39: 1233–1241.
  • Regulation (EC) No 1935/2004 of The European Parliament and of the Council of 27 October 2004 on Materials and Articles İntended to Come into Contact with Food and Repealing Directives 80/590/EEC and 89/109/EEC.
  • Robertson G.L. 2012. Food packaging: Principles and Practices, 3rd ed, CRC Press.
  • Selke S. 2005. Food packaging: Plastics (Vol.3), in Handbook of Food Technology and Engineering, Y. Hui (ed), CRC Taylor & Francis, Boca Raton.
  • Simeneau C. 2008. Food Contact Materials (Chapter 21), in Comprehensive Analytical Chemistry. 1st ed., D. Barcelo (ed), Elsevier, Amsterdam.
  • Türk Gıda Kodeksi Gıda ile Temas Eden Plastik Madde ve Malzemeler Tebliği (No: 2013/34)
  • Türk Gıda Kodeksi Gıda İle Temas Eden Plastik Madde ve Malzemelerin Bileşenlerinin Migrasyon Testinde Kullanılan Gıda Benzerleri Listesi Tebliği (No: 2013/35)
  • Türk Gıda Kodeksi Gıda İle Temas Eden Seramik Malzemeler Tebliği (Tebliğ No: 2012/30)
  • Yang., Hu C., Zhong H., Chen X., Chen R., Yam K.L. 2016. Effects of ultraviolet (UV) on degradation of Irgafos 168 and migration of its degradation products from polypropylene films, J. Agric. Food Chem., 64(41):7866–7873.
There are 53 citations in total.

Details

Primary Language English
Journal Section Article
Authors

Perihan Yolcı Omeroğlu

Tuğba Özdal This is me

Rüya Bulut This is me

Publication Date August 30, 2017
Published in Issue Year 2017 Volume: 1 Issue: 1

Cite

APA Yolcı Omeroğlu, P., Özdal, T., & Bulut, R. (2017). Chemical Migration from Plastic Types of Food Contact Materials. Eurasian Journal of Food Science and Technology, 1(1), 22-32.
AMA Yolcı Omeroğlu P, Özdal T, Bulut R. Chemical Migration from Plastic Types of Food Contact Materials. EJFST. August 2017;1(1):22-32.
Chicago Yolcı Omeroğlu, Perihan, Tuğba Özdal, and Rüya Bulut. “Chemical Migration from Plastic Types of Food Contact Materials”. Eurasian Journal of Food Science and Technology 1, no. 1 (August 2017): 22-32.
EndNote Yolcı Omeroğlu P, Özdal T, Bulut R (August 1, 2017) Chemical Migration from Plastic Types of Food Contact Materials. Eurasian Journal of Food Science and Technology 1 1 22–32.
IEEE P. Yolcı Omeroğlu, T. Özdal, and R. Bulut, “Chemical Migration from Plastic Types of Food Contact Materials”, EJFST, vol. 1, no. 1, pp. 22–32, 2017.
ISNAD Yolcı Omeroğlu, Perihan et al. “Chemical Migration from Plastic Types of Food Contact Materials”. Eurasian Journal of Food Science and Technology 1/1 (August 2017), 22-32.
JAMA Yolcı Omeroğlu P, Özdal T, Bulut R. Chemical Migration from Plastic Types of Food Contact Materials. EJFST. 2017;1:22–32.
MLA Yolcı Omeroğlu, Perihan et al. “Chemical Migration from Plastic Types of Food Contact Materials”. Eurasian Journal of Food Science and Technology, vol. 1, no. 1, 2017, pp. 22-32.
Vancouver Yolcı Omeroğlu P, Özdal T, Bulut R. Chemical Migration from Plastic Types of Food Contact Materials. EJFST. 2017;1(1):22-3.

Eurasian Journal of Food Science and Technology (EJFST)   e-ISSN: 2667-4890   Web: https://dergipark.org.tr/en/pub/ejfst   e-mail: foodsciencejournal@gmail.com