Akıllı Malzemelerin Hazırlanmasında Kullanılacak Amin Türevi Monomerlerin Sentez ve Karakterizasyonu

Year 2019, Issue: 16, 242 - 246, 31.08.2019

Yeliz Ulaş

https://doi.org/10.31590/ejosat.558597

Cited By: 2

Abstract

Bu çalışmada; polimerleşme ve
metal kompleksi oluşturabilme özelliklerine sahip amin türevi; üç yeni monomer sentezlenmiştir.
 Sentez reaksiyonu olarak, petasis
reaksiyonu seçilmiştir. Uygun optimizasyon koşullarında, herhangi bir katalizör
kullanılmadan ve oldukça yüksek verimlerle hedef ürünler(monomer) elde
edilmiştir. Reaksiyon verimine; sıcaklık, çözücü, atmosfer koşullarının yanısıra,
substitüentlerin de etkili olduğu görülmüştür. Özellikle elektron salıcı
substitüent içeren yapıların elektron çekici substitüent içeren bileşiklere göre
daha istemli olduğu ve veriminin de yüksek olduğu görülmüştür. Alkilaminofenol
bileşik sınıfına ait olan bu monomerlerin yapısal analizleri ise ¹H-NMR
ve ¹³C-NMR ile tamamlanmıştır. Sentezi yapılan monomerler, moleküler
baskılanmış polimer olarak biyomoleküler tanımada kullanılabilir. Bu durum; bir
çok hedef molekül için onları tanıyan uygun materyallerin  elde edilmesi anlamına gelmektedir. Çalışma
bu yönüyle oldukça önemlidir. 

Keywords

Moleküler Baskılanmış Polimerler, Alkilaminofenol, Petasis Reaksiyonu, Akıllı Malzemeler

Supporting Institution

Bursa Uludağ Üniversitesi Bilimsel Araştırma Projeleri Birimi

Project Number

ÖAP(F)-2018/2

Thanks

Bu çalışma Bursa Uludağ Üniversitesi Bilimsel Araştırma Projeleri Birimi tarafından ÖAP(F)-2018/2 nolu proje ile desteklenmiştir.

Synthesis and Characterization of Amine Derivative Monomers to be used in Preparing Smart Materials

Abstract

In this study, amine derivative three new monomers forming polymer and metal complex synthesized. As the synthesis reaction, the petasis reaction was chosen. Under optimization conditions, target products (monomer) were obtained without any catalyst and with very high yields. Some parameters, such as temperature, solvent, atmospheric conditions, and substituents, has affected reaction yields.In particular, it observed that the structures containing the electron release substituent were more eager than the compounds containing the electron acceptor and the yield was high. Structural analyses of monomers of the alkylaminophenol class were made with 1H-NMR and 13C-NMR. The synthesized monomers can use as molecular printed polymers in biomolecular recognition. That means to obtain suitable materials for synthesized of target molecules. Therefore, this aspect of the study is important.

Keywords

Molecular Imprinted Polymers, Alkylaminophenol, Petasis Reaction, smart materials, monomer

Project Number

ÖAP(F)-2018/2

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