Research Article
BibTex RIS Cite

Leakage-Free Wood-Derived Activated Carbon/Methyl Palmitate Composite Phase Change Material for Thermal Management Applications

Year 2023, , 197 - 201, 31.12.2023
https://doi.org/10.36222/ejt.1293404

Abstract

This study aimed to create a leakage-free composite phase change material (PCM) that has high potential for various thermal management applications. Activated carbon derived from wood (ACW) with a porous structure was used to address the leakage issue and improve the thermal conductivity of Methyl palmitate (MPt) used as the PCM. The optimum MPt impregnation ratio was found to be 53 wt% in the leakage-free ACW/MPt composite. The results of FTIR analysis showed that the integration of MPt and ACW was achieved through physical interaction. Scanning electron microscopy (SEM) analysis indicated that MPt was uniformly distributed within pores of the ACW scaffold. DSC analyses demonstrated that the fusion enthalpy and temperature of the ACW/MPt (53 wt%) were 129 J/g and 27.59 °C, respectively. Thermal gravimetric analysis (TGA) measurements confirmed that the ACW/MPt was thermally stable. By incorporating MPt with ACW, thermal conductivity of MPt was increased by 2.16 times. The fusion enthalpy of ACW/MPt did not change, and the melting temperature remained constant after 750 thermal cycles. The results of this study indicate that the fabricated leak-free ACW/MPt is cost-effective and environmentally friendly and has the potential to be utilized as a thermal energy storage (TES) material for temperature regulation in various applications.

References

  • [1] F. Kuznik et al., “A review on phase change materials integrated in building walls’’, Renewable and Sustainable Energy Reviews, vol. 15, no. 1, pp. 379–391, 2011, doi: 10.1016/j.rser.2010.08.019ï.
  • [2] I. Sarbu and C. Sebarchievici, “A Comprehensive Review of Thermal Energy Storage,” Sustainability, vol. 10, no. 1, p. 191, Jan. 2018, doi: 10.3390/SU10010191.
  • [3] A. Sharma, V. V. Tyagi, C. R. Chen, and D. Buddhi, “Review on thermal energy storage with phase change materials and applications,” Renewable and Sustainable Energy Reviews, vol. 13, no. 2, pp. 318–345, Feb. 2009, doi: 10.1016/J.RSER.2007.10.005.
  • [4] S. Wu, T. Yan, Z. Kuai, and W. Pan, “Thermal conductivity enhancement on phase change materials for thermal energy storage: A review,” Energy Storage Mater, vol. 25, pp. 251–295, Mar. 2020, doi: 10.1016/j.ensm.2019.10.010.
  • [5] Y. Zhang, Z. Jia, A. Moqeet Hai, S. Zhang, and B. Tang, “Shape-stabilization micromechanisms of form-stable phase change materials-A review,” Compos Part A Appl Sci Manuf, vol. 160, p. 107047, Sep. 2022, doi: 10.1016/j.compositesa.2022.107047.
  • [6] P. Lv, C. Liu, and Z. Rao, “Review on clay mineral-based form-stable phase change materials: Preparation, characterization and applications,” Renewable and Sustainable Energy Reviews, vol. 68, pp. 707–726, Feb. 2017, doi: 10.1016/j.rser.2016.10.014.
  • [7] M. M. Kenisarin and K. M. Kenisarina, “Form-stable phase change materials for thermal energy storage,” Renewable and Sustainable Energy Reviews, vol. 16, no. 4, pp. 1999–2040, May 2012, doi: 10.1016/j.rser.2012.01.015.
  • [8] J. Paul et al., “Nano-enhanced organic form stable PCMs for medium temperature solar thermal energy harvesting: Recent progresses, challenges, and opportunities,” Renewable and Sustainable Energy Reviews, vol. 161, p. 112321, Jun. 2022, doi: 10.1016/J.RSER.2022.112321.
  • [9] S. Rostami et al., “A review of melting and freezing processes of PCM/nano-PCM and their application in energy storage,” Energy, vol. 211, p. 118698, Nov. 2020, doi: 10.1016/J.ENERGY.2020.118698.
  • [10] X. Huang, C. Zhu, Y. Lin, and G. Fang, “Thermal properties and applications of microencapsulated PCM for thermal energy storage: A review,” Appl Therm Eng, vol. 147, pp. 841–855, Jan. 2019, doi: 10.1016/J.APPLTHERMALENG.2018.11.007.
  • [11] P. K. S. Rathore and S. kumar Shukla, “Improvement in thermal properties of PCM/Expanded vermiculite/expanded graphite shape stabilized composite PCM for building energy applications,” Renew Energy, vol. 176, pp. 295–304, Oct. 2021, doi: 10.1016/j.renene.2021.05.068.
  • [12] L. Yang, J. Huang, and F. Zhou, “Thermophysical properties and applications of nano-enhanced PCMs: An update review,” Energy Convers Manag, vol. 214, p. 112876, Jun. 2020, doi: 10.1016/j.enconman.2020.112876.
  • [13] D. G. Atinafu, B. Y. Yun, S. Wi, Y. Kang, and S. Kim, “A comparative analysis of biochar, activated carbon, expanded graphite, and multi-walled carbon nanotubes with respect to PCM loading and energy-storage capacities,” Environ Res, vol. 195, no. February, p. 110853, 2021, doi: 10.1016/j.envres.2021.110853.
  • [14] A. F. Nicholas, M. Z. Hussein, Z. Zainal, and T. Khadiran, “Palm kernel shell activated carbon as an inorganic framework for shape-stabilized phase change material,” Nanomaterials, 2018, doi: 10.3390/nano8090689.
  • [15] G. Hekimoğlu, A. Sarı, Y. Önal, O. Gencel, V. V. Tyagi, and E. Aslan, “Utilization of waste apricot kernel shell derived-activated carbon as carrier framework for effective shape-stabilization and thermal conductivity enhancement of organic phase change materials used for thermal energy storage,” Powder Technol, vol. 401, p. 117291, Mar. 2022, doi: 10.1016/J.POWTEC.2022.117291.
  • [16] X. Gu, P. Liu, C. Liu, L. Peng, and H. He, “A novel form-stable phase change material of palmitic acid-carbonized pepper straw for thermal energy storage,” Mater Lett, 2019, doi: 10.1016/j.matlet.2019.03.130.
  • [17] W. Zhang et al., “Lauric-stearic acid eutectic mixture/carbonized biomass waste corn cob composite phase change materials: Preparation and thermal characterization,” Thermochim Acta, vol. 674, pp. 21–27, Apr. 2019, doi: 10.1016/J.TCA.2019.01.022.
  • [18] Y. Xu et al., “Preparation and performance of shape-stable phase change materials based on carbonized-abandoned orange peel and paraffin,” vol. 27, no. 4, pp. 289–298, Apr. 2019, doi: 10.1080/1536383X.2018.1543279.
  • [19] R. Wen, W. Zhang, Z. Lv, Z. Huang, and W. Gao, “A novel composite Phase change material of Stearic Acid/Carbonized sunflower straw for thermal energy storage,” Mater Lett, 2018, doi: 10.1016/j.matlet.2017.12.008.
  • [20] H. Yang et al., “Low-cost, three-dimension, high thermal conductivity, carbonized wood-based composite phase change materials for thermal energy storage,” Energy, vol. 159, pp. 929–936, Sep. 2018, doi: 10.1016/J.ENERGY.2018.06.207.
  • [21] Z. Yang, Y. Deng, and J. Li, “Preparation of porous carbonized woods impregnated with lauric acid as shape-stable composite phase change materials,” Appl Therm Eng, 2019, doi: 10.1016/j.applthermaleng.2019.01.063.
  • [22] Y. Wan et al., “A promising form-stable phase change material prepared using cost effective pinecone biochar as the matrix of palmitic acid for thermal energy storage,” Sci Rep, vol. 9, no. 1, p. 11535, Dec. 2019, doi: 10.1038/s41598-019-47877-z.
  • [23] G. Hekimoğlu et al., “Walnut shell derived bio-carbon/methyl palmitate as novel composite phase change material with enhanced thermal energy storage properties,” J Energy Storage, vol. 35, p. 102288, Mar. 2021, doi: 10.1016/j.est.2021.102288.
  • [24] L. Feng, J. Zheng, H. Yang, Y. Guo, W. Li, and X. Li, “Preparation and characterization of polyethylene glycol/active carbon composites as shape-stabilized phase change materials,” Sol Energy Mater Sol Cells, vol. 95, no. 2, pp. 644-650, Feb. 2011, doi: 10.1016/j.solmat.2010.09.033.
  • [25] G. Hekimoğlu, A. Sarı, S. Arunachalam, H. Arslanoğlu, and O. Gencel, “Porous biochar/heptadecane composite phase change material with leak-proof, high thermal energy storage capacity and enhanced thermal conductivity,” Powder Technol, vol. 394, pp. 1017–1025, Dec. 2021, doi: 10.1016/j.powtec.2021.09.030.
  • [26] L. Feng, J. Zheng, H. Yang, Y. Guo, W. Li, and X. Li, “Cost-Effective Biochar Produced from Agricultural Residues and Its Application for Preparation of High Performance Form-Stable Phase Change Material via Simple Method,” Int J Mol Sci, vol. 19, no. 10, p. 3055, Oct. 2018, doi: 10.3390/ijms19103055
Year 2023, , 197 - 201, 31.12.2023
https://doi.org/10.36222/ejt.1293404

Abstract

References

  • [1] F. Kuznik et al., “A review on phase change materials integrated in building walls’’, Renewable and Sustainable Energy Reviews, vol. 15, no. 1, pp. 379–391, 2011, doi: 10.1016/j.rser.2010.08.019ï.
  • [2] I. Sarbu and C. Sebarchievici, “A Comprehensive Review of Thermal Energy Storage,” Sustainability, vol. 10, no. 1, p. 191, Jan. 2018, doi: 10.3390/SU10010191.
  • [3] A. Sharma, V. V. Tyagi, C. R. Chen, and D. Buddhi, “Review on thermal energy storage with phase change materials and applications,” Renewable and Sustainable Energy Reviews, vol. 13, no. 2, pp. 318–345, Feb. 2009, doi: 10.1016/J.RSER.2007.10.005.
  • [4] S. Wu, T. Yan, Z. Kuai, and W. Pan, “Thermal conductivity enhancement on phase change materials for thermal energy storage: A review,” Energy Storage Mater, vol. 25, pp. 251–295, Mar. 2020, doi: 10.1016/j.ensm.2019.10.010.
  • [5] Y. Zhang, Z. Jia, A. Moqeet Hai, S. Zhang, and B. Tang, “Shape-stabilization micromechanisms of form-stable phase change materials-A review,” Compos Part A Appl Sci Manuf, vol. 160, p. 107047, Sep. 2022, doi: 10.1016/j.compositesa.2022.107047.
  • [6] P. Lv, C. Liu, and Z. Rao, “Review on clay mineral-based form-stable phase change materials: Preparation, characterization and applications,” Renewable and Sustainable Energy Reviews, vol. 68, pp. 707–726, Feb. 2017, doi: 10.1016/j.rser.2016.10.014.
  • [7] M. M. Kenisarin and K. M. Kenisarina, “Form-stable phase change materials for thermal energy storage,” Renewable and Sustainable Energy Reviews, vol. 16, no. 4, pp. 1999–2040, May 2012, doi: 10.1016/j.rser.2012.01.015.
  • [8] J. Paul et al., “Nano-enhanced organic form stable PCMs for medium temperature solar thermal energy harvesting: Recent progresses, challenges, and opportunities,” Renewable and Sustainable Energy Reviews, vol. 161, p. 112321, Jun. 2022, doi: 10.1016/J.RSER.2022.112321.
  • [9] S. Rostami et al., “A review of melting and freezing processes of PCM/nano-PCM and their application in energy storage,” Energy, vol. 211, p. 118698, Nov. 2020, doi: 10.1016/J.ENERGY.2020.118698.
  • [10] X. Huang, C. Zhu, Y. Lin, and G. Fang, “Thermal properties and applications of microencapsulated PCM for thermal energy storage: A review,” Appl Therm Eng, vol. 147, pp. 841–855, Jan. 2019, doi: 10.1016/J.APPLTHERMALENG.2018.11.007.
  • [11] P. K. S. Rathore and S. kumar Shukla, “Improvement in thermal properties of PCM/Expanded vermiculite/expanded graphite shape stabilized composite PCM for building energy applications,” Renew Energy, vol. 176, pp. 295–304, Oct. 2021, doi: 10.1016/j.renene.2021.05.068.
  • [12] L. Yang, J. Huang, and F. Zhou, “Thermophysical properties and applications of nano-enhanced PCMs: An update review,” Energy Convers Manag, vol. 214, p. 112876, Jun. 2020, doi: 10.1016/j.enconman.2020.112876.
  • [13] D. G. Atinafu, B. Y. Yun, S. Wi, Y. Kang, and S. Kim, “A comparative analysis of biochar, activated carbon, expanded graphite, and multi-walled carbon nanotubes with respect to PCM loading and energy-storage capacities,” Environ Res, vol. 195, no. February, p. 110853, 2021, doi: 10.1016/j.envres.2021.110853.
  • [14] A. F. Nicholas, M. Z. Hussein, Z. Zainal, and T. Khadiran, “Palm kernel shell activated carbon as an inorganic framework for shape-stabilized phase change material,” Nanomaterials, 2018, doi: 10.3390/nano8090689.
  • [15] G. Hekimoğlu, A. Sarı, Y. Önal, O. Gencel, V. V. Tyagi, and E. Aslan, “Utilization of waste apricot kernel shell derived-activated carbon as carrier framework for effective shape-stabilization and thermal conductivity enhancement of organic phase change materials used for thermal energy storage,” Powder Technol, vol. 401, p. 117291, Mar. 2022, doi: 10.1016/J.POWTEC.2022.117291.
  • [16] X. Gu, P. Liu, C. Liu, L. Peng, and H. He, “A novel form-stable phase change material of palmitic acid-carbonized pepper straw for thermal energy storage,” Mater Lett, 2019, doi: 10.1016/j.matlet.2019.03.130.
  • [17] W. Zhang et al., “Lauric-stearic acid eutectic mixture/carbonized biomass waste corn cob composite phase change materials: Preparation and thermal characterization,” Thermochim Acta, vol. 674, pp. 21–27, Apr. 2019, doi: 10.1016/J.TCA.2019.01.022.
  • [18] Y. Xu et al., “Preparation and performance of shape-stable phase change materials based on carbonized-abandoned orange peel and paraffin,” vol. 27, no. 4, pp. 289–298, Apr. 2019, doi: 10.1080/1536383X.2018.1543279.
  • [19] R. Wen, W. Zhang, Z. Lv, Z. Huang, and W. Gao, “A novel composite Phase change material of Stearic Acid/Carbonized sunflower straw for thermal energy storage,” Mater Lett, 2018, doi: 10.1016/j.matlet.2017.12.008.
  • [20] H. Yang et al., “Low-cost, three-dimension, high thermal conductivity, carbonized wood-based composite phase change materials for thermal energy storage,” Energy, vol. 159, pp. 929–936, Sep. 2018, doi: 10.1016/J.ENERGY.2018.06.207.
  • [21] Z. Yang, Y. Deng, and J. Li, “Preparation of porous carbonized woods impregnated with lauric acid as shape-stable composite phase change materials,” Appl Therm Eng, 2019, doi: 10.1016/j.applthermaleng.2019.01.063.
  • [22] Y. Wan et al., “A promising form-stable phase change material prepared using cost effective pinecone biochar as the matrix of palmitic acid for thermal energy storage,” Sci Rep, vol. 9, no. 1, p. 11535, Dec. 2019, doi: 10.1038/s41598-019-47877-z.
  • [23] G. Hekimoğlu et al., “Walnut shell derived bio-carbon/methyl palmitate as novel composite phase change material with enhanced thermal energy storage properties,” J Energy Storage, vol. 35, p. 102288, Mar. 2021, doi: 10.1016/j.est.2021.102288.
  • [24] L. Feng, J. Zheng, H. Yang, Y. Guo, W. Li, and X. Li, “Preparation and characterization of polyethylene glycol/active carbon composites as shape-stabilized phase change materials,” Sol Energy Mater Sol Cells, vol. 95, no. 2, pp. 644-650, Feb. 2011, doi: 10.1016/j.solmat.2010.09.033.
  • [25] G. Hekimoğlu, A. Sarı, S. Arunachalam, H. Arslanoğlu, and O. Gencel, “Porous biochar/heptadecane composite phase change material with leak-proof, high thermal energy storage capacity and enhanced thermal conductivity,” Powder Technol, vol. 394, pp. 1017–1025, Dec. 2021, doi: 10.1016/j.powtec.2021.09.030.
  • [26] L. Feng, J. Zheng, H. Yang, Y. Guo, W. Li, and X. Li, “Cost-Effective Biochar Produced from Agricultural Residues and Its Application for Preparation of High Performance Form-Stable Phase Change Material via Simple Method,” Int J Mol Sci, vol. 19, no. 10, p. 3055, Oct. 2018, doi: 10.3390/ijms19103055
There are 26 citations in total.

Details

Primary Language English
Subjects Material Production Technologies
Journal Section Research Article
Authors

Gökhan Hekimoğlu 0000-0002-0991-6897

Publication Date December 31, 2023
Published in Issue Year 2023

Cite

APA Hekimoğlu, G. (2023). Leakage-Free Wood-Derived Activated Carbon/Methyl Palmitate Composite Phase Change Material for Thermal Management Applications. European Journal of Technique (EJT), 13(2), 197-201. https://doi.org/10.36222/ejt.1293404

All articles published by EJT are licensed under the Creative Commons Attribution 4.0 International License. This permits anyone to copy, redistribute, remix, transmit and adapt the work provided the original work and source is appropriately cited.Creative Commons Lisansı