Çevresel Su Numunelerinde Eser Miktardaki Cu(II) İyonunun Seçici Spektrofotometrik Tayini

Year 2019, Volume: 12 Issue: 1, 367 - 378, 24.03.2019

Berrin Topuz

https://doi.org/10.18185/erzifbed.469433

Abstract

Mikrokristal naftalin (MN)
üzerinde pH 3.0-8.0 aralığında potasyum 2,6-dimetilmorfolinditiyokarbamat
(KMDMMDTC) ligantı kullanılarak büyük hacimli sulu çözeltilerden Cu(II) iyonu
önderiştirilmiştir. Cu(II)-DMMDTC 
kompleksi içeren MN, 5 mL asetonda çözülerek Cu(II) iyonu kör çözeltiye
karşı 431 nm’de spektrofotometrik metot ile tayin edildi. pH, numune
çözeltisinin hacmi, DMMDTC yüklü MN miktarı, çalkalama süresi, yabancı iyon
etkisi gibi katı faz ekstraksiyon (SPE) metodunun temel parametreleri
incelendi. Aseton çözeltisinde 0,09 µgmL^-1 tayin sınırı ile lineer
kalibrasyon aralığı 0,05-5,0 µgmL^-1’dir. Sudaki potansiyel yabancı
iyonların etkisi araştırıldı ve önerilen metot ilaç ve çevresel numunelerden Cu(II) iyonunun tayini için
uygulanarak % 90 üzerinde geri kazanım değerleri elde edildi. Doğruluk,
sertifikalı referans madde NW-TMDA-70.2 analizi ve geri kazanım deneyleri ile
değerlendirildi.

Keywords

Potasyum-2-6-dimetilmorfolinditiyokarbamat, SPE metot, Eser Cu(II) tayini.

References

• Alonso A, Almendral MJ, Curto Y, Porras MJ, 2003. Spectrophotometric Determination of Copper in Waste Water Using Liquid–Liquid Extraction in a Flow-Injection System. Microchimica Acta, 143 (4): 217-220.
• Cassella RJ, Magalhães O.I.B, Couto MT, Lima ELS, Neves MAFS, Coutinho FMB, 2005, Synthesis and application of a functionalized resin for flow injection/FAAS copper determination in waters. Talanta, 67 (1): 121-128.
• Cesur H, 2003. Determination of Manganese, Copper, Cadmium and Lead by FAAS after Solid-Phase Extraction of Their Phenylpiperazine Dithiocarbamate Complexes on Activated Carbon. Turkish Journal of Chemistry, 27(3): 307-314.
• Dalman Ö, Tufekci M, Nohut S, Güner S, Karaböcek S, 2002. Spectrophotometric determination of copper in pharmaceutical and biological samples with 3-{2-[2-(2-hydroxyimino-1-methyl-propylideneamino)- ethylamino]-ethyl-imino}-butan-2-one oxime. Journal of Pharmaceutical and Biomedical Analysis, 27(1-2): 183-189.
• Diniz MCT, Filho OF, Rohwedder JJR, 2004. An automated system for liquid–liquid extraction based on a new micro-batch extraction chamber with on-line detection preconcentration and determination of copper(II). Analytica Chimica Acta, 525(2): 281-287.
• Endo M, Suzuki K, Abe S, 1998. Novel preconcentration technique for trace metal ions by aggregate fılm formation. Spectrophotometric determination of copper(II). Analytica Chimica Acta, 364(1-3): 13-17.
• Fu D, Yuan D, 2007. Spectrophotometric determination of trace copper in water samples with thiomichlersketone. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 66(2): 434-437.
• Ghaedi M, Ahmadi F, Tavakoli Z, Montazerozohori M, Khanmohammadi A, Soylak M, 2008. Three modified activated carbons by different ligands for the solid phase extraction of copper and lead. Journal of Hazardous Materials, 152(3): 1248-1255.
• Gholivand MB, Ahmadi F, Rafiee E, 2007. Solid Phase Extraction and Determination of Ultra Trace Amounts of Copper using Activated Carbon Modified by N,N′‐Bis(Salicylidene)‐1,2 Phenylenediamine. Separation Science and Technology, 42(4): 897-910.
• Hejazi L, Mohammadi DE, Yamini Y, Brereton RG, 2004. Solid-phase extraction and simultaneous spectrophotometric determination of trace amounts of Co, Ni and Cu using partial least squares regression. Talanta, 62(1): 183-189.
• Karaböcek S, Nohut S, Dalman Ö, Güner S, 2000. A new spectrophotometric reagent for copper:3,30-(1,3-propanediyldiimine)bis-[3-methyl-2-butanone]dioxime. Analytica Chimica Acta, 408 (1-2): 163-168.
• Karimi H, Ghaedi M, Shokrollahi A, Rajabi HR, Soylak M, Karami B, 2008. Development of a selective and sensitive flotation method for determination of trace amounts of cobalt, nickel, copper and iron in environmental samples, Journal of Hazardous Materials, 151(1), 26-32.
• Kaur V, Malik AK, Verma N, 2007. Derivative Spectrophotometric Determination of Copper and Palladium Simultaneously by Using MDTC as a Reagent, Analytical Letters, 40(12): 2360-2373.
• Kendüzler E, Türker AR, 2003. Atomic absorption spectrophotometric determination of trace copper in waters, aluminium foil and tea samples after preconcentration with 1-nitroso-2-naphthol-3,6-disulfonic acid on Ambersorb 572. Analytica Chimica Acta, 480(2): 259-266.
• KneŽević S, Milačič R, Veber M, 1998. ETAAS determination of aluminium and copper in dialysis concentrates after microcolumn chelating ion-exchange preconcentration. Fresenius' Journal of Analytical Chemistry, 362(1): 162-166.
• Lemos VA, Santos JS, Baliza PX, 2006. Me-BTABr Reagent in Cloud Point Extraction for Spectrometric Determination of Copper in Water Samples. Journal of the Brazilian Chemical Society, 17(1): 30-35.
• Liang P, Yang J, 2010. Cloud point extraction preconcentration and spectrophotometric determination of copper in food and water samples using amino acid as the complexing agent. Journal of Food Composition and Analysis, 23(1): 95-99.
• Liu Y, Guo Y, Chang X, Meng S, Yang D, Din B, 2005. Column Solid-Phase Extraction with 2-Acetylmercaptophenyldiazoaminoazobenzene (AMPDAA) Impregnated Amberlite XAD-4 and Determination of Trace Heavy Metals in Natural Waters by Flame Atomic Absorption Spectrometry. Microchimica Acta, 149(1-2): 95-101.
• Lutfullah, Sharma S, Rahman N, Azmi SNH, Iqbal B, Amburk MIBB, Barwani ZMHA, 2010. UV Spectrophotometric Determination of Cu(II) in Synthetic Mixture and Water Samples, Journal of the Chinese Chemical Society, 57(4A): 622-631.
• Marahel F, Ghaedi M, Montazerozohori M, Biyareh MN, Kokhdan SN, Soylak M, 2011. Solid-phase extraction and determination of trace amount of some metal ions on Duolite XAD 761 modified with a new Schiff base as chelating agent in some food samples. Food and Chemical Toxicology, 49(1), 208-214.
• Mashhadizadeh MH, Pesteh M, Talakesh M, Sheikhshoaie I, Ardakani MM, Karimi MA, 2008. Solid phase extraction of copper (II) by sorption on octadecyl silica membrane disk modified with a new Schiff base and determination with atomic absorption spectrometry, Spectrochimica Acta Part B: Atomic Spectroscopy, 63(8), 885-888.
• Morales L, Toral MI, 2007. Simultaneous determination of Au(III) and Cu(II) with 1-phenyl-1,2-propanedione-2-oximethiosemicarbazone (PPDOT) on solid phase. Minerals engineering, 20(8): 802-806.
• Pancras JP, Puri BK, 2002. Column preconcentration and FAAS determination of copper, iron, nickel and zinc using 2-(5-bromo-2-pyridylazo)-5diethylaminophenol–tetraphenylborate–naphthalene adsorbent. Analytical and Bioanalytical Chemistry, 374(7-8): 1306-1311.
• Peker DSK, Turkoglu O, Soylak M, 2007. Dysprosium(III) hydroxide coprecipitation system for the separation and preconcentration of heavy metal contents of table salts and natural waters. Journal of Hazardous Materials, 143(1-2): 555-560.
• QuanMin L, XiaoHong Z, Kai J, GuoGuang L, 2007. Study of spectrophotometric method for determination of trace copper after the separation and enrichment with solid phase extractant-microcrystalline phenolphthalein. Chinese Science Bulletin, 52(1): 65-70.
• Ramesh A, Mohan KR, Seshaiah K, 2002. Preconcentration of trace metals on Amberlite XAD-4 resin coated with dithiocarbamates and determination by inductively coupled plasma-atomic emission spectrometry in saline matrices. Talanta, 57(2), 243-252.
• Rao GPC, Veni SS, Pratap K, Rao YK, Seshaiah K, 2006. Solid phase extraction of trace metals in seawater using morpholine dithiocarbamate-loaded amberlite XAD-4 and determined by ICP-AES. Analytical Letters, 39(5): 1009-1021.
• Reddy KJ, Kumar JR, Narayana SL, Ramachandraiah C, Thriveni T, Reddy AV, 2007. N-ethyl-3-carbazolecarboxaldehyde-3-thiosemicarbazone: a new extractive spectrophotometric reagent for the determination of copper(ii) in environmental and pharmaceutical samples. Environmental Monitoring and Assessment, 124(1-3): 309-320.
• Rezaei B, Sadeghi E, Meghdadi S, 2009. Nano-level determination of copper with atomic absorption spectrometry after pre-concentration on N,N-(4-methyl-1,2-phenylene)diquinoline-2-carboxamide–naphthalene. Journal of Hazardous Materials, 168(2-3): 787-792.
• Shabani AMH, Dadfarnia S, Nasirizadeh N, Shishehbore MR, 2007. Preconcentration of Copper with Dithizone-Naphthalene for Subsequent Determination by Atomic Absorption Spectrometry, Journal of Analytical Chemistry, 62(1): 46-50.
• Shamsipur M, Ghiasvand AR, Sharghi H, Naeimi H, 2000. Solid phase extraction of ultra trace copper(II) using octadecyl silica membrane disks modified by a naphthol-derivative Schiff’s base. Analytica Chimica Acta, 408(1-2): 271-277.Tarley CRT, Dos Santos WNL, Dos Santos CM, Arruda MAZ, Ferreira SLC, 2004. Factorial Design and Doehlert Matrix in Optimization of Flow System for Preconcentration of copper on polyurethane foam loaded with 4‐(2‐pyridylazo)‐resorcinol. Analytical Letters, 37(7): 1437-1455.
• Topuz B, Macit M, 2011. Solid phase extraction and preconcentration of Cu(II), Pb(II), and Ni(II) in environmental samples on chemically modified Amberlite XAD-4 with a proper Schiff base. Environmental Monitoring and Assessment, 173(1-4): 709-722.
• Topuz, B., Adanur ŞM, Yalcuk A. 2017. A new method for simultaneous determination of trace amounts of Cu (II) and Ni (II) ions by preconcentration and spectrophotometric analysis. Turkish Journal of Chemistry, 41(5): 619-629.
• Turkoglu O, Soylak M, 2005. Spectrophotometric Determination of Copper in Natural Waters and Pharmaceutical Samples with Chloro(phenyl) glyoxime. Journal of the Chinese Chemical Society, 52(3): 575-579.
• Tuzen M, Uluozlu OD, Usta C, Soylak M, 2007. Biosorption of copper(II), lead(II), iron(III) and cobalt(II) on Bacillus sphaericus-loaded Diaion SP-850 resin. Analytica Chimica Acta, 581(2): 241-246.
• Tuzen M, Saygi KO, Soylak M, 2008. Solid phase extraction of heavy metal ions in environmental samples on multiwalled carbon nanotubes. Journal of Hazardous Materials, 152(2): 632-639.
• Yamini Y, Tamaddon A, 1999. Solid-phase extraction and spectrophotometric determination of trace amounts of copper in water samples. Talanta, 49(1): 119-124.
• Zendelovska D, Pavlovska G, Cundeva K, Stafilov T, 2001. Electrothermal atomic absorption spectrometric determination of cobalt, copper, lead and nickel traces in aragonite following flotation and extraction separation. Talanta, 54(1), 139-146.
• Zereen F, Yilmaz V, Arslan Z, 2014. Multielement Solid Phase Preconcentration Using a Chelating Resin of Styrene Divinylbenzene Copolymer and Application for the Analysis of Seawater and Fish Otoliths by Inductively Coupled Plasma Mass Spectrometry (ICP-MS). Analytical Letters, 47(1), 58-76.