THE ANALYSES OF THE EFFECT OF HEAT TREATMENT ON THE STRUCTURAL PROPERTIES OF ZEOLITES FROM TURKEY USING FT-IR, MAS NMR AND XRD METHODS

Year 2019, Volume: 20 Issue: 4, 474 - 480, 30.12.2019

Burcu Erdoğan Alver Gökhan Dikmen , Özgür Alver

https://doi.org/10.18038/estubtda.519641

Cited By: 1

Abstract

Upon the heat exposure, natural
zeolites show structural alterations which leads to a possibility to be used
for different purposes in science and industry including building stones,
concrete bricks and ceramic foam etc. The effect of heat treatment at 800^oC
with different treatment times of 30, 60, 150 min of  clinoptilolite rich zeolites from Gördes
region of Turkey were investigated by Fourier Transform IR (FT-IR), solid state
magic angle spinning nuclear magnetic resonance (MAS NMR), and X-ray diffraction
(XRD) spectroscopic methods. The obtained spectroscopic results indicated that
rather than a total collapse, severe structural distortions occur for the
investigated samples.

Keywords

Zeolite, FT-IR, MAS NMR, XRD

References

• [1] Erdem E, Karapinar N, Donat R. The removal of heavy metal cations by natural zeolites.J. Colloid Interface Sci. 2004; 280: 309–314.
• [2] Cabrera C, Gabaldon C, Marzal P. Sorption characteristics of heavy metal ions by a natural zeolite. J. Chem. Technol. Biotechnol. 2005; 80: 477–481.
• [3] M. Danilczuk, K. Dlugopolska, T. Ruman, D. Pogocki. Molecular sieves in medicine, Mini Rev. Med. Chem. 2008; 8: 1407-1417.
• [4] Andronikashvili T, Pagava K, Kurashvili T, Eprikashvili L. Possibility of application of natural zeolites for medicinal purposes. Bull. Georg. Natl. Acad. Sci. 2009; 3: 158-167.
• [5] Otero Areán C, Turnes Palomino G, Llop Carayol MR, Pulido A, Rubeš M, Bludský O, Nachtigall P. Hydrogen adsorption on the zeolite Ca-A: DFT and FT-IR investigation. Chem. Phys. Lett. 2009; 477: 139-143.
• [6] Deka A, Deka RC, Choudhury A. Adsorption of CO on gas phase and zeolite supported gold monomers: a computational study. Chem. Phys. Lett. 2010; 490: 184-188.
• [7] Gottardi G, Galli E. Natural zeolites. Berlin: Springer, 1985.
• [8] Breck DW. Zeolite molecular sieves: structure, chemistry, and use. New York: Wiley, 1974.
• [9] Breck DW. Potential uses of natural and synthetic zeolites in industry. In: Towsand RP, editor. The properties and application of zeolites, J Chem Soc (Lond), 1980.
• [10] Tsitsishvili G, Andronikashvili T, Kirov G, Filizova L. Natural zeolites. New York, Ellis Horwood, 1992.
• [11] Mumpton FA. Clinoptilolite redefined. Am .Min. 1960; 45: 351–69.
• [12] Ackley MW, Giese RF, Yang RT. Clinoptilolite: an untapped potential for kinetic gas separations. Zeolites, 1992; 12: 780–787.
• [13] Çağlar Duvarcı Ö, Akdeniz Y, Özmıhçı F, Ülkü S, Balköse D, Çiftçioğlu M. Thermal behaviour of a zeolitic tuff. Ceram. Int. 2007; 33: 795-801.
• [14] Zhan Z, Ma N, Han H, Peng Y, Wang Z, Yan Y. Heat treatment for improving performance of inner-side zeolite NaA membranes on composite hollow fibers. J. Membr. Sci. 2015; 485: 94–102.
• [15] Ahmad J, Häg MB. Effect of zeolite preheat treatment and membrane post heat treatment on the performance of polyvinyl acetate/zeolite 4A mixed matrix membrane. Sep. Purif. Technol. 2013; 115: 163–171.
• [16] Mozgawa W, Fojud Z, Handke M, Jurga S. MAS NMR and FTIR spectra of framework aluminosilicates. J. Mol. Struct. 2002; 614: 281–287.
• [17] Costa DG, Capaz RB. Structural analysis of zeolite beta through periodic ab initio simulations of XRD and 29Si and 17O NMR spectra. J. Mol. Struct. 2015; 1097: 112–116.
• [18] Kneller JM, Pietraß T, Ott KC, Labouriau A. Synthesis of dealuminated zeolites NaY and MOR and characterization by diverse methodologies: 27Al and 29Si MAS NMR, XRD, and temperature dependent 129Xe NMR. Micropor. Mesopor. Mat. 2003; 62: 121–131.[19] Doula MK. Synthesis of a clinoptilolite–Fe system with high Cu sorption capacity. Chemosphere, 2007; 67: 731–740.
• [20] Mansouri N, Rikhtegar N, Panahi HA, Atabi F, Shahraki BK. Porosity, characterization and structural properties of natural zeolite - clinoptilolite - as a sorbent. Environ. Prot. Eng. 2013; 39(1): 139-152.
• [21] Korkuna O, Leboda R, Skubiszewska-Ziȩba J, Vrublevs’ka T, Gun’ko VM, Ryczkoeski J.Structural and physicochemical properties of natural zeolites: Clinoptilolite and mordenite. Micropor. Mesopor. Mat. 2006; 87: 243–254.
• [22] Faghihian H, Kabiri-Tadi M. Removal of zirconium from aqueous solution by modified clinoptilolite. J. Hazard. Mater. 2010; 178: 66–73.
• [23] Tsyntsarski B, Petrova B, Budinova T, Petrov N, Sarbu A, Sandu T, Ferhat Yardım M, Sirkecioğlu A. Removal of detergents by zeolites and membranes. Bulg. Chem. Commun. 2014; 46(1): 157–164.
• [24] Kumbasa I, Özkar S. The study of clinoptilolite - rich tuffs from Bigadiç by NMR Technique. Turkish Geo. Bull. 1993; 36: 1-5.
• [25] Rodriques-Fuentes G, de Ménorval LC, Reguera E, Chávez Rivas F. Solid state multinuclear NMR study of iron species in natural and modified clinoptilolite from Tasajera deposit (Cuba). Micropor. Mesopor. Mat. 2008; 111: 577–590.
• [26] Riviera A, Farías T, Ruiz-Salvador AR, de Ménorval LC. Preliminary characterization of drug support systems based on natural clinoptilolite. Micropor. Mesopor. Mat. 2003; 61: 249–259.
• [27] Loewenstein W. The distribution of aluminium in the tetrahedral of silicates and aluminates. Am. Mineral. 1954; 39: 92-96.
• [28] Barras J, Klinowski J, McComb DW. 27Al and 29Si solid-state NMR studies of dealuminated mordenite. J. Chem. Soc. Faraday Trans. 1994; 90(24): 3719-3723.
• [29] Hunger M, Brunner E. Characterization I-NMR Spectroscopy, in Molecular Sieves-Science and Technology, Springer, Berlin, 2004.
• [30] Petrov OE. Cation Exchange in Clinoptilolite: An X-Ray Powder Diffraction Analysis. In Natural Zeolite’93: Occurrence, Properties, Use; Ming DW, Mumpton FA. Eds. International Committee on Natural Zeolites: Brockport, NY, 1995.
• [31] Nezamzadeh-Ejhieh A, Moeinirad S. Heterogeneous photocatalytic degradation of furfural using NiS-clinoptilolite zeolite. Desalination, 2001; 273: 248–257.
• [32] Esenli F, Sirkecioğlu A. The relationship between zeolite (heulandite–clinoptilolite) content and the ammonium-exchange capacity of pyrodastic rocks in Gordes, Turkey. Clay Miner. 2005; 40(4): 557–564.
• [33] Christidis GE, Moraetis D, Keheyan E, Akhalbedashvili L, Kekelidze N, Gevorkyan R, Yeritsyan H, Sargsyan H. Chemical and thermal modification of natural HEU-type zeolitic materials from Armenia, Georgia and Greece. Appl. Clay Sci. 2003; 24: 79– 91.[34] Dimowa LT, Petrov SL, Shivachev BL. Natural and Zn exchanged clinoptilolite: in situ high temperature XRD study of structural behavior and cation positions. Bulg. Chem. Commun. 2013; 45(4): 466–473.
• [35] Akkoca DB, Yιlgιn M, Ural M, Akçin H, Mergen A. Hydrothermal and thermal treatment of natural clinoptilolite zeolite from Bigadiç, Turkey: An experimental study. Geochem. Int. 2013; 51(7): 495–504.