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EFFECT OF BENTONITE AND DOLOMITE ADDITIVES ON RIGID POLYURETHANE

Year 2023, Volume: 24 Issue: - - 19th National Clay Symposium (Clay’2023) Sprecial Issue - 2023, 1 - 8, 29.11.2023
https://doi.org/10.18038/estubtda.1367889

Abstract

In this study, clay minerals such as bentonite and dolomite were included to increase the compressive tensile strength and decrease the thermal conductivity of rigid polyurethane foam. The effect of different combinations and amounts of clay minerals on the test parameters of the foam was investigated. The surface morphology of the doped foams was investigated by scanning electron microscopy (SEM). Polyurethane foams were subjected to compressive-tensile strength and thermal conductivity tests. Improvement was observed in the thermal conductivity of polyurethane foams containing 1% bentonite and in the compressive and tensile strengths of polyurethane foams containing 2% dolomite. When clay minerals were added to polyurethane foam in combination, both thermal conductivity and compressive and tensile strengths were improved.

References

  • [1] Chuayjuljit S, Maungchareon A & Saravari O. Preparation and Properties of Palm Oil-Based Rigid Polyurethane Nanocomposite Foams. J. Reinf. Plast. Compos 2010; 29(2): 218-225.
  • [2] Omotoyinbo JA, Oladele IO, Jabar JM, Borode JO, Alaneme KK, Akinwekomi, AD, Samuel RO, Omotosho TF, Saliu LO. Comparative investigation of the influence of Kaolin and Dolomite on the Properties of Polyurethane Foam. Manufacturing Rev 2021; 8: 27-32.
  • [3] Aydoğan B, Nazım USTA. Experimental Investigation of Thermal Conductivity, Thermal Degradation and Burning Resistance of Rigid Polyurethane Foams with Nanocalcite and Swelling Flame Retardant Addition. Isı Bilimi ve Tekniği Dergisi 2015; 35(2): 63‒74.
  • [4] Widya T & Macosko CW. Nanoclay‐Modified Rigid Polyurethane Foam. J Macromol Sci B: Phys J 2005; 44(6): 897‒908.
  • [5] Alan N & İşçi S. Surface Modification of Sepiolite Particles with Polyurethane and Polyvinyl Alcohol. Prog. Org. Coat 2014; 77(2): 444‒448.
  • [6] Erdem M, Ortaç K, Erdem B, Türk H. Effect of Reactive Organobentonite Additives on Some Performance Properties of Rigid Polyurethane Foam. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 2017; 32(4): 1209‒1220.
  • [7] Baysal B. The Effect of Phosphonium Salt on Thermal Stability and Mechanical Properties in Montmorillonite/Polymer Nanocomposites Master Thesis, İstanbul University, İstanbul, Turkey, 2012.
  • [8] Aydoğan B. Investigation of Thermal Decomposition and Combustion Behaviors of Polyurethane Based Composite Materials Containing Natural Minerals, Doctoral Thesis, Pamukkale University, Denizli, Türkiye, 2015.
  • [9] Rehab A & Salahuddin N. Nanocomposite Materials Based on Polyurethane Intercalated into Montmorillonite Clay. Mater. Sci. Eng. A, 2005; 399(1-2): 368‒376.

EFFECT OF BENTONITE AND DOLOMITE ADDITIVES ON RIGID POLYURETHANE

Year 2023, Volume: 24 Issue: - - 19th National Clay Symposium (Clay’2023) Sprecial Issue - 2023, 1 - 8, 29.11.2023
https://doi.org/10.18038/estubtda.1367889

Abstract

In this study, clay minerals such as bentonite and dolomite were included to increase the compressive tensile strength and decrease the thermal conductivity of rigid polyurethane foam. The effect of different combinations and amounts of clay minerals on the test parameters of the foam was investigated. The surface morphology of the doped foams was investigated by scanning electron microscopy (SEM). Polyurethane foams were subjected to compressive-tensile strength and thermal conductivity tests. Improvement was observed in the thermal conductivity of polyurethane foams containing 1% bentonite and in the compressive and tensile strengths of polyurethane foams containing 2% dolomite. When clay minerals were added to polyurethane foam in combination, both thermal conductivity and compressive and tensile strengths were improved.

References

  • [1] Chuayjuljit S, Maungchareon A & Saravari O. Preparation and Properties of Palm Oil-Based Rigid Polyurethane Nanocomposite Foams. J. Reinf. Plast. Compos 2010; 29(2): 218-225.
  • [2] Omotoyinbo JA, Oladele IO, Jabar JM, Borode JO, Alaneme KK, Akinwekomi, AD, Samuel RO, Omotosho TF, Saliu LO. Comparative investigation of the influence of Kaolin and Dolomite on the Properties of Polyurethane Foam. Manufacturing Rev 2021; 8: 27-32.
  • [3] Aydoğan B, Nazım USTA. Experimental Investigation of Thermal Conductivity, Thermal Degradation and Burning Resistance of Rigid Polyurethane Foams with Nanocalcite and Swelling Flame Retardant Addition. Isı Bilimi ve Tekniği Dergisi 2015; 35(2): 63‒74.
  • [4] Widya T & Macosko CW. Nanoclay‐Modified Rigid Polyurethane Foam. J Macromol Sci B: Phys J 2005; 44(6): 897‒908.
  • [5] Alan N & İşçi S. Surface Modification of Sepiolite Particles with Polyurethane and Polyvinyl Alcohol. Prog. Org. Coat 2014; 77(2): 444‒448.
  • [6] Erdem M, Ortaç K, Erdem B, Türk H. Effect of Reactive Organobentonite Additives on Some Performance Properties of Rigid Polyurethane Foam. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 2017; 32(4): 1209‒1220.
  • [7] Baysal B. The Effect of Phosphonium Salt on Thermal Stability and Mechanical Properties in Montmorillonite/Polymer Nanocomposites Master Thesis, İstanbul University, İstanbul, Turkey, 2012.
  • [8] Aydoğan B. Investigation of Thermal Decomposition and Combustion Behaviors of Polyurethane Based Composite Materials Containing Natural Minerals, Doctoral Thesis, Pamukkale University, Denizli, Türkiye, 2015.
  • [9] Rehab A & Salahuddin N. Nanocomposite Materials Based on Polyurethane Intercalated into Montmorillonite Clay. Mater. Sci. Eng. A, 2005; 399(1-2): 368‒376.
There are 9 citations in total.

Details

Primary Language English
Subjects Polymerisation Mechanisms
Journal Section Articles
Authors

Sinem Tümük 0009-0002-4485-5126

Bilgehan Güzel 0000-0002-0234-6940

Erdem Delil 0009-0002-6375-2288

Publication Date November 29, 2023
Published in Issue Year 2023 Volume: 24 Issue: - - 19th National Clay Symposium (Clay’2023) Sprecial Issue - 2023

Cite

AMA Tümük S, Güzel B, Delil E. EFFECT OF BENTONITE AND DOLOMITE ADDITIVES ON RIGID POLYURETHANE. Eskişehir Technical University Journal of Science and Technology A - Applied Sciences and Engineering. November 2023;24(-):1-8. doi:10.18038/estubtda.1367889