Paulownia Elongata odununun pirolizinde sürükleyici gaz hızı ve parçacık boyutunun ürün verimlerine etkisi ve katran karakterizasyonu

Year 2023, Volume: 38 Issue: 3, 1699 - 1710, 06.01.2023

Derya Yıldız

https://doi.org/10.17341/gazimmfd.1050524

Cited By: 1

Abstract

Son yıllarda birçok gelişmiş ülkede çevresel nedenlerle biyokütle, kimyasal hammadde ve yenilenebilir enerji kaynağı olarak kullanılmaktadır. Bu çalışmada biyokütlenin pirolizi ile elde edilen katranın biyo yakıt özelliklerinin aydınlatılması amaçlanmıştır. Biyokütle kaynağı olarak Paulownia (P. elongata) ağacı seçilmiştir. Paulownia, hızlı büyüyen bir ağaç cinsidir, biyo yakıt hammaddesi olarak yetiştiriciliği yapılır ve avantajlı birçok özelliğinden dolayı endüstriyel uygulamalarda da kullanılmaktadır. Asya ülkelerinde özellikle mobilya ve süs eşyası yapımında yoğun olarak kullanılmaktadır. Bu tür üretimler sonrası oluşan atıkların biyoenerji ürünlerine dönüştürülme potansiyeli de oldukça yüksektir. Biyo yakıt üretimi için en sık uygulanan termokimyasal yöntem pirolizdir. Bu çalışmada, sürükleyici gaz akış hızı (N2) (0,05, 0,10, 0,2, 0,3 L/min) ve partikül boyutunun (0,224-0,425; 0,425-0,6; 0,6-0,85; 0,85-1; 1-1,8 mm) piroliz ürün verimleri üzerine etkisi 50°C/min ısıtma hızında ve 500°C sıcaklıkta incelenmiştir. 0,1 L/min sürükleyici gaz (N2) hızında ve 0,6-0,85 mm partikül boyutunda en yüksek katran verimine ulaşılmıştır. Bu koşullarda elde edilen katranın elementel analizi, FT-IR, 1H-NMR, GC-MS analizleri yapılmış ve katranın, hidrokarbonları, uzun zincirli karboksilik asit/esterleri, ketonları, fenolik bileşikleri ve onların türevlerini içerdiği gözlenmiştir. Zengin bir kimyasal içeriğe ve yüksek ısıl değere sahip katranın kimyasal hammadde kaynağı olarak ve katalitik iyileştirme sonrası sıvı yakıt olarak kullanılabileceği söylenebilir.

Keywords

Biyokütle, Paulownia odunu, piroliz, katran karakterizasyonu

Supporting Institution

yok

Project Number

yok

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