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Kimyasal metalurjide çevreci bir yaklaşım: Solvometalurji

Year 2024, Volume: 39 Issue: 4, 2643 - 2654, 20.05.2024

Çisem Çelik Kurtulan , Şevki Samet Kaplan , Elif Güloğlu , Gökhan Orhan , Sebahattin Gürmen , Mehmet Şeref Sönmez

https://doi.org/10.17341/gazimmfd.1250678

Abstract

Hidrometalurji metal ekstraksiyonunda sıkça kullanılan etkin ve bilinen bir yöntemdir. Ancak bu sistemlerde kullanılan yüksek miktarda su ve açığa çıkan atık asit miktarı sebebiyle, bilim dünyasında alternatif metot araştırma faaliyetleri her geçen gün artmaktadır. Bu noktada literatür incelendiğinde yeşil kimya ve solvometalurji kavramının ön plana çıktığı görülmektedir. Bu çalışmada solvometalurjik yöntemlerde kullanılan yeşil çözücüler tanımlanmış, iyonik sıvılar ve ötektik altı çözücüler hakkında bilgiler verilmiştir. Solvometalurjik yöntemlerin birincil hammaddelere uygulandığı örneklere yer verilmiş, bu bağlamda nadir toprak elementlerinin ve bakırın solvometalurjik yöntemlerle eldesi üzerine detaylı açıklamalarda bulunulmuştur. İkincil kaynaklardan hareketle; atık lityum iyon pillerin, floresan lamba atıklarının, hurda NdFeB ve SmCo mıknatısların, maden atıklarından solvometalurjik yöntemler kullanılarak metallerin geri kazanılması hakkında detaylı bilgiler verilmiştir. Sonuç olarak; solvometalurjinin hidrometalurjik temelli yöntemlere göre daha az su kullanımı başta olmak üzere üretimde kaynak kullanımını azaltma iddiası taşıdığı, solvometalurjik yöntemlerin uygulandığı birçok proseste gerek çözümlendirme verimleri, gerekse çözelti saflaştırma ve zenginleştirme oranlarının daha yüksek olduğu, bu yöntemlerin oda sıcaklığında çalışma olanağı ve geleneksel yöntemlerle karşılaştırıldığında çok daha düşük enerji tükettiği ifade edilmiştir. Solvometalurjik yöntemlerin araştırıldığı akademik çalışmaların önümüzdeki dönemlerde de artarak devam edeceğinin beklendiği, bununla birlikte yöntemin laboratuvar ölçeğinden yarı-endüstriyel hatta endüstriyel boyuta taşınmasına yönelik çalışmaların kısa-orta vadede artarak devam edeceğinin öngörüldüğü belirtilmiştir.

Keywords

Solvometalurji Ekstraktif Metalurji Geri Dönüşüm Yeşil Kimya

Supporting Institution

Türkiye Enerji, Nükleer ve Maden Araştırma Kurumu Nadir Toprak Elementleri Araştırma Enstitüsü

Project Number

A8.H1.P3

Thanks

Yazarlar Türkiye Enerji, Nükleer ve Maden Araştırma Kurumu Nadir Toprak Elementleri Araştırma Enstitüsü tarafından desteklenen “Bastnazit Kompleks Cevherinden/Konsantresinden Nadir Toprak Elementlerinin Solvometalurjik Yöntemle Ekstraksiyonu Ve Oksitlerinin Üretimi” başlıklı ve A8.H1.P3 nolu proje için teşekkür eder.

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Year 2024, Volume: 39 Issue: 4, 2643 - 2654, 20.05.2024

Çisem Çelik Kurtulan , Şevki Samet Kaplan , Elif Güloğlu , Gökhan Orhan , Sebahattin Gürmen , Mehmet Şeref Sönmez

https://doi.org/10.17341/gazimmfd.1250678

Abstract

Keywords

Solvometalurji Ekstraktif Metalurji Geri Dönüşüm Yeşil Kimya

Project Number

A8.H1.P3

References

  • 1. BOR F.Y., Ekstraktif Metalurji Prensipleri, Matbaa Teknisyenleri Basımevi, İstanbul, Türkiye, 1977.
  • 2. Gupta C.K., Chemical Metallurgy: Principles and Practice, Wiley-VCH, New Jersey, A.B.D., 2003.
  • 3. Habashi F., Handbook of Extractive Metallurgy, Wiley-VCH, New Jersey, A.B.D., 3, 1997.
  • 4. Anderson C.G., Dunne R.C., Uhrie J.L., Mineral Processing and Extractive Metallurgy: 100 Years of Innovation, Society For Mining, Metallurgy & Exploration, 2014.
  • 5. Hayes P.C., Process Principles in Minerals and Materials Production, Hayes Publisihing Co. , Brisbane, Queensland, Australia, 2003.
  • 6. Binnemans K., Jones P.T., Solvometallurgy: An Emerging Branch of Extractive Metallurgy, Journal of Sustainable Metallurgy, 3, 570–600, 2017.
  • 7. Anastas P.T., Warner J.C., Green Chemistry: Theory and Practice, Oxford University Press, 1998.
  • 8. Sheldon R.A., Arends I., Hanefeld U., Sheldon R. A., Arends I. and Hanefeld U., Green Chemistry and Catalysis. Wiley-VCH, New Jersey, A.B.D., 2007.
  • 9. Anastas P., Eghbali N., Green Chemistry: Principles and Practice, Chemical Society Reviews, 39 (1), 301–312, 2010.
  • 10. Cunha S.C., Fernandes J.O., Extraction Techniques with Deep Eutectic Solvents, TrAC Trends in Analytical Chemistry, 105, 225–239, 2018.
  • 11. Smith E.L., Abbott A.P., Ryder K.S., Deep Eutectic Solvents (DESs) and Their Applications, Chemical Reviews, 114, 11060–11082, 2014.
  • 12. Zhang Q., De Oliveira Vigier K., Royer S., Jérôme F., Deep Eutectic Solvents: Syntheses, Properties and Applications, Chemical Society Reviews, 41 (21), 7108–7146, 2012.
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  • 18. Li Z., Li X., Raiguel S., Binnemans K., Separation of Transition Metals from Rare Earths by Non-Aqueous Solvent Extraction from Ethylene Glycol Solutions Using Aliquat 336, Separation and Purification Technology, 201, 318–326, 2018.
  • 19. Riaño S., Petranikova M., Onghena B., Vander Hoogerstraete T., Banerjee D., Foreman M.R.StJ., Ekberg C., Binnemans K., Separation of Rare Earths and Other Valuable Metals from Deep-Eutectic Solvents: A New Alternative for the Recycling of Used NdFeB Magnets, RSC Advances, 7, 32100–32113, 2017.
  • 20. Dewulf B., Development of a Solvometallurgical Process for the Separation of Trivalent Yttrium And Europium, KU Leuven, 2018.
  • 21. Binnemans K., Jones P.T., Solvometallurgy: An Emerging Branch of Extractive Metallurgy, Journal of Sustainable Metallurgy, 3, 570–600, 2017.
  • 22. Kopkova E.K., Shchelokova E.A., Gromov P.B., Processing of Titanomagnetite Concentrate with a Hydrochloric Extract of N-Octanol, Hydrometallurgy, 156, 21–27, 2015.
  • 23. Li X., Monnens W., Li Z., Fransaer J., Binnemans K., Solvometallurgical Process for Extraction of Copper from Chalcopyrite and Other Sulfidic Ore Minerals, Green Chemistry, 22, 417–426, 2020.
  • 24. Li Z., Li X., Raiguel S., Binnemans K., Separation of Transition Metals from Rare Earths by Non-Aqueous Solvent Extraction from Ethylene Glycol Solutions Using Aliquat 336, Separation and Purification Technology, 201, 318–326, 2018.
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  • 27. Weber C.C., Masters A.F., Maschmeyer T., Structural Features of Ionic Liquids: Consequences for Material Preparation and Organic Reactivity, Green Chemistry, 15, 2655–2679, 2013.
  • 28. Huddleston J.G., Willauer H.D., Swatloski R.P., Visser A.E., Rogers R.D., Room Temperature Ionic Liquids as Novel Media for ‘Clean’ Liquid–Liquid Extraction, Chemical Communications, 16, 1765–1766, 1998.
  • 29. Peeters N., Janssens K., Vos D., Binnemans K., Riaño S., Choline Chloride-Ethylene Glycol Based Deep-Eutectic Solvents as Lixiviants for Cobalt Recovery from Lithium-Ion Battery Cathode Materials: Are These Solvents Really Green in High-Temperature Processes? Green Chemistry, 24, 6685–6695, 2022.
  • 30. Hansen B.B., Spittle S., Chen B., Poe D., Zhang Y., Klein J.M., Horton A., Adhikari L., Zelovich T., Doherty B.W., Gurkan B., Maginn E.J., Ragauskas A., Dadmun M., Zawodzinski T.A., Baker G.A., Tuckerman M.E., Savinell R.F., Sangoro J.R., Deep Eutectic Solvents: A Review of Fundamentals and Applications, Chemical Reviews, 121, 1232–1285, 2021.
  • 31. Benvenutti L., Zielinski A.A.F., Ferreira S.R.S., Which is the Best Food Emerging Solvent: IL, DES Or NADES?, Trends in Food Science & Technology, 90, 133–146, 2019.
  • 32. Abbott A.P., Capper G., Davies D.L., Rasheed R.K., Tambyrajah V., Novel Solvent Properties of Choline Chloride/Urea Mixtures, Chemical Communications, 1, 70–71, 2003.
  • 33. Abbott A.P., Capper G., Davies D.L., Munro H.L., Rasheed R.K., Tambyrajah V., Preparation of Novel, Moisture-Stable, Lewis-Acidic Ionic Liquids Containing Quaternary Ammonium Salts with Functional Side Chains, Chemical Communications. 1, 2010–2011, 2001.
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  • 36. Hayyan M., Mbous Y.P., Looi C.Y., Wong W.F., Hayyan A., Salleh, Z., Mohd-Ali O., Natural Deep Eutectic Solvents: Cytotoxic Profile, SpringerPlus. 5, 1-12, 2016.
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There are 59 citations in total.

Details

Primary Language Turkish
Subjects Engineering
Journal Section Makaleler
Authors

Çisem Çelik Kurtulan 0000-0001-7728-2075

Şevki Samet Kaplan 0000-0003-4806-5797

Elif Güloğlu 0000-0001-7371-6075

Gökhan Orhan 0000-0002-1684-5548

Sebahattin Gürmen 0000-0002-3830-9041

Mehmet Şeref Sönmez 0000-0001-7766-1198

Project Number A8.H1.P3
Early Pub Date May 17, 2024
Publication Date May 20, 2024
Submission Date February 15, 2023
Acceptance Date October 21, 2023
Published in Issue Year 2024 Volume: 39 Issue: 4

Cite

APA Çelik Kurtulan, Ç., Kaplan, Ş. S., Güloğlu, E., Orhan, G., et al. (2024). Kimyasal metalurjide çevreci bir yaklaşım: Solvometalurji. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, 39(4), 2643-2654. https://doi.org/10.17341/gazimmfd.1250678
AMA Çelik Kurtulan Ç, Kaplan ŞS, Güloğlu E, Orhan G, Gürmen S, Sönmez MŞ. Kimyasal metalurjide çevreci bir yaklaşım: Solvometalurji. GUMMFD. May 2024;39(4):2643-2654. doi:10.17341/gazimmfd.1250678
Chicago Çelik Kurtulan, Çisem, Şevki Samet Kaplan, Elif Güloğlu, Gökhan Orhan, Sebahattin Gürmen, and Mehmet Şeref Sönmez. “Kimyasal Metalurjide çevreci Bir yaklaşım: Solvometalurji”. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 39, no. 4 (May 2024): 2643-54. https://doi.org/10.17341/gazimmfd.1250678.
EndNote Çelik Kurtulan Ç, Kaplan ŞS, Güloğlu E, Orhan G, Gürmen S, Sönmez MŞ (May 1, 2024) Kimyasal metalurjide çevreci bir yaklaşım: Solvometalurji. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 39 4 2643–2654.
IEEE Ç. Çelik Kurtulan, Ş. S. Kaplan, E. Güloğlu, G. Orhan, S. Gürmen, and M. Ş. Sönmez, “Kimyasal metalurjide çevreci bir yaklaşım: Solvometalurji”, GUMMFD, vol. 39, no. 4, pp. 2643–2654, 2024, doi: 10.17341/gazimmfd.1250678.
ISNAD Çelik Kurtulan, Çisem et al. “Kimyasal Metalurjide çevreci Bir yaklaşım: Solvometalurji”. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 39/4 (May 2024), 2643-2654. https://doi.org/10.17341/gazimmfd.1250678.
JAMA Çelik Kurtulan Ç, Kaplan ŞS, Güloğlu E, Orhan G, Gürmen S, Sönmez MŞ. Kimyasal metalurjide çevreci bir yaklaşım: Solvometalurji. GUMMFD. 2024;39:2643–2654.
MLA Çelik Kurtulan, Çisem et al. “Kimyasal Metalurjide çevreci Bir yaklaşım: Solvometalurji”. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, vol. 39, no. 4, 2024, pp. 2643-54, doi:10.17341/gazimmfd.1250678.
Vancouver Çelik Kurtulan Ç, Kaplan ŞS, Güloğlu E, Orhan G, Gürmen S, Sönmez MŞ. Kimyasal metalurjide çevreci bir yaklaşım: Solvometalurji. GUMMFD. 2024;39(4):2643-54.