BIOMONITORING OF SOME PERSISTENT ORGANOCHLORINE CONTAMINANTS IN THE MILK OF ANATOLIAN WATER BUFFALOES

Year 2019, Volume: 44 Issue: 2, 348 - 356, 15.04.2019

Enes Atmaca

https://doi.org/10.15237/gida.GD19020

Cited By: 3

Abstract

In this study, 50 raw milk
samples of Anatolian water buffalo (Bubalus bubalis, Linneaus, 1758)
belonging to different dairy farmers in the Kızılırmak Delta in Samsun, Turkey,
were investigated for contamination by 9 organochlorine pesticides (OCPs) and
16 polychlorinated biphenyls (PCBs). The contaminants were extracted
cryogenically from the milk fat and their concentrations were determined with a
gas chromatography-electron capture detector (GC-ECD). The mean level of
alpha-hexachlorocyclohexane (HCH) in the milk samples was 6.34 ng/g^/fat,
beta-HCH was 20.41 ng/g/fat, gamma-HCH was 9.77 ng/g/fat, ∑DDTs was 18.11
ng/g/fat and ∑Indicator-PCBs was 127.27 ng/g/fat. The mean values, except for
aldrin and ∑DDTs, were above the maximum residue limits (MRLs) stated in the
European Commission (EC) Regulations and Turkish Food Codex (TFC). Regular monitoring and reporting of the levels of
persistent organochlorines in the meat, milk and processed products of water
buffaloes is essential for the assessment of human, animal and environmental
health. 

Keywords

Biomonitoring, organochlorine pesticides, polychlorinated biphenyls, water buffalo milk

ANADOLU MANDASI SÜTLERİNDE BAZI KALICI ORGANİK KLORLU KİRLETİCİLERİN BİYOİZLENMESİ

Abstract

Bu çalışmada, Samsun Kızılırmak
deltasındaki farklı yetiştiricilere ait mandalardan (Bubalus bubalis,
Linneaus, 1758) toplanan 50 çiğ süt örneğinde, çevresel kontaminasyonu
belirlemek için 9 organik klorlu pestisit ve 16 poliklorlu bifenil bileşik
kalıntısı araştırıldı. Süt yağından kriyojenik yöntemle ekstrakte edilen
analitlerin düzeyleri elektron yakalama detektörlü gaz kromatografi (GC-ECD)
ile ölçüldü. Süt örneklerinde ortalama alfa-HCH düzeyi 6.34 ng/g/yağ, ortalama
beta-HCH 20.41 ng/g yağ, ortalama gamma-HCH 9.77 ng/g/yağ, ortalama ∑DDT 18.11
ng/g/yağ ve ortalama ∑İndikatör-PCB 127.27 ng/g/yağ olarak tespit edildi. Aldrin
ve ∑DDT dışındaki miktarlar Avrupa Birliği Yönetmelikleri ve Türk Gıda
Kodeksi’nde belirtilen değerlerin üzerinde bulundu. Çevrede uzun yıllar
etkinliklerini koruyabilen kalıcı organik klorlu bileşiklerin mandalardan elde
edilen et, süt ve işlenmiş hayvansal ürünlerde düzenli aralıklarla izlenmesi ve
bildirilmesi insan, hayvan ve çevre sağlığının değerlendirilmesi açısından
önemlidir.

Keywords

Biyoizleme, organik klorlu pestisitler, poliklorlu bifeniller, manda sütü.

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