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PREVENTING OF MIGRATION IN FOOD CONTACT POLYVINYL CHLORIDE-BASED STRETCH FILMS WITH POLYLACTIC ACID LAYER

Year 2024, Volume: 49 Issue: 4, 624 - 640, 14.08.2024

Adnan Fatih Dağdelen , Fatma Tuba Kıraç Demirel , Furkan Türker Sarıcaoğlu

https://doi.org/10.15237/gida.GD23131

Abstract

In this study, the effectiveness of biodegradable polylactic acid (PLA) coatings for the prevention of residues migrating through polyvinyl chloride (PVC) films was investigated. PLA films prepared in chloroform at concentrations of 5, 10, 15 and 20 wt% were heat sealed to PVC film surfaces in a hot press (130 °C, 5 min, 5 tons). Physical, mechanical, FTIR and migration analyses were performed on these two-layer films. With PLA coating, the thickness of the films increased, mechanical properties decreased and some changes in color values occurred. It was determined by FTIR that there was no structural change on both surfaces of the films as a result of hot pressing. From the overall migration analysis, no migration was observed in the tests with aqueous food simulants, while migration was detected in fatty food simulants. In the specific migration analysis by GC-MS, di-2-ethylhexyl phthalate (DEHP) migration decreased by 50% with PLA coating. It is concluded that PLA coating of PVC stretch films may be a promising application to reduce migration.

Keywords

PVC PLA film coating migration functional barrier

Supporting Institution

This research was financially supported by Bursa Technical University Scientific Research Projects Office with a project number of 182N29.

Project Number

182N29

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GIDA İLE TEMAS EDEN POLİVİNİL KLORÜR BAZLI STREÇ FİLMLERDEKİ MİGRASYONUN POLİLAKTİK ASİT KATMANI İLE ENGELLENMESİ

Year 2024, Volume: 49 Issue: 4, 624 - 640, 14.08.2024

Adnan Fatih Dağdelen , Fatma Tuba Kıraç Demirel , Furkan Türker Sarıcaoğlu

https://doi.org/10.15237/gida.GD23131

Abstract

Bu çalışmada, Polivinil klorür (PVC) filmlerden geçen kalıntıların engellenmesi için biyobozunur polilaktik asit (PLA) kaplamaların etkinlikleri araştırılmıştır. Kloroform içerisinde ağırlıkça %5, 10, 15 ve 20 konsantrasyonlarda hazırlanan PLA filmler, sıcak preste (130 °C, 5 dk., 5 t) PVC film yüzeylerine ısıl olarak yapıştırılmıştır. Hazırlanan bu iki katlı filmlerde fiziksel, mekanik, FTIR ve migrasyon analizleri gerçekleştirilmiştir. PLA kaplama ile birlikte filmlerin kalınlıklar artmış, mekanik özellikleri azalmış ve renk değerlerinde bazı değişikler meydana gelmiştir. Sıcak pres sonucu filmlerin her iki yüzeyinde de yapısal bir değişiklik olmadığı FTIR ile tespit edilmiştir. Toplam migrasyon analizlerinden sulu gıda benzerlerini ile yapılan testlerde migrasyon gözlenmezken, yağlı gıda benzerlerinde migrasyon tespit edilmiştir. GC-MS ile yapılan spesifik migrasyon analizinde ise di-2-etilhekzil ftalat (DEHP) migrasyonu PLA kaplama ile birlikte %50 oranında azalmıştır. PVC streç filmlerin PLA ile kaplanmasının migrasyonu azaltmak için umut verici bir uygulama olabileceği sonucuna varılmıştır.

Keywords

PVC PLA Film Kaplama Migrasyon Fonksiyonel bariyer

Project Number

182N29

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Details

Primary Language English
Subjects Food Engineering, Food Packaging, Preservation and Processing, Food Technology
Journal Section Articles
Authors

Adnan Fatih Dağdelen 0000-0002-6777-273X

Fatma Tuba Kıraç Demirel 0000-0002-1730-7688

Furkan Türker Sarıcaoğlu 0000-0003-1173-5793

Project Number 182N29
Publication Date August 14, 2024
Submission Date November 16, 2023
Acceptance Date July 9, 2024
Published in Issue Year 2024 Volume: 49 Issue: 4

Cite

APA Dağdelen, A. F., Kıraç Demirel, F. T., & Sarıcaoğlu, F. T. (2024). PREVENTING OF MIGRATION IN FOOD CONTACT POLYVINYL CHLORIDE-BASED STRETCH FILMS WITH POLYLACTIC ACID LAYER. Gıda, 49(4), 624-640. https://doi.org/10.15237/gida.GD23131
AMA Dağdelen AF, Kıraç Demirel FT, Sarıcaoğlu FT. PREVENTING OF MIGRATION IN FOOD CONTACT POLYVINYL CHLORIDE-BASED STRETCH FILMS WITH POLYLACTIC ACID LAYER. The Journal of Food. August 2024;49(4):624-640. doi:10.15237/gida.GD23131
Chicago Dağdelen, Adnan Fatih, Fatma Tuba Kıraç Demirel, and Furkan Türker Sarıcaoğlu. “PREVENTING OF MIGRATION IN FOOD CONTACT POLYVINYL CHLORIDE-BASED STRETCH FILMS WITH POLYLACTIC ACID LAYER”. Gıda 49, no. 4 (August 2024): 624-40. https://doi.org/10.15237/gida.GD23131.
EndNote Dağdelen AF, Kıraç Demirel FT, Sarıcaoğlu FT (August 1, 2024) PREVENTING OF MIGRATION IN FOOD CONTACT POLYVINYL CHLORIDE-BASED STRETCH FILMS WITH POLYLACTIC ACID LAYER. Gıda 49 4 624–640.
IEEE A. F. Dağdelen, F. T. Kıraç Demirel, and F. T. Sarıcaoğlu, “PREVENTING OF MIGRATION IN FOOD CONTACT POLYVINYL CHLORIDE-BASED STRETCH FILMS WITH POLYLACTIC ACID LAYER”, The Journal of Food, vol. 49, no. 4, pp. 624–640, 2024, doi: 10.15237/gida.GD23131.
ISNAD Dağdelen, Adnan Fatih et al. “PREVENTING OF MIGRATION IN FOOD CONTACT POLYVINYL CHLORIDE-BASED STRETCH FILMS WITH POLYLACTIC ACID LAYER”. Gıda 49/4 (August 2024), 624-640. https://doi.org/10.15237/gida.GD23131.
JAMA Dağdelen AF, Kıraç Demirel FT, Sarıcaoğlu FT. PREVENTING OF MIGRATION IN FOOD CONTACT POLYVINYL CHLORIDE-BASED STRETCH FILMS WITH POLYLACTIC ACID LAYER. The Journal of Food. 2024;49:624–640.
MLA Dağdelen, Adnan Fatih et al. “PREVENTING OF MIGRATION IN FOOD CONTACT POLYVINYL CHLORIDE-BASED STRETCH FILMS WITH POLYLACTIC ACID LAYER”. Gıda, vol. 49, no. 4, 2024, pp. 624-40, doi:10.15237/gida.GD23131.
Vancouver Dağdelen AF, Kıraç Demirel FT, Sarıcaoğlu FT. PREVENTING OF MIGRATION IN FOOD CONTACT POLYVINYL CHLORIDE-BASED STRETCH FILMS WITH POLYLACTIC ACID LAYER. The Journal of Food. 2024;49(4):624-40.
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