Research Article
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Year 2023, , 78 - 88, 28.03.2023
https://doi.org/10.54287/gujsa.1239552

Abstract

References

  • Baytar, O., Ceyhan, A. A., & Şahin, O. (2018). İğde Çekirdeğinden Elde Edilen Aktif Karbon Kullanılarak Sulu Çözeltilerden Pb(II) Adsorpsiyonun İncelenmesi: İzoterm ve Kinetik. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, 7(2), 256-267. doi:10.17798/bitlisfen.422446
  • Bhattacharyya, K. G., & Gupta, S. S. (2008). Kaolinite and montmorillonite as adsorbents for Fe(III), Co(II) and Ni(II) in aqueous medium. Applied Clay Science, 41(1-2), 1-9. doi:10.1016/j.clay.2007.09.005
  • Borst, A. B., Smith, M. P., Finch, A. A., Estrade, G., Villanova-de-Benavent, C., Nason, P., Marquis, E., Horsburgh, N. J., Goodenough, K. M., Xu, C., Kynický, J., & Geraki, K. (2020). Adsorption of rare earth elements in regolith-hosted clay deposits. Nature Communications, 11(1), 4386. doi:10.1038/s41467-020-17801-5
  • Dal, M. C., Onursal, N., Arıca, E., & Yavuz, Ö. (2021). Diyarbakır Karacadağ Kırmızı Tepe Skoryası ile Cu(II) Adsorpsiyon Kinetiğinin İncelenmesi. Dicle Üniversitesi Mühendislik Fakültesi Mühendislik Dergisi, 12(2), 337-346. doi:10.24012/dumf.881650
  • Dawodu, F. A., & Akpomie, K. G. (2014). Simultaneous adsorption of Ni(II) and Mn(II) ions from aqueous solution unto a Nigerian kaolinite clay. Journal of Materials Research and Technology, 3(2), 129-141. doi:10.1016/j.jmrt.2014.03.002
  • Eren, E. (2008). Removal of copper ions by modified Unye clay, Turkey. Journal of Hazardous Materials, 159(2-3), 235-244. doi:10.1016/j.jhazmat.2008.02.035
  • Ewis, D., Ba-Abbad, M. M., Benamor, A., & El-Naas, M. H. (2022). Adsorption of organic water pollutants by clays and clay minerals composites: A comprehensive review. Applied Clay Science, 229, 106686. doi:10.1016/j.clay.2022.106686
  • Fu, C., Zhu, X., Dong, X., Zhao, P., & Wang, Z. (2021). Study of adsorption property and mechanism of lead(II) and cadmium(II) onto sulfhydryl modified attapulgite. Arabian Journal of Chemistry, 14(2), 102960. doi:10.1016/j.arabjc.2020.102960
  • Ho, Y. S., & Mckay, G. (1998). Kinetic Models for The Sorption of Dye from Aqueous Solution by Wood to Pollutant Removal on Various Sorbents. Process Safety and Environmental Protection, 76(2), 183-191. doi:10.1205/095758298529326
  • Jiang, M., Jin, X., Lu, X.-Q., & Chen, Z. (2010). Adsorption of Pb(II), Cd(II), Ni(II) and Cu(II) onto natural kaolinite clay. Desalination, 252(1-3), 33-39. doi:10.1016/j.desal.2009.11.005
  • Khan, U., & Rao, R. A. K. (2017). A high activity adsorbent of chemically modified Cucurbita moschata (a novel adsorbent) for the removal of Cu(II) and Ni(II) from aqueous solution: Synthesis, characterization and metal removal efficiency. Process Safety and Environmental Protection, 107, 238-258. doi:10.1016/j.psep.2017.02.008
  • Mu'azu, N. D., Bukhari, A., & Munef, K. (2020). Effect of montmorillonite content in natural Saudi Arabian clay on its adsorptive performance for single aqueous uptake of Cu(II) and Ni(II). Journal of King Saud University-Science, 32(1), 412-422. doi:10.1016/j.jksus.2018.06.003
  • Onursal, N., Dal, M. C., Kul, A. R., Yavuz, Ö. (2020). Cu(II) iyonlarının doğal karışık tipteki kil ile sulu ortamdan uzaklaştırılması, izoterm, kinetik ve termodinamik parametrelerin incelenmesi. Eurasia Journal of Mathematics, Engineering, Natural & Medical Sciences, 7(9), 85-103. doi:10.38065/euroasiaorg.84
  • Potgieter, J. H., Potgieter-Vermaak, S. S., & Kalibantonga, P. D. (2006). Heavy metals removal from solution by palygorskite clay. Minerals Engineering, 19(5), 463-470. doi:10.1016/j.mineng.2005.07.004
  • Sarı, A., & Tüzen, M. (2009). Kinetic and equilibrium studies of biosorption of Pb(II) and Cd(II) from aqueous solution by macro fungus (Amanita rubescens) biomass. Journal of Hazardous Materials, 164(2-3), 1004-1011. doi:10.1016/j.jhazmat.2008.09.002
  • Tirtom, V. N., Dincer, A., Becerik, S., Aydemir, T., & Celik, A. (2012). Comparative adsorption of Ni(II) and Cd(II) ions on epichlorohydrin crosslinked chitosan–clay composite beads in aqueous solution. Chemical Engineering Journal, 197, 379-386. doi:10.1016/j.cej.2012.05.059
  • Yavuz, Ö., Altunkaynak, Y., & Güzel, F. (2002). Removal of copper, nickel, cobalt and manganese from aqueous solution by kaolinite. Water Research, 37(4), 948-952. doi:10.1016/S0043-1354(02)00409-8
  • Yavuz, O., Guzel, R., Aydin, F., Tegin, I., & Ziyadanogullari, R. (2007). Removal of Cadmium and Lead from Aqueous Solution by Calcite. Polish Journal of Environmental Studies, 16(3), 467-471.

Adsorption Kinetics of Cu(II) and Ni(II) Ions Using Clay in Kulp District of Diyarbakır Province

Year 2023, , 78 - 88, 28.03.2023
https://doi.org/10.54287/gujsa.1239552

Abstract

In this study, the adsorption kinetics of Cu (II) and Ni (II) ions in the aqueous medium of the natural clay sample found in Kulp district of Diyarbakır province were investigated. For this purpose, the characterization of the natural clay mineral found in Kulp district of Diyarbakır province was carried out using X-Ray (XRD and XRF) and BET methods. The copper and nickel from the aqueous medium was measurmented at 25, 35 and 45 degrees. When the obtained data were applied to other models, it was found that it followed the Ho McKay equation for both ions. The qmax values here were measured as 1.51, 2.05, 2.30 for Cu (II) and 1.044, 1.086 and 1.741 for Ni (II) at the working temperatures, respectively. The increase in qmax values shows the accuracy of our study.

References

  • Baytar, O., Ceyhan, A. A., & Şahin, O. (2018). İğde Çekirdeğinden Elde Edilen Aktif Karbon Kullanılarak Sulu Çözeltilerden Pb(II) Adsorpsiyonun İncelenmesi: İzoterm ve Kinetik. Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, 7(2), 256-267. doi:10.17798/bitlisfen.422446
  • Bhattacharyya, K. G., & Gupta, S. S. (2008). Kaolinite and montmorillonite as adsorbents for Fe(III), Co(II) and Ni(II) in aqueous medium. Applied Clay Science, 41(1-2), 1-9. doi:10.1016/j.clay.2007.09.005
  • Borst, A. B., Smith, M. P., Finch, A. A., Estrade, G., Villanova-de-Benavent, C., Nason, P., Marquis, E., Horsburgh, N. J., Goodenough, K. M., Xu, C., Kynický, J., & Geraki, K. (2020). Adsorption of rare earth elements in regolith-hosted clay deposits. Nature Communications, 11(1), 4386. doi:10.1038/s41467-020-17801-5
  • Dal, M. C., Onursal, N., Arıca, E., & Yavuz, Ö. (2021). Diyarbakır Karacadağ Kırmızı Tepe Skoryası ile Cu(II) Adsorpsiyon Kinetiğinin İncelenmesi. Dicle Üniversitesi Mühendislik Fakültesi Mühendislik Dergisi, 12(2), 337-346. doi:10.24012/dumf.881650
  • Dawodu, F. A., & Akpomie, K. G. (2014). Simultaneous adsorption of Ni(II) and Mn(II) ions from aqueous solution unto a Nigerian kaolinite clay. Journal of Materials Research and Technology, 3(2), 129-141. doi:10.1016/j.jmrt.2014.03.002
  • Eren, E. (2008). Removal of copper ions by modified Unye clay, Turkey. Journal of Hazardous Materials, 159(2-3), 235-244. doi:10.1016/j.jhazmat.2008.02.035
  • Ewis, D., Ba-Abbad, M. M., Benamor, A., & El-Naas, M. H. (2022). Adsorption of organic water pollutants by clays and clay minerals composites: A comprehensive review. Applied Clay Science, 229, 106686. doi:10.1016/j.clay.2022.106686
  • Fu, C., Zhu, X., Dong, X., Zhao, P., & Wang, Z. (2021). Study of adsorption property and mechanism of lead(II) and cadmium(II) onto sulfhydryl modified attapulgite. Arabian Journal of Chemistry, 14(2), 102960. doi:10.1016/j.arabjc.2020.102960
  • Ho, Y. S., & Mckay, G. (1998). Kinetic Models for The Sorption of Dye from Aqueous Solution by Wood to Pollutant Removal on Various Sorbents. Process Safety and Environmental Protection, 76(2), 183-191. doi:10.1205/095758298529326
  • Jiang, M., Jin, X., Lu, X.-Q., & Chen, Z. (2010). Adsorption of Pb(II), Cd(II), Ni(II) and Cu(II) onto natural kaolinite clay. Desalination, 252(1-3), 33-39. doi:10.1016/j.desal.2009.11.005
  • Khan, U., & Rao, R. A. K. (2017). A high activity adsorbent of chemically modified Cucurbita moschata (a novel adsorbent) for the removal of Cu(II) and Ni(II) from aqueous solution: Synthesis, characterization and metal removal efficiency. Process Safety and Environmental Protection, 107, 238-258. doi:10.1016/j.psep.2017.02.008
  • Mu'azu, N. D., Bukhari, A., & Munef, K. (2020). Effect of montmorillonite content in natural Saudi Arabian clay on its adsorptive performance for single aqueous uptake of Cu(II) and Ni(II). Journal of King Saud University-Science, 32(1), 412-422. doi:10.1016/j.jksus.2018.06.003
  • Onursal, N., Dal, M. C., Kul, A. R., Yavuz, Ö. (2020). Cu(II) iyonlarının doğal karışık tipteki kil ile sulu ortamdan uzaklaştırılması, izoterm, kinetik ve termodinamik parametrelerin incelenmesi. Eurasia Journal of Mathematics, Engineering, Natural & Medical Sciences, 7(9), 85-103. doi:10.38065/euroasiaorg.84
  • Potgieter, J. H., Potgieter-Vermaak, S. S., & Kalibantonga, P. D. (2006). Heavy metals removal from solution by palygorskite clay. Minerals Engineering, 19(5), 463-470. doi:10.1016/j.mineng.2005.07.004
  • Sarı, A., & Tüzen, M. (2009). Kinetic and equilibrium studies of biosorption of Pb(II) and Cd(II) from aqueous solution by macro fungus (Amanita rubescens) biomass. Journal of Hazardous Materials, 164(2-3), 1004-1011. doi:10.1016/j.jhazmat.2008.09.002
  • Tirtom, V. N., Dincer, A., Becerik, S., Aydemir, T., & Celik, A. (2012). Comparative adsorption of Ni(II) and Cd(II) ions on epichlorohydrin crosslinked chitosan–clay composite beads in aqueous solution. Chemical Engineering Journal, 197, 379-386. doi:10.1016/j.cej.2012.05.059
  • Yavuz, Ö., Altunkaynak, Y., & Güzel, F. (2002). Removal of copper, nickel, cobalt and manganese from aqueous solution by kaolinite. Water Research, 37(4), 948-952. doi:10.1016/S0043-1354(02)00409-8
  • Yavuz, O., Guzel, R., Aydin, F., Tegin, I., & Ziyadanogullari, R. (2007). Removal of Cadmium and Lead from Aqueous Solution by Calcite. Polish Journal of Environmental Studies, 16(3), 467-471.
There are 18 citations in total.

Details

Primary Language English
Journal Section Chemistry
Authors

Emine Buldağ 0000-0001-9965-8272

Ömer Yavuz 0000-0002-5618-2881

Publication Date March 28, 2023
Submission Date January 19, 2023
Published in Issue Year 2023

Cite

APA Buldağ, E., & Yavuz, Ö. (2023). Adsorption Kinetics of Cu(II) and Ni(II) Ions Using Clay in Kulp District of Diyarbakır Province. Gazi University Journal of Science Part A: Engineering and Innovation, 10(1), 78-88. https://doi.org/10.54287/gujsa.1239552