Vibrational Spectroscopic Study on the Hofmann-Td-type 1,4-Dioxane Clathrates

Year 2019, Volume: 47 Issue: 1, 99 - 106, 01.02.2019

Celal Bayrak

Abstract

Two new 1,4-dioxane-Td-type clathrates of the form Cd(CPA)2M(CN)4.2C4H8O2 (CPA= cyclopentylamine; M = Cd or Hg) have been prepared in powder form and their FT-IR (400-4000 cm-1), FT-Raman (70-4000 cm-1), far-IR (50-400 cm-1) spectra, X-ray diffraction (XRD) and elemental analyses are reported. The spectral data suggest that the host frameworks of these compounds are similar to those of the Hofmann-Td-type benzene clathrates.

Keywords

Cyclopentylamine, 1, 4-dioxane, FT-IR, FT-Raman, far-IR spectra, XRD, Hofmann-Td-type clathrates

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