Structural Characterization of Complexes Formed by Cadmium (II) Transition Metal with Schiff Bases

Year 2024, Volume: 1 Issue: 1, 22 - 28, 31.07.2024

Şenol Yavuz , Dursun Ali Köse

Abstract

Schiff bases are condensation product compounds obtained from the reaction of carbonyl group compounds with primary amines. The C=N bond formed due to the reaction is called the azomethine bond or imine bond. Coordination compounds formed by Schiff bases with metals have broad application areas and play essential roles as catalysts, biological agents, analytical reagents, materials, and environmental solutions. These compounds' various chemical and physical properties increase their importance in basic science research and industrial applications. These compounds' various chemical and physical properties increase their importance in basic science research and industrial applications. In this study, Schiff base ligands (3,5) were synthesized from the reaction of vanillin, an aldehyde compound, with primary amines in an acidic medium. The structure of the synthesized Schiff base ligands was characterized by 1H NMR, 13C NMR, and FTIR spectroscopy, and new metal complexes (6,7) were synthesized from the reaction with cadmium metal salt (Cd(NO3)2). The structures of the synthesized metal complex compounds were characterized by elemental analysis, FTIR, and thermogravimetric analysis, and their properties were investigated. Although the magnetic susceptibility of cadmium was investigated in the literature on metal complex studies, magnetic susceptibility analysis was not deemed necessary due to the low magnetic susceptibility of cadmium.

Keywords

Schiff Base, Cadmium (II), Ligand, Metal Complex, Thermal Stability

References

• Schiff H. Untersuchungen über salicinderivate, Justus Liebigs Annalen der Chemie, 150 (2), 193-200, 1869.
• Karaca Ö. Yeni Schiff bazı bileşiklerinin sentezi ve yapılarının aydınlatılması. Politeknik Dergisi 2018; 21(1): 245-249.
• Abu-Dief AM, Mohamed IMA. A review on versatile applications of transition metal complexes incorporating Schiff bases. Beni-Suef University Journal of Basic and Applied Sciences 2015; 4(2):119-133.https://doi.org/10.1016/j.bjbas.2015.05.004.
• Taşkın OK, Öztürk ÖF, Canpolat E. Yeni Bir Schiff Bazı ve Geçiş Metalleri İle Oluşturdukları Komplekslerin Sentezi ve Karakterizasyonu, Bitlis Eren Üniversitesi Fen Bilimleri Dergisi 2012; 1(1); 34-39.
• Silva CM, Silva DN, Modolo LV, Alves RB, Resende MA, Martins CVB, Fatima A. Schiff Bases: a Short Review of Their Antimicrobial Activities 2, Cario University Journal of Advanced Research 2011;1-8.
• Sılku P, Özkınalı S, Öztürk Z, Asan A., Köse DA. Synthesis of novel Schiff Bases containing acryloyl moiety and the investigation of spectroscopic and electrochemical properties, Journal of Molecular Structure 2016; 1116:72-83. https://doi.org/10.1016/j.molstruc.2016.03.028.
• Özkınalı S, Yavuz Ş, Tosun T, Köse DA, Gür M, Kocaokutgen H. Synthesis, Spectroscopic and Thermal Analysis and Investigation of Dyeing Properties of o‐Hydroxy Schiff Bases and Their Metal Complexes. ChemistrySelect 2020; 5(40): 12624-12634.
• Koç E. Tripodal Schiff Bazlı Ligandların Sentezi ve Metal Komplekslerinin İncelenmesi. Doktora Tezi, Selçuk Üniversitesi Fen Bilimleri Enstitüsü, Konya ,2006.
• Patai S. The Chemistry of Carbon-Nitrogen Double Bond. Interscience Publisher, London 1970; 360p.
• Seçkin T, Köytepe S, Demir S, Özdemir İ, Çetinkaya B. Novel type of metal-containing polyimides for the heck and Suzuki-Miyaura cross-coupling reactions as highly active catalysts. J. Inorg. Organomet P. 2003;13(4): 223-235.
• Ashraf M, Wajid A, Mahmood K, Maah M, Yusoff I. Spectral Investigation of the Activities of Amino Substituted Bases. Orient. J. Chem. 2011; 27: 363–372.
• Soroceanu A, Bargan A. Advanced and Biomedical Applications of Schiff-Base Ligands and Their Metal Complexes: A Review. Crystals 2022.
• Petruccı HR, Harwood SW, Herrıng GF, Qın W, Long S, Panunzıo M, Bıondı S, Schiff Bases: A Short Survey on an Evergreen Chemistry Tool. Molecules 2008; 18: 12264-12289.
• Agrawal YK, Talati JD, Shah MD, Desai MN, Shah NK. Schiff bases of ethylenediamine as corrosion inhibitors of zinc in sulphuric acid. Corrosion Science 2004; 46(3): 633-651.
• Desai MN, Desai MB, Shah CB, Desai SM. Schiff bases as corrosion inhibitors for mild steel in hydrochloric acit solutions. Corrosion Science 1986; 26: 827.
• Niederhoffer EC, Timmons JH, Martell AE. Thermodynamics of oxygen binding in natural and synthetic dioxygen complexes. Chemical Reviews 1984; 84(2): 137-203.
• Özşahin AD, Bozhan N. Bazı Schiff Bazlarının Saccharomyces cerevisiae BY4741 Kültür Ortamlarında Biyokimyasal Parametreler Üzerine Etkileri. Kahramanmaraş Sütçü İmam Üniversitesi Tarım ve Doğa Dergisi 2018;21(2): 131-140.
• Karlin KD, Tyekkerz L. Bioorganic Chemistry of Cupper. Chapman and Hill, NewYork 1993.
• Kuduk J, Trynda L. Impact of K2 PtCl6 on the structure of human serum albumin and its binding ability of heme and bilirubin. Journal of Inorganic Biochemistry 1994;53:4: 249-260.
• Mohamed GG. Synthesis, characterization and biological activity of bis(phenylimine) Schiff base ligands and their metal complexes. Spectrochim. Acta A 2006; 64: 188.
• Data S, Banerjee P, Banerjee RD, Sarkar GM, Saha SK, Dey K, Maiti RK, Sen RK, Bhar JK. Antimicrobial, insect sterilizing and ovicidal activity of some oxo-vanadium(IV) and oxo-vanadium(V) complexes. Agents Actions 1982;12(4): 543-51.
• Rao NS, Reddy MG. Studies on the synthesis, characterisation and antimicrobial activity of new Co(II), Ni(II) and Zn(II) complexes of Schiff base derived from ninhydrin and glycine. Biol. Met. 1990; 3(1):19-23.
• Liu Y, Yang L, Yin D, Dang Y, Yang L, Zou Q, Li J, Sun J. Solvent-free synthesis, characterization, biological activity of schiff bases and their metal (II) complexes derived from ferrocenyl chalcone. Journal of Organometallic Chemistry 2019; 899: 120903.
• Desai S, Desai P, Desai K. Synthesis of Some Schiff Bases,Thiazolidinones and Azetidinones Derived From 2,6-Diaminobenzo[1,2-D:4,5-D'] Bisthiazole and Their Anticancer Activities. Heterocyclic Communications 2001;7(1): 83-90. https://doi.org/10.1515/HC.2001.7.1.83
• Boulechfar C, Ferkous H, Delimi A, Djedouani A, Kahlouche A, Boublia A, Benguerba, Y. Schiff bases and their metal Complexes: A review on the history, synthesis, and applications. Inorganic Chemistry Communications 2023; 150: 110451.
• Bhattacharyya R, Roy AS. Catalytic Activity of Schiff Base Complexes in Organic Reactions. Journal of Catalysis and Chemical Engineering 2012; 14(2): 56-63.
• De Vos DE, Verpoort F. Photophysical Properties of Schiff Base Metal Complexes. Coordination Chemistry Reviews 2003; 245(1-2): 149-160. DOI: 10.1016/S0010-8545(03)00251-5.
• Da Silva CM, Da Silva DL, Modolo LV, Alves RB, De Resende MA, Martins CVB,  De Fátima A. Schiff Bases: A Short Review of Their Antimicrobial Activities. Journal of Advanced Research 2011; 2(1): 1-8. DOI: 10.1016/j.jare.2010.05.004.
• Atwood JL, Steed JW. Schiff Base Complexes in Supramolecular Chemistry. Supramolecular Chemistry 2004; 16(5): 399-409. DOI: 10.1080/10610270412331334021
• Mohapatra M, Anand, S. Cadmium Schiff Base Complexes for Environmental Remediation. Journal of Environmental Chemical Engineering 2010; 3(2):89-97. DOI: 10.1016/j.jece.2010.02.005.
• Sutradhar M. Coordination Chemistry of Schiff Bases: Structural Diversity and Applications. Coordination Chemistry Reviews 2017; 344: 276-299. DOI: 10.1016/j.ccr.2016.01.010.
• Boulechfar C, Ferkous H, Delimi A, Djedouani A, Kahlouche A, Boublia A, Benguerba Y. Schiff bases and their metal Complexes: A review on the history, synthesis, and applications. Inorganic Chemistry Communications 2023;150:110451.
• Mohamed G G, Omar MM, Hindy AM. Synthesis, characterization and biological activity of some transition metals with Schiff base derived from 2-thiophene carboxaldehyde and aminobenzoic acid. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2005; 62(4-5): 1140-1150.
• Refat MS. Synthesis and characterization of some transition metal complexes with Schiff base ligand derived from 4,6-diacetylresorcinol. Journal of Molecular Structure 2007; 842(1-3): 24-37
• Kaim W, Schwederski B, Klein A. Bioinorganic Chemistry--Inorganic Elements in the Chemistry of Life: An Introduction and Guide. John Wiley & Sons ;2013
• Holleman AF, Wiberg E.Inorganic Chemistry. Academic Press; 2001.