Application of Sepiolite-Poly(vinylimidazole) composite for the removal of Cu(II) from aqueous solution: Isotherm and thermodynamics studies

Ali Kara; Muhsin Kılıç; Nalan Tekin; Nuray Dinibütün; Akif Şafaklı

doi:10.32571/ijct.341542

Research Article

Application of Sepiolite-Poly(vinylimidazole) composite for the removal of Cu(II) from aqueous solution: Isotherm and thermodynamics studies

Year 2018, Volume: 2 Issue: 1, 20 - 33, 16.02.2018

Ali Kara , Muhsin Kılıç , Nalan Tekin , Nuray Dinibütün Akif Şafaklı

https://doi.org/10.32571/ijct.341542

Cited By: 3

Abstract

For removal of Cu(II) ions from aqueous solution, a
novel composite was prepared from 1-vinyl imidazole and sepiolite by the
technique of in-situ polymerization. Adsorption of Cu(II) ions from aqueous solution onto Sepiolite-Poly(vinylimidazole) composite has been studied at 277,
298, 318, and 338 K and the experimental data were analyzed using fourteen
isotherm models. The determination
coefficients (R²) were determined for each
isotherm analysis. The determination
coefficients demonstrated
that in general the accuracy of models to fit experimental data improves with
the number of parameters. The Langmuir model provided the best fit to the
experimental data among the two-parameter isotherms. The Toth model provided
the best fit to the data among the three-parameter models. Adsorption isotherm
modeling shows that the interaction of Cu(II) with Sepiolite-Poly(vinylimidazole) composite surface is localized to
monolayer sorption and adsorption is an endothermic process. Additionally, adsorption
experiments showed that Sepiolite-Poly(vinylimidazole) composite
can be used as an effective adsorbent for the removal
of Cu(II) ions from aqueous solution.

Keywords

Clay, composite, heavy metal, isotherms, nonlinear methods

References

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8. Karapinar, N.; Donat, R. Desalination 2009, 249, 123–129.
9. Wan Ngah, W.S.; Fatinathan, S. J. Environ. Manag. 2010, 91, 958–969.
10. Serencam, H.; Ozdes, D.; Duran, C.; Senturk, H.B. Desalin. Water Treat. 2014, 52, 3226–3236.
11. Ibrahim, H.S.; Ammar, N.S.; Ghafar, H.H.A.; Farahat, M. Desalin. Water Treat. 2012, 48, 320–328.
12. Nadaroglu, H.; Kalkan, E.; Demir, N. Desalination 2010, 251, 90–95.
13. Wan Ngah, W.S.; Teong, L.C.; Toh, R.H.; Hanafiah, M.A.K.M. Chem. Eng. J. 2013, 223, 231–238.
14. Keshtkar, A.R.; Irani, M.; Moosavian, M.A. J. Taiwan Inst. Chem. Eng. 2013, 44, 279–286.
15. Hu, X.-J.; Liu, Y.-G.; Wang, H.; Chen, A.-W.: Zeng, G.-M.; Liu, S.-M.; Guo, Y.-M.; Hu, X.; Li, T.-T.; Wang, Y.-Q.; Zhou, L.; Liu, S.-H. Sep. Purif. Technol. 2013, 108, 189–195.
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17. Yu, Y.; Qi, S.; Zhan, J.; Wu, Z.; Yang, X.; Wu, D. Mater. Res. Bull. 2011, 46, 1593–1599.
18. Kavas, H.; Baykal, A.; Senel, M.; Kaynak, M. Mater. Res. Bull. 2013, 48, 3973–3980.
19. Tekin, N.; Kadıncı, E.; Demirbaş, Ö.; Alkan, M.; Kara, A. J. Colloid Interf. Sci. 2006, 296, 472–479.
20. Gurbuz, O.; Sahan, Y.; Kara, A.; Osman, B. Hacettepe J. Biol. Chem. 2009, 37, 353–357.
21. Caner, H.; Yilmaz, E.; Yilmaz, O. Carbohyd. Polym. 2007, 69, 318–325.
22. Bergaya, F.; Jaber, M.; Lambert, J. F.; Galimberti, M. Rubber-Clay Nanocomposites: Science, Technology, and Applications. (1. Clay and Clay Minerals). Wiley, 2011.
23. Fukushima, K.; Tabuani, D.; Camino, G. Mater. Sci. Eng. C. 2009, 29, 1433–1441.
24. Kara, A.; Demirbel, E.; Sözeri, H.; Küçük, İ.; Ovalıoğlu, H. Hacettepe J. Biol. Chem. 2014, 42, 299–312.
25. Ho, Y.S. Carbon 2004, 42, 2115–2116.
26. Kumar, K.V. J. Hazard. Mater. B. 2006,136, 197–202.
27. Tekin, N.; Kaya, A.U.; Esmer, K.; Kara, A. Appl. Clay Sci. 2012, 57, 32–38.
28. Al-Degs, Y.S.; Abu-El-Halawa, R.; Abu-Alrub, S.S. Chem. Eng. J. 2012, 191, 185– 194.
29. Freundlich, H.M.F. Z. Phys. Chem. 1906, 57, 385–471.
30. Rengaraj, S.; Yeon, J.-W.; Kim, Y.; Jung, Y.; Ha, Y.-K.; Kim, W.-H. J. Hazard. Mater. 2007, 143, 469–477.
31. Langmuir, I. J. Am. Chem. Soc. 1916, 38, 2221–2295.
32. Dubinin, M.M. Chem. Rev. 1960, 60, 235–266.
33. Kundu, S.; Gupta, A.K. Chem. Eng. J. 2006, 122, 93–106.
34. Halsey, G. J. Chem. Phys. 1948, 16, 931-937.
35. Redlich, O.; Peterson, D.L. J. Phys. Chem. 1959, 63, 1024.
36. Sips, R.J. J. Chem. Phys. 1948, 16, 490–495.
37. Foo, K.Y.; Hameed, B.H. Chem. Eng. J. 2010, 156, 2–10.
38. Khan, A.R.; Ataullah, R.; Al-Haddad, A. J. Colloid Interf. Sci. 1997, 194, 154–165.
39. Liu, Y.; Liu, Y.-J. Sep. Purif. Technol. 2008, 61, 229–242.
40. Vijayaraghavan, K.; Padmesh, T.V.N.; Palanivelu, K.; Velan, M. J. Hazard. Mater. B. 2006, 133, 304–308.
41. Toth, J. Acta Chem. Acad. Sci. Hungaria. 1971, 69, 311–317.
42. Koble, R.A.; Corrigan, T.E. Ind. Eng. Chem. 1952, 44, 383–387.
43. Basha, S.; Murthy, Z.V.P.; Jha, B. Ind. Eng. Chem. Res. 2008, 47, 980–986.
44. Fritz, W.; Schlunder, E.U. Chem. Eng. Sci. 1974, 29, 1279–1282.
45. Rangabhashiyam, S.; Anu, N.; Nandagopal, M.S.G.; Selvaraju, N. J. Environ. Chem. Eng. 2014, 2, 398–414.
46. Beauger, C.; Lainé, G.; Burr, A.; Taguet, A.; Otazaghine, B.; Rigacci, A. J. Membr. Sci. 2013, 130, 167–179.
47. Alkan, M.; Tekin, G.; Namli, H. Micropor. Mesopor. Mat. 2005, 84, 75–83.
48. Wan, C.; Chen, B. Nanoscale. 2011, 3, 693–700.
49. Unal, H. I.; Erol, O.; Gumus, O.Y. Colloids and Surfaces A: Physicochem. Eng. Aspects. 2014, 442, 132– 138.
50. Chen, Z.; Yang, J.; Yin, D.; Li, Y.; Wu, S.; Lu, J.; Wang, J. J. Membrane Sci. 2010, 349, 175–182.
51. Soheilmoghaddam, M.; Wahit, M.U.; Yussuf, A.A.; Al-Saleh, M.A.; Whye, W.T. Polym. Test. 2014, 33, 121–130.
52. Lu, P.; Xu, J.; Liu, K. J. Appl. Polym. Sci. 2011, 119, 3043–3050.
53. Killeen, D.; Frydrych, M.; Chen, B. Mater. Sci. Eng. C. 2012, 32, 749-757.
54. Jang, J.; Kim, H. J. Appl. Polym. Sci. 1995, 56, 1495–1504.
55. Fodor, C.; Bozi, J.; Blazsoi, M.; Ivain, B. Macromolecules 2012, 45, 8953–8960.
56. Frost, R.L.; Kristof, J.; Horvath, E. J. Therm. Anal. Calorim. 2009, 98, 749–755.
57. Serna, C.; Ahlrichs, J.L.; Serratosa, J.M. Clay Miner. 1975, 23, 452–457.
58. Tartaglione, G.; Tabuani, D.; Camino, G.; Moisio, M. Compos. Sci. Technol. 2008, 68, 451–460.
59. Bidsorkhi, H.C.; Soheilmoghaddam, M.; Pour, R.H.; Adelnia, H.; Mohamad, Z. Polym. Test. 2014, 37, 117–122.
60. Ghasemi, Z.; Seif, A.; Ahmadi, T.S.; Zargar, B.; Rashidi, F.; Rouzbahani, G.M. Adv. Powder Technol. 2012, 23, 148–156.
61. McKay, G.; Mesdaghinia, A.; Nasseri, S.; Hadi, M.; Aminabad, M.S. Chem. Eng. J. 2014, 251, 236–247.
62. Oubagaranadin, J.U.K.; Murthy, Z.V.P. Appl. Clay Sci. 2010, 50, 409–413.
63. Kumar, K.V. Dyes Pigments. 2007, 74, 595–597.
64. Özcan, A.; Ömeroğlu, Ç.; Erdoğan, Y.; Özcan, A.S. J. Hazard. Mater. 2007, 140, 173–179.

Year 2018, Volume: 2 Issue: 1, 20 - 33, 16.02.2018

Ali Kara , Muhsin Kılıç , Nalan Tekin , Nuray Dinibütün Akif Şafaklı

https://doi.org/10.32571/ijct.341542

Cited By: 3

Abstract

References

1. Kizilkaya, B.; Tekinay, A. A.; Dilgin, Y. Desalination 2010, 264, 37–47.
2. Wu, X.-W.; Ma, H.-W.; Zhang, L.-T.; Wang, F.-J. Appl. Surf. Sci. 2012, 261, 902– 907.
3. Dalida, M.L.P.; Mariano, A.F.V.; Futalan, C.M.; Kan, C.-C.; Tsai, W.-C.; Wan, M.-W. Desaliation 2011, 275, 154–159.
4. Wan Ngah, W.S.; Teong, L.C.; Toh, R.H.; Hanafiah, M.A.K.M. Chem. Eng. J. 2012, 209, 46–53.
5. Liu, Y.; Chen, M.; Hao, Y. Chem. Eng. J. 2013, 218, 46–54.
6. Pellera, F.-M.; Giannis, A.; Kalderis, D.; Anastasiadou, K.; Stegmann, R.; Wang, J.-Y.; Gidarakos, E. J. Environ. Manag. 2012, 96, 35–42.
7. Chen, J.J.; Ahmad, A.L.; Ooi, B.S. J. Environ. Chem. Eng. 2013, 1, 339–348.
8. Karapinar, N.; Donat, R. Desalination 2009, 249, 123–129.
9. Wan Ngah, W.S.; Fatinathan, S. J. Environ. Manag. 2010, 91, 958–969.
10. Serencam, H.; Ozdes, D.; Duran, C.; Senturk, H.B. Desalin. Water Treat. 2014, 52, 3226–3236.
11. Ibrahim, H.S.; Ammar, N.S.; Ghafar, H.H.A.; Farahat, M. Desalin. Water Treat. 2012, 48, 320–328.
12. Nadaroglu, H.; Kalkan, E.; Demir, N. Desalination 2010, 251, 90–95.
13. Wan Ngah, W.S.; Teong, L.C.; Toh, R.H.; Hanafiah, M.A.K.M. Chem. Eng. J. 2013, 223, 231–238.
14. Keshtkar, A.R.; Irani, M.; Moosavian, M.A. J. Taiwan Inst. Chem. Eng. 2013, 44, 279–286.
15. Hu, X.-J.; Liu, Y.-G.; Wang, H.; Chen, A.-W.: Zeng, G.-M.; Liu, S.-M.; Guo, Y.-M.; Hu, X.; Li, T.-T.; Wang, Y.-Q.; Zhou, L.; Liu, S.-H. Sep. Purif. Technol. 2013, 108, 189–195.
16. Anirudhan, T.S.; Suchithra, P.S. Chem. Eng. J. 2010, 156, 146–156.
17. Yu, Y.; Qi, S.; Zhan, J.; Wu, Z.; Yang, X.; Wu, D. Mater. Res. Bull. 2011, 46, 1593–1599.
18. Kavas, H.; Baykal, A.; Senel, M.; Kaynak, M. Mater. Res. Bull. 2013, 48, 3973–3980.
19. Tekin, N.; Kadıncı, E.; Demirbaş, Ö.; Alkan, M.; Kara, A. J. Colloid Interf. Sci. 2006, 296, 472–479.
20. Gurbuz, O.; Sahan, Y.; Kara, A.; Osman, B. Hacettepe J. Biol. Chem. 2009, 37, 353–357.
21. Caner, H.; Yilmaz, E.; Yilmaz, O. Carbohyd. Polym. 2007, 69, 318–325.
22. Bergaya, F.; Jaber, M.; Lambert, J. F.; Galimberti, M. Rubber-Clay Nanocomposites: Science, Technology, and Applications. (1. Clay and Clay Minerals). Wiley, 2011.
23. Fukushima, K.; Tabuani, D.; Camino, G. Mater. Sci. Eng. C. 2009, 29, 1433–1441.
24. Kara, A.; Demirbel, E.; Sözeri, H.; Küçük, İ.; Ovalıoğlu, H. Hacettepe J. Biol. Chem. 2014, 42, 299–312.
25. Ho, Y.S. Carbon 2004, 42, 2115–2116.
26. Kumar, K.V. J. Hazard. Mater. B. 2006,136, 197–202.
27. Tekin, N.; Kaya, A.U.; Esmer, K.; Kara, A. Appl. Clay Sci. 2012, 57, 32–38.
28. Al-Degs, Y.S.; Abu-El-Halawa, R.; Abu-Alrub, S.S. Chem. Eng. J. 2012, 191, 185– 194.
29. Freundlich, H.M.F. Z. Phys. Chem. 1906, 57, 385–471.
30. Rengaraj, S.; Yeon, J.-W.; Kim, Y.; Jung, Y.; Ha, Y.-K.; Kim, W.-H. J. Hazard. Mater. 2007, 143, 469–477.
31. Langmuir, I. J. Am. Chem. Soc. 1916, 38, 2221–2295.
32. Dubinin, M.M. Chem. Rev. 1960, 60, 235–266.
33. Kundu, S.; Gupta, A.K. Chem. Eng. J. 2006, 122, 93–106.
34. Halsey, G. J. Chem. Phys. 1948, 16, 931-937.
35. Redlich, O.; Peterson, D.L. J. Phys. Chem. 1959, 63, 1024.
36. Sips, R.J. J. Chem. Phys. 1948, 16, 490–495.
37. Foo, K.Y.; Hameed, B.H. Chem. Eng. J. 2010, 156, 2–10.
38. Khan, A.R.; Ataullah, R.; Al-Haddad, A. J. Colloid Interf. Sci. 1997, 194, 154–165.
39. Liu, Y.; Liu, Y.-J. Sep. Purif. Technol. 2008, 61, 229–242.
40. Vijayaraghavan, K.; Padmesh, T.V.N.; Palanivelu, K.; Velan, M. J. Hazard. Mater. B. 2006, 133, 304–308.
41. Toth, J. Acta Chem. Acad. Sci. Hungaria. 1971, 69, 311–317.
42. Koble, R.A.; Corrigan, T.E. Ind. Eng. Chem. 1952, 44, 383–387.
43. Basha, S.; Murthy, Z.V.P.; Jha, B. Ind. Eng. Chem. Res. 2008, 47, 980–986.
44. Fritz, W.; Schlunder, E.U. Chem. Eng. Sci. 1974, 29, 1279–1282.
45. Rangabhashiyam, S.; Anu, N.; Nandagopal, M.S.G.; Selvaraju, N. J. Environ. Chem. Eng. 2014, 2, 398–414.
46. Beauger, C.; Lainé, G.; Burr, A.; Taguet, A.; Otazaghine, B.; Rigacci, A. J. Membr. Sci. 2013, 130, 167–179.
47. Alkan, M.; Tekin, G.; Namli, H. Micropor. Mesopor. Mat. 2005, 84, 75–83.
48. Wan, C.; Chen, B. Nanoscale. 2011, 3, 693–700.
49. Unal, H. I.; Erol, O.; Gumus, O.Y. Colloids and Surfaces A: Physicochem. Eng. Aspects. 2014, 442, 132– 138.
50. Chen, Z.; Yang, J.; Yin, D.; Li, Y.; Wu, S.; Lu, J.; Wang, J. J. Membrane Sci. 2010, 349, 175–182.
51. Soheilmoghaddam, M.; Wahit, M.U.; Yussuf, A.A.; Al-Saleh, M.A.; Whye, W.T. Polym. Test. 2014, 33, 121–130.
52. Lu, P.; Xu, J.; Liu, K. J. Appl. Polym. Sci. 2011, 119, 3043–3050.
53. Killeen, D.; Frydrych, M.; Chen, B. Mater. Sci. Eng. C. 2012, 32, 749-757.
54. Jang, J.; Kim, H. J. Appl. Polym. Sci. 1995, 56, 1495–1504.
55. Fodor, C.; Bozi, J.; Blazsoi, M.; Ivain, B. Macromolecules 2012, 45, 8953–8960.
56. Frost, R.L.; Kristof, J.; Horvath, E. J. Therm. Anal. Calorim. 2009, 98, 749–755.
57. Serna, C.; Ahlrichs, J.L.; Serratosa, J.M. Clay Miner. 1975, 23, 452–457.
58. Tartaglione, G.; Tabuani, D.; Camino, G.; Moisio, M. Compos. Sci. Technol. 2008, 68, 451–460.
59. Bidsorkhi, H.C.; Soheilmoghaddam, M.; Pour, R.H.; Adelnia, H.; Mohamad, Z. Polym. Test. 2014, 37, 117–122.
60. Ghasemi, Z.; Seif, A.; Ahmadi, T.S.; Zargar, B.; Rashidi, F.; Rouzbahani, G.M. Adv. Powder Technol. 2012, 23, 148–156.
61. McKay, G.; Mesdaghinia, A.; Nasseri, S.; Hadi, M.; Aminabad, M.S. Chem. Eng. J. 2014, 251, 236–247.
62. Oubagaranadin, J.U.K.; Murthy, Z.V.P. Appl. Clay Sci. 2010, 50, 409–413.
63. Kumar, K.V. Dyes Pigments. 2007, 74, 595–597.
64. Özcan, A.; Ömeroğlu, Ç.; Erdoğan, Y.; Özcan, A.S. J. Hazard. Mater. 2007, 140, 173–179.

There are 64 citations in total.

Details

Primary Language	English
Subjects	Chemical Engineering
Journal Section	Research Articles
Authors	Ali Kara 0000-0003-2457-6314 Muhsin Kılıç Nalan Tekin Nuray Dinibütün This is me Akif Şafaklı This is me
Publication Date	February 16, 2018
Published in Issue	Year 2018 Volume: 2 Issue: 1

Cite

APA	Kara, A., Kılıç, M., Tekin, N., Dinibütün, N., et al. (2018). Application of Sepiolite-Poly(vinylimidazole) composite for the removal of Cu(II) from aqueous solution: Isotherm and thermodynamics studies. International Journal of Chemistry and Technology, 2(1), 20-33. https://doi.org/10.32571/ijct.341542
AMA	Kara A, Kılıç M, Tekin N, Dinibütün N, Şafaklı A. Application of Sepiolite-Poly(vinylimidazole) composite for the removal of Cu(II) from aqueous solution: Isotherm and thermodynamics studies. Int. J. Chem. Technol. June 2018;2(1):20-33. doi:10.32571/ijct.341542
Chicago	Kara, Ali, Muhsin Kılıç, Nalan Tekin, Nuray Dinibütün, and Akif Şafaklı. “Application of Sepiolite-Poly(vinylimidazole) Composite for the Removal of Cu(II) from Aqueous Solution: Isotherm and Thermodynamics Studies”. International Journal of Chemistry and Technology 2, no. 1 (June 2018): 20-33. https://doi.org/10.32571/ijct.341542.
EndNote	Kara A, Kılıç M, Tekin N, Dinibütün N, Şafaklı A (June 1, 2018) Application of Sepiolite-Poly(vinylimidazole) composite for the removal of Cu(II) from aqueous solution: Isotherm and thermodynamics studies. International Journal of Chemistry and Technology 2 1 20–33.
IEEE	A. Kara, M. Kılıç, N. Tekin, N. Dinibütün, and A. Şafaklı, “Application of Sepiolite-Poly(vinylimidazole) composite for the removal of Cu(II) from aqueous solution: Isotherm and thermodynamics studies”, Int. J. Chem. Technol., vol. 2, no. 1, pp. 20–33, 2018, doi: 10.32571/ijct.341542.
ISNAD	Kara, Ali et al. “Application of Sepiolite-Poly(vinylimidazole) Composite for the Removal of Cu(II) from Aqueous Solution: Isotherm and Thermodynamics Studies”. International Journal of Chemistry and Technology 2/1 (June 2018), 20-33. https://doi.org/10.32571/ijct.341542.
JAMA	Kara A, Kılıç M, Tekin N, Dinibütün N, Şafaklı A. Application of Sepiolite-Poly(vinylimidazole) composite for the removal of Cu(II) from aqueous solution: Isotherm and thermodynamics studies. Int. J. Chem. Technol. 2018;2:20–33.
MLA	Kara, Ali et al. “Application of Sepiolite-Poly(vinylimidazole) Composite for the Removal of Cu(II) from Aqueous Solution: Isotherm and Thermodynamics Studies”. International Journal of Chemistry and Technology, vol. 2, no. 1, 2018, pp. 20-33, doi:10.32571/ijct.341542.
Vancouver	Kara A, Kılıç M, Tekin N, Dinibütün N, Şafaklı A. Application of Sepiolite-Poly(vinylimidazole) composite for the removal of Cu(II) from aqueous solution: Isotherm and thermodynamics studies. Int. J. Chem. Technol. 2018;2(1):20-33.