Eco-friendly synthesis of nano copper and its use in fenton-like reactions for methylene blue degradation

Demet Demirci Gültekin; Azize Alaylı; Hayrunnisa Nadaroglu

doi:10.32571/ijct.724056

Research Article

Year 2020, Volume: 4 Issue: 1, 71 - 78, 30.06.2020

Demet Demirci Gültekin , Azize Alaylı , Hayrunnisa Nadaroglu

https://doi.org/10.32571/ijct.724056

Cited By: 1

Abstract

References

1. Sen, T. Int. J. Environ. Pollut. Control Manage. 2011, 3 (1), 1-10.
2. Bombardelli, E.; Morazzoni, P. Fitoterapia (Milano). 1995, 66 (4), 291-317.
3. Fan, P.; Lou, H.; Yu, W.; Ren, D.; Ma, B.; Ji, M. Tetrahedron Lett. 2004, 45 (15), 3163-3166.
4. Królikowska, A.; Kudelski, A.; Michota, A.; Bukowska. J. Surf. Sci. 2003, 532, 227-232.
5. Catauro, M.; Raucci, M. G.; De Gaetano, F.; Marotta, A. J. Mater. Sci-Mater. M. 2004, 15 (7), 831-837.
6. Crabtree, J. H.; Burchette, R. J.; Siddiqi, R. A.; Huen I. T.; Hadnott, L. L.; Fishman, A. Periton. Dialysis Int. 2003, 23 (4), 368-374.
7. Sharma, V. K.; Yngard, R. A.; Lin, Y. Adv. Colloid Interfac. 2009, 145 (1-2), 83-96.
8. Balantrapu, K.; Goia, D. V. J. Mater. Res. 2009, 24 (9), 2828-2836.
9. Taleb, A.; Petit, C.; Pileni, M. P. Chem. Mater. 1997, 9 (4), 950-959.
10. Begum, N. A.; Mondal, S.; Basu, S.; Laskar, R. A.; Mandal, D. Colloid Surface B. 2009, 71 (1), 113-118.
11. He, S.; Guo, Z.; Zhang, Y.; Zhang, S.; Wang, J.; Gu, N. Mater. Lett. 2007, 61 (18), 3984-3987.
12. Roy, K. Green’Synthesis of Silver Nanoparticles by using Grape (Vitis Vinifera) Fruit Extract: Characterization of the Particles and Study of Antibacterial Activity. PhD Dissertation, Indian Institute of Technology, Kharagpur, 2012.
13. Robinson, T.; Chandran, B.; Nigam, P. Enzyme Microb. Tech. 2001, 29 (8-9), 575-579.
14. de Campos Ventura-Camargo B.; Marin-Morales, M. A. Text. Light Ind. Sci. Technol. 2013, 2 (2), 85-103.
15. Correia, V. M.; Stephenson, T.; Judd, S. J. Environ. Technol. 1994, 15 (10), 917-929.
16. Wesenberg, D.; Kyriakides I.; Agathos, S. N. Biotechnol. Adv. 2003, 22 (1-2), 161-187.
17. De Moraes, S. G.; Freire, R. S.; Duran, N. Chemosphere 2000, 40 (4), 369-373.
18. Celebi, N.; Nadaroglu, H.; Kalkan, E.; Kotan R. Arch. Environ. Prot. 2016, 42 (4), 58-69.
19. Hoffmann, M. R.; Martin, S. T.; Choi, W.; Bahnemann DW. Chem. Rev. 1995, 95 (1), 69-96.
20. Pérez, M.; Torrades, F.; Garcı́a-Hortal, J. A.; Domènech, X.; Peral, J. Appl. Catal. B- Environ. 2002, 36 (1), 63-74.
21. Nadaroglu, H.; Kalkan, E.; Celik, H. Inter. J. Environ. Sci. Technol. 2015, 12 (6), 2079-2090.
22. Alaton, I. A.; Balcioglu, I. A.; Bahnemann, D. W. Water Res. 2002, 36 (5), 1143-1154.
23. Neamtu, M.; Siminiceanu, I.; Yediler, A.; Kettrup, A. Dyes Pigments 2002, 53 (2), 93-99.
24. Solmaz, S. K.; Birgül, A.; Üstün, G. E.; Yonar, T. Color. Technol. 2006, 122 (2), 102-109.
25. Deng, J.; Jiang, J.; Zhang, Y.; Lin, X.; Du, C.; Xiong, Y. Appl. Catal. B- Environ. 2008, 84 (3-4), 468-473.
26. Neyens, E.; Baeyens, J. J. Hazard. Mater. 2003, 98 (1-3), 33-50.
27. Sun, J. H.; Sun, S. P.; Wang, G. L.; Qiao, L. P. Dyes Pigments 2007, 74 (3), 647-652.
28. Gürtekin, E.; Şekerdağ, N. Sigma Mühendislik ve Fen Bilimleri Dergisi. 2008, 26 (3), 216-226 (in Turkish).
29. Naqvi, K. R.; Marsh, J.; Chechik, V. Dalton T. 2014, 43 (12), 4745-4751.
30. Ismail, E. H.; Khalil, M. M.; Al Seif, F. A.; El-Magdoub, F.; Bent, A. N.; Rahman, A. Prog. Nanotechnol. Nanomater. 2014, 3, 1-12.
31. Rai, A.; Singh, A.; Ahmad, A. Langmuir 2006, 22 (2), 736-741.
32. Ogale, S. B.; Ahmad, A.; Pasricha, R.; Dhas, V. V.; Syed, A. Appl. Phys. Lett. 2006, 89 (26), 263105.
33. Nadaroglu, H.; Kalkan, E. Indıan J. Chem. Techn. 2014, 21, 249-256.
34. Tian K.; Liu C.; Yang H.; Ren X. Colloids and Surfaces A. 2012, 397, 12-15.
35. Joseph, A.; Sumalatha, D.; Shubha, L. N. IJMTER 2016, 03 (11), 186-190.
36. Benhammou, A.; Yaacoubi, A.; Nibou, L.; Tanouti, B. J. Colloid Interf. Sci. 2005, 282 (2), 320-326.
37. Nadaroglu, H.; Kalkan, E.; Demir, N. Desalination 2010, 251 (1-3), 90-95.
38. Onundi, Y. B.; Mamun, A. A.; Al Khatib, M. F.; Ahmed, Y. M. Int. J. Environ. Sci. Te. 2010, 7 (4), 751-758.
39. Nadaroğlu, H.; Kalkan, E.; Celebi, N. Carpath. J. Earth Env. Sci. 2014, 9 (1), 69-80.
40. Gultekin, D. D.; Gungor, A. A.; Onem, H.; Babagil, A.; Nadaroglu H. J. Turkish Chem. Soc. A. 2016, 3 (3), 623-636.

Eco-friendly synthesis of nano copper and its use in fenton-like reactions for methylene blue degradation

Year 2020, Volume: 4 Issue: 1, 71 - 78, 30.06.2020

Demet Demirci Gültekin , Azize Alaylı , Hayrunnisa Nadaroglu

https://doi.org/10.32571/ijct.724056

Cited By: 1

Abstract

Copper oxide nanoparticles (CuO NPs) were produced using green synthesis method with Cimin grape extract (Vitis vinifera cv.). The produced CuO NPs were used to remove methylene blue (MB) from water by degradation with Fenton-like reactions. The surface properties of the CuO NPs were determined by FT-IR, SEM and XRD techniques. Experimental parameters for MB removal were selected as: pH: 3 – 11; Temp: 20 - 80°C; initial MB concentration (15 - 50 ml-1), and CuO NPs concentrations (25 - 800 mg ml-1). The best reaction conditions were found to be pH: 7 - 11, temperature: 40 - 45C, interaction time: 120 min, initial MB concentration: 3.125 mg ml-1 and CuO NPs concentration: 25 mg ml-1. Under these conditions, CuO NPs showed a 97.80% efficacy for the removal of MB from wastewater with Fenton-like process. Moreover, this study showed that reagents were reusable, inexpensive, biocompatible, easy to prepare, harmless (CuO NPs, H2O2), and Fenton-like reaction conditions were created.

Keywords

Copper oxide nanoparticles, fenton-like, methylene blue, degradation, removal

References

1. Sen, T. Int. J. Environ. Pollut. Control Manage. 2011, 3 (1), 1-10.
2. Bombardelli, E.; Morazzoni, P. Fitoterapia (Milano). 1995, 66 (4), 291-317.
3. Fan, P.; Lou, H.; Yu, W.; Ren, D.; Ma, B.; Ji, M. Tetrahedron Lett. 2004, 45 (15), 3163-3166.
4. Królikowska, A.; Kudelski, A.; Michota, A.; Bukowska. J. Surf. Sci. 2003, 532, 227-232.
5. Catauro, M.; Raucci, M. G.; De Gaetano, F.; Marotta, A. J. Mater. Sci-Mater. M. 2004, 15 (7), 831-837.
6. Crabtree, J. H.; Burchette, R. J.; Siddiqi, R. A.; Huen I. T.; Hadnott, L. L.; Fishman, A. Periton. Dialysis Int. 2003, 23 (4), 368-374.
7. Sharma, V. K.; Yngard, R. A.; Lin, Y. Adv. Colloid Interfac. 2009, 145 (1-2), 83-96.
8. Balantrapu, K.; Goia, D. V. J. Mater. Res. 2009, 24 (9), 2828-2836.
9. Taleb, A.; Petit, C.; Pileni, M. P. Chem. Mater. 1997, 9 (4), 950-959.
10. Begum, N. A.; Mondal, S.; Basu, S.; Laskar, R. A.; Mandal, D. Colloid Surface B. 2009, 71 (1), 113-118.
11. He, S.; Guo, Z.; Zhang, Y.; Zhang, S.; Wang, J.; Gu, N. Mater. Lett. 2007, 61 (18), 3984-3987.
12. Roy, K. Green’Synthesis of Silver Nanoparticles by using Grape (Vitis Vinifera) Fruit Extract: Characterization of the Particles and Study of Antibacterial Activity. PhD Dissertation, Indian Institute of Technology, Kharagpur, 2012.
13. Robinson, T.; Chandran, B.; Nigam, P. Enzyme Microb. Tech. 2001, 29 (8-9), 575-579.
14. de Campos Ventura-Camargo B.; Marin-Morales, M. A. Text. Light Ind. Sci. Technol. 2013, 2 (2), 85-103.
15. Correia, V. M.; Stephenson, T.; Judd, S. J. Environ. Technol. 1994, 15 (10), 917-929.
16. Wesenberg, D.; Kyriakides I.; Agathos, S. N. Biotechnol. Adv. 2003, 22 (1-2), 161-187.
17. De Moraes, S. G.; Freire, R. S.; Duran, N. Chemosphere 2000, 40 (4), 369-373.
18. Celebi, N.; Nadaroglu, H.; Kalkan, E.; Kotan R. Arch. Environ. Prot. 2016, 42 (4), 58-69.
19. Hoffmann, M. R.; Martin, S. T.; Choi, W.; Bahnemann DW. Chem. Rev. 1995, 95 (1), 69-96.
20. Pérez, M.; Torrades, F.; Garcı́a-Hortal, J. A.; Domènech, X.; Peral, J. Appl. Catal. B- Environ. 2002, 36 (1), 63-74.
21. Nadaroglu, H.; Kalkan, E.; Celik, H. Inter. J. Environ. Sci. Technol. 2015, 12 (6), 2079-2090.
22. Alaton, I. A.; Balcioglu, I. A.; Bahnemann, D. W. Water Res. 2002, 36 (5), 1143-1154.
23. Neamtu, M.; Siminiceanu, I.; Yediler, A.; Kettrup, A. Dyes Pigments 2002, 53 (2), 93-99.
24. Solmaz, S. K.; Birgül, A.; Üstün, G. E.; Yonar, T. Color. Technol. 2006, 122 (2), 102-109.
25. Deng, J.; Jiang, J.; Zhang, Y.; Lin, X.; Du, C.; Xiong, Y. Appl. Catal. B- Environ. 2008, 84 (3-4), 468-473.
26. Neyens, E.; Baeyens, J. J. Hazard. Mater. 2003, 98 (1-3), 33-50.
27. Sun, J. H.; Sun, S. P.; Wang, G. L.; Qiao, L. P. Dyes Pigments 2007, 74 (3), 647-652.
28. Gürtekin, E.; Şekerdağ, N. Sigma Mühendislik ve Fen Bilimleri Dergisi. 2008, 26 (3), 216-226 (in Turkish).
29. Naqvi, K. R.; Marsh, J.; Chechik, V. Dalton T. 2014, 43 (12), 4745-4751.
30. Ismail, E. H.; Khalil, M. M.; Al Seif, F. A.; El-Magdoub, F.; Bent, A. N.; Rahman, A. Prog. Nanotechnol. Nanomater. 2014, 3, 1-12.
31. Rai, A.; Singh, A.; Ahmad, A. Langmuir 2006, 22 (2), 736-741.
32. Ogale, S. B.; Ahmad, A.; Pasricha, R.; Dhas, V. V.; Syed, A. Appl. Phys. Lett. 2006, 89 (26), 263105.
33. Nadaroglu, H.; Kalkan, E. Indıan J. Chem. Techn. 2014, 21, 249-256.
34. Tian K.; Liu C.; Yang H.; Ren X. Colloids and Surfaces A. 2012, 397, 12-15.
35. Joseph, A.; Sumalatha, D.; Shubha, L. N. IJMTER 2016, 03 (11), 186-190.
36. Benhammou, A.; Yaacoubi, A.; Nibou, L.; Tanouti, B. J. Colloid Interf. Sci. 2005, 282 (2), 320-326.
37. Nadaroglu, H.; Kalkan, E.; Demir, N. Desalination 2010, 251 (1-3), 90-95.
38. Onundi, Y. B.; Mamun, A. A.; Al Khatib, M. F.; Ahmed, Y. M. Int. J. Environ. Sci. Te. 2010, 7 (4), 751-758.
39. Nadaroğlu, H.; Kalkan, E.; Celebi, N. Carpath. J. Earth Env. Sci. 2014, 9 (1), 69-80.
40. Gultekin, D. D.; Gungor, A. A.; Onem, H.; Babagil, A.; Nadaroglu H. J. Turkish Chem. Soc. A. 2016, 3 (3), 623-636.

There are 40 citations in total.

Details

Primary Language	English
Subjects	Chemical Engineering
Journal Section	Research Articles
Authors	Demet Demirci Gültekin 0000-0003-0773-6048 Azize Alaylı 0000-0002-7568-6970 Hayrunnisa Nadaroglu 0000-0002-7015-5169
Publication Date	June 30, 2020
Published in Issue	Year 2020 Volume: 4 Issue: 1

Cite

APA	Gültekin, D. D., Alaylı, A., & Nadaroglu, H. (2020). Eco-friendly synthesis of nano copper and its use in fenton-like reactions for methylene blue degradation. International Journal of Chemistry and Technology, 4(1), 71-78. https://doi.org/10.32571/ijct.724056
AMA	Gültekin DD, Alaylı A, Nadaroglu H. Eco-friendly synthesis of nano copper and its use in fenton-like reactions for methylene blue degradation. Int. J. Chem. Technol. June 2020;4(1):71-78. doi:10.32571/ijct.724056
Chicago	Gültekin, Demet Demirci, Azize Alaylı, and Hayrunnisa Nadaroglu. “Eco-Friendly Synthesis of Nano Copper and Its Use in Fenton-Like Reactions for Methylene Blue Degradation”. International Journal of Chemistry and Technology 4, no. 1 (June 2020): 71-78. https://doi.org/10.32571/ijct.724056.
EndNote	Gültekin DD, Alaylı A, Nadaroglu H (June 1, 2020) Eco-friendly synthesis of nano copper and its use in fenton-like reactions for methylene blue degradation. International Journal of Chemistry and Technology 4 1 71–78.
IEEE	D. D. Gültekin, A. Alaylı, and H. Nadaroglu, “Eco-friendly synthesis of nano copper and its use in fenton-like reactions for methylene blue degradation”, Int. J. Chem. Technol., vol. 4, no. 1, pp. 71–78, 2020, doi: 10.32571/ijct.724056.
ISNAD	Gültekin, Demet Demirci et al. “Eco-Friendly Synthesis of Nano Copper and Its Use in Fenton-Like Reactions for Methylene Blue Degradation”. International Journal of Chemistry and Technology 4/1 (June 2020), 71-78. https://doi.org/10.32571/ijct.724056.
JAMA	Gültekin DD, Alaylı A, Nadaroglu H. Eco-friendly synthesis of nano copper and its use in fenton-like reactions for methylene blue degradation. Int. J. Chem. Technol. 2020;4:71–78.
MLA	Gültekin, Demet Demirci et al. “Eco-Friendly Synthesis of Nano Copper and Its Use in Fenton-Like Reactions for Methylene Blue Degradation”. International Journal of Chemistry and Technology, vol. 4, no. 1, 2020, pp. 71-78, doi:10.32571/ijct.724056.
Vancouver	Gültekin DD, Alaylı A, Nadaroglu H. Eco-friendly synthesis of nano copper and its use in fenton-like reactions for methylene blue degradation. Int. J. Chem. Technol. 2020;4(1):71-8.

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