Research Article
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Preparation and characterization of potato crust-based polyurethane Foam-II

Year 2023, Volume: 7 Issue: 2, 215 - 223, 31.12.2023
https://doi.org/10.32571/ijct.1368730

Abstract

In this research study, environmentally friendly and biodegradable PU polymer foam was synthesized from starch-containing potato crust to be used as a thermal insulation material by reducing reliance on fossil resources and utilizing biomass resources. Biopolyols were obtained by reacting with active solvents at different reaction times, in the presence of different catalysts and at different catalyst concentrations. The most suitable polyol in terms of biomass content, density, viscosity and acid-hydroxyl number was selected for PU foam synthesis. Reactions for PU synthesis were tried and PU foam was synthesized. The synthesized PU foam was examined by Scanning Electron Microscope (SEM) and Thermo Gravimetric Analysis (TGA). Its morphological structure, thermal degradation properties, sound transmission coefficient and water absorption properties were determined by comparing it with a commercial PU foam.
SEM images showed a heterogeneous pore distribution with closed and open cells, the majority of which were closed. From the TGA results, it was determined that a two-step degradation occurred and incorporating biomass into its structure improved the total thermal degradation properties. The sound transmission rate of starch-containing PU foam, when used as a thermal insulation material, was measured to be lower than the concrete structure, but partially close to and higher than that of commercial PU foam. The water absorption properties of the synthesized PU foam were found to be significantly higher compared to commercial PU foam and and contributed to its usability as a thermal insulation material. Thermal insulation material PU foam is synthesized in terms of its properties.

Ethical Statement

I declare that there is no a conflict of interest with any person, institute, company etc.

Supporting Institution

Van Yüzüncü Yıl University Scientific Search Project Department

Project Number

2013- FBE-D060

Thanks

We are grateful for the financial support provided for this research by Van Yüzüncü Yıl University Scientific Search Project Department (2013- FBE-D060).

References

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  • 16. Chang, C.; Liu, L.; Li, P.; Xu, G.; Xu, C. Ind. Crops Prod. 2021, 160, 113098.
  • 17. Fidan, M.S., and Ertaş, M., Bioresources. 2020, 15(3), 6061-6079.
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  • 19. Yan, Y.; Pang, H.; Yang, X.; Zhang, R.; Liao, B. J. Appl. Polym. Sci. 2008, 110, 1099–1111.
  • 20. Kurimoto, Y.; Takeda, M.; Doi, S.; Tamura, Y.; Ono, H. Bioresour. Technol. 2001, 77, 33–40.
  • 21. Kurimoto, Y.; Doi, S.; Tamura, Y. Holzforschung. 1999, 53, 617–622.
  • 22. Chang, C.; Liu, L.; Li, P.; Xu, G.; Xu, C. Ind. Crops Prod. 2021, 160, 113098.
  • 23. Yao, Y.; Yoshioka, M.; Shiraishi, N. Journal of Applied Polimer Science. 1996, 60(11): 1939-1949.
  • 24. Ugarte, L.; Saralegi, A.; Fernandez, R.; Martin, L.; Corcuera, M.A.; Eceiza, A. Industrial Crops and Products. 2014, 62, 545-551.
  • 25. Zou, J.; Zhang, F.; Huang, J.; Chang, P.R.; Su, Z.; Yu, J. Carbonhydrate Polymers. 2011, 85, 824-831.
  • 26. Alfani, R.; Iannace, S.; Nicolais, L. Journal of Applied Polymer Science. 1998, 68, 739-745.
  • 27. Hakim, A.A.A.; Nassar, M.; A. Emam, A.; Sultan, M. Material Chemistry and Physics. 2011, 129 (1-2): 301-307.
  • 28. Öz, H.N.; Köse, E. International Journal of Engineering Research and Development. 2020, 12(2): 664-674.
  • 19. Yamada, T.; Ono, H.; Ohara, S.; A. Yamaguchi, A. Mokuzai Gakkaishi. 1996, 42(11): 1098-1104.
  • 20. Yan, Y.; Pang, H.; Yang, X.; Zhang, R.; Liao, B. J. Appl. Polym. Sci. 2008, 110, 1099–1111.
  • 21. Kurimoto, Y.; Takeda, M.; Doi, S.; Tamura, Y.; Ono, H. Bioresour. Technol. 2001, 77, 33–40.
  • 22. Kurimoto, Y.; Doi, S.; Tamura, Y. Holzforschung. 1999, 53, 617–622.
  • 23. Chang, C.; Liu, L.; Li, P.; Xu, G.; Xu, C. Ind. Crops Prod. 2021, 160, 113098.
  • 24. Yao, Y.; Yoshioka, M.; Shiraishi, N. Journal of Applied Polimer Science. 1996, 60(11): 1939-1949.
  • 25. Ugarte, L.; Saralegi, A.; Fernandez, R.; Martin, L.; Corcuera, M.A.; Eceiza, A. Industrial Crops and Products. 2014, 62, 545-551.
  • 26. Zou, J.; Zhang, F.; Huang, J.; Chang, P.R.; Su, Z.; Yu, J. Carbonhydrate Polymers. 2011, 85, 824-831.
  • 27. Alfani, R.; Iannace, S.; Nicolais, L. Journal of Applied Polymer Science. 1998, 68, 739-745.
  • 28. Hakim, A.A.A.; Nassar, M.; A. Emam, A.; Sultan, M. Material Chemistry and Physics. 2011, 129 (1-2): 301-307.
  • 29. Öz, H.N.; Köse, E. International Journal of Engineering Research and Development. 2020, 12(2): 664-674.
  • 30. N. B. Perkins, U.S. Pat. 5, 116, 550 (1992)
  • 31. F. Hostettler, U.S. Pat. 4, 197, 372 (1980)
Year 2023, Volume: 7 Issue: 2, 215 - 223, 31.12.2023
https://doi.org/10.32571/ijct.1368730

Abstract

Project Number

2013- FBE-D060

References

  • 1. Bailey, F.E. Handbook of Polymeric Foams and Foam Technology. Klempner, D.; Frisch, K.C. Ed., Hanser Publisher: Munich, 1991; Chapter 4.
  • 2. Olszewski, A.; Kosmela, P.; Piszczyk, K. European Journal of Wood and Wood Products. 2022, 80, 57-74.
  • 3. http://nigtas.com/tr/cozumlerımız/polimerler/poliureta n (accessed September 14, 2023)
  • 4. http://pluskim.com.tr/teknik/poliuretan-nedir/ (accessed September 14, 2023) 5. http://polure.com/c/poliuretannedir (accessed September 14, 2023)
  • 6. http://acikders.ankara.edu.tr/mod/resource/viev.phd.?= 34598 (accessed September 14, 2023)
  • 7. Zhang, H.; Ding, F.; Luo, C.; Xiong, L.; Chen, X. Ind. Crops Prod. 2012, 39, 47–51.
  • 8. El-barbary, M.H.; Shukry, N. Ind. Crops Prod. 2008, 27, 33–38.
  • 9. Wang, H.; Chen, H.-Z. J. Chin. Inst. Chem. Eng. 2007, 38, 95–102.
  • 10. Olszewski, A.; Nowak, P.; Kosmela, P.; Piszczyk, K. Materials. 2021, 14(6): 1391.
  • 11. Peterson, A.A.; Lachance, R.P.; Tester, J.W. Ind. Eng. Chem. Res. 2010, 49 (2010): 2107–2117.
  • 12. Guo, Y.; Yeh, T.; Song, W.; Xu, D.; Wang, S. Renew. Sustain. Energy Rev. 2015, 48 (2015): 776–790.
  • 13. Maldas, D.; Shiraishi, N. Int. J. Polym. Mater. Polym. Biomater. 1996, 33, 61–71.
  • 14. Alma, M.H.; Shiraishi, N. Holz als Roh- und Werkstoff. 1998, 56, 245–246.
  • 15. Bontaş, M.G.; Diacon, A.; Calinescu, I.; Rusen, E. Polymers. 2023, 15(63):1-26.
  • 16. Chang, C.; Liu, L.; Li, P.; Xu, G.; Xu, C. Ind. Crops Prod. 2021, 160, 113098.
  • 17. Fidan, M.S., and Ertaş, M., Bioresources. 2020, 15(3), 6061-6079.
  • 18. Norouzi, O.; Mazhkoo, S.; Haddadi, S.A.; Arjmand, M.; Dutta, A. Catalysis Today. 2022, 404(2022): 93- 104.Yamada, T.; Ono, H.; Ohara, S.; Yamaguchi, A. Mokuzai Gakkaishi. 1996, 42(11): 1098-1104.
  • 19. Yan, Y.; Pang, H.; Yang, X.; Zhang, R.; Liao, B. J. Appl. Polym. Sci. 2008, 110, 1099–1111.
  • 20. Kurimoto, Y.; Takeda, M.; Doi, S.; Tamura, Y.; Ono, H. Bioresour. Technol. 2001, 77, 33–40.
  • 21. Kurimoto, Y.; Doi, S.; Tamura, Y. Holzforschung. 1999, 53, 617–622.
  • 22. Chang, C.; Liu, L.; Li, P.; Xu, G.; Xu, C. Ind. Crops Prod. 2021, 160, 113098.
  • 23. Yao, Y.; Yoshioka, M.; Shiraishi, N. Journal of Applied Polimer Science. 1996, 60(11): 1939-1949.
  • 24. Ugarte, L.; Saralegi, A.; Fernandez, R.; Martin, L.; Corcuera, M.A.; Eceiza, A. Industrial Crops and Products. 2014, 62, 545-551.
  • 25. Zou, J.; Zhang, F.; Huang, J.; Chang, P.R.; Su, Z.; Yu, J. Carbonhydrate Polymers. 2011, 85, 824-831.
  • 26. Alfani, R.; Iannace, S.; Nicolais, L. Journal of Applied Polymer Science. 1998, 68, 739-745.
  • 27. Hakim, A.A.A.; Nassar, M.; A. Emam, A.; Sultan, M. Material Chemistry and Physics. 2011, 129 (1-2): 301-307.
  • 28. Öz, H.N.; Köse, E. International Journal of Engineering Research and Development. 2020, 12(2): 664-674.
  • 19. Yamada, T.; Ono, H.; Ohara, S.; A. Yamaguchi, A. Mokuzai Gakkaishi. 1996, 42(11): 1098-1104.
  • 20. Yan, Y.; Pang, H.; Yang, X.; Zhang, R.; Liao, B. J. Appl. Polym. Sci. 2008, 110, 1099–1111.
  • 21. Kurimoto, Y.; Takeda, M.; Doi, S.; Tamura, Y.; Ono, H. Bioresour. Technol. 2001, 77, 33–40.
  • 22. Kurimoto, Y.; Doi, S.; Tamura, Y. Holzforschung. 1999, 53, 617–622.
  • 23. Chang, C.; Liu, L.; Li, P.; Xu, G.; Xu, C. Ind. Crops Prod. 2021, 160, 113098.
  • 24. Yao, Y.; Yoshioka, M.; Shiraishi, N. Journal of Applied Polimer Science. 1996, 60(11): 1939-1949.
  • 25. Ugarte, L.; Saralegi, A.; Fernandez, R.; Martin, L.; Corcuera, M.A.; Eceiza, A. Industrial Crops and Products. 2014, 62, 545-551.
  • 26. Zou, J.; Zhang, F.; Huang, J.; Chang, P.R.; Su, Z.; Yu, J. Carbonhydrate Polymers. 2011, 85, 824-831.
  • 27. Alfani, R.; Iannace, S.; Nicolais, L. Journal of Applied Polymer Science. 1998, 68, 739-745.
  • 28. Hakim, A.A.A.; Nassar, M.; A. Emam, A.; Sultan, M. Material Chemistry and Physics. 2011, 129 (1-2): 301-307.
  • 29. Öz, H.N.; Köse, E. International Journal of Engineering Research and Development. 2020, 12(2): 664-674.
  • 30. N. B. Perkins, U.S. Pat. 5, 116, 550 (1992)
  • 31. F. Hostettler, U.S. Pat. 4, 197, 372 (1980)
There are 40 citations in total.

Details

Primary Language English
Subjects Chemical Engineering (Other)
Journal Section Research Articles
Authors

Tülay Gürsoy 0000-0001-6166-6875

M. Alma 0000-0001-6323-7230

Ertuğrul Altuntaş 0000-0003-2840-0703

Eyyüp Karaoğul 0000-0001-8162-6838

Project Number 2013- FBE-D060
Early Pub Date November 22, 2023
Publication Date December 31, 2023
Published in Issue Year 2023 Volume: 7 Issue: 2

Cite

APA Gürsoy, T., Alma, M., Altuntaş, E., Karaoğul, E. (2023). Preparation and characterization of potato crust-based polyurethane Foam-II. International Journal of Chemistry and Technology, 7(2), 215-223. https://doi.org/10.32571/ijct.1368730
AMA Gürsoy T, Alma M, Altuntaş E, Karaoğul E. Preparation and characterization of potato crust-based polyurethane Foam-II. Int. J. Chem. Technol. December 2023;7(2):215-223. doi:10.32571/ijct.1368730
Chicago Gürsoy, Tülay, M. Alma, Ertuğrul Altuntaş, and Eyyüp Karaoğul. “Preparation and Characterization of Potato Crust-Based Polyurethane Foam-II”. International Journal of Chemistry and Technology 7, no. 2 (December 2023): 215-23. https://doi.org/10.32571/ijct.1368730.
EndNote Gürsoy T, Alma M, Altuntaş E, Karaoğul E (December 1, 2023) Preparation and characterization of potato crust-based polyurethane Foam-II. International Journal of Chemistry and Technology 7 2 215–223.
IEEE T. Gürsoy, M. Alma, E. Altuntaş, and E. Karaoğul, “Preparation and characterization of potato crust-based polyurethane Foam-II”, Int. J. Chem. Technol., vol. 7, no. 2, pp. 215–223, 2023, doi: 10.32571/ijct.1368730.
ISNAD Gürsoy, Tülay et al. “Preparation and Characterization of Potato Crust-Based Polyurethane Foam-II”. International Journal of Chemistry and Technology 7/2 (December 2023), 215-223. https://doi.org/10.32571/ijct.1368730.
JAMA Gürsoy T, Alma M, Altuntaş E, Karaoğul E. Preparation and characterization of potato crust-based polyurethane Foam-II. Int. J. Chem. Technol. 2023;7:215–223.
MLA Gürsoy, Tülay et al. “Preparation and Characterization of Potato Crust-Based Polyurethane Foam-II”. International Journal of Chemistry and Technology, vol. 7, no. 2, 2023, pp. 215-23, doi:10.32571/ijct.1368730.
Vancouver Gürsoy T, Alma M, Altuntaş E, Karaoğul E. Preparation and characterization of potato crust-based polyurethane Foam-II. Int. J. Chem. Technol. 2023;7(2):215-23.