Removal of Cu (II), Co (II) and Ni (II) Ions from Aqueous Solutions Using Modified Sporopollenin

Year 2018, Volume: 12 Issue: 3, 42 - 44, 26.12.2018

Ali Bilgiç , Aysel Çimen , Mehmet Ay

Abstract

In this study, (E)-2-((2-hydroxynaphthalen-1-yl)methyleneamino)pyridin-3-ol(HNMAP) compound was immobilized on sporopollenin
of Lycopodium clavatum spores. The obtained structure was characterized by infrared spectroscopy
(IR) and scanning electron microscopy (SEM). This newly synthesized compound has been used as an adsorbent in
the separation of heavy metals. Batch method was used to separate Cu (II), Co
(II) and Ni (II) ions from waste waters. In
addition, different experimental parameters such as pH, concentration, duration
of interaction and concentration were selected to effectively separate heavy
metals from aquous solution and waste waters. The experimental results were
applied to Langmuir, Freundlich and Dubinin-Radushkevich (D-R) isotherm
equations. Thermodynamic parameters such as
free energy (∆G⁰), entropy (∆S⁰) and enthalpy (∆H⁰)
were  calculated from the experimental
results to explain the mechanism of the sorption. As a result, this adsorbent
has been successfully used to separate Cu (II), Co (II) and Ni (II) from
aqueous solutions and waste water.

Keywords

Immobilization, waste water, heavy metals, sporopollenin

References

• [1] Hatay B, Gup R, Ersoz M. 2008. Silica gel functionalized with 4-phenylacetophynone 4-aminobenzoylhydrazone: synthesis of a new chelating matrix and its application as metal ion collector. J. Hazard. Mater. 150:546–553.
• [2] Wang J, Zhang D, Lawson TR, Bartsch RA. 2009. Sorption of heavy metal ions by silica gel-immobilized, proton-ionizable calix[4]arenes, Talanta 78:477–483.
• [3] Gurten AA, Ucan M, Abdullah MI, Ayar A. 2006. Effect of the temperature and mobile phase composition on the retention behavior of nitroanilines on ligandexchange stationary phase, J. Hazard. Mater. B135:53–57.
• [4] Xie F, Lin X, Wu X, Xie Z. 2008. Solid phase extraction of lead (II), copper (II), cadmium (II) and nickel (II) using gallic acid-modified silica gel prior to determination by flameatomic absorption spectrometry, Talanta.74:836–843.
• [5] Zhu X, Chang X, Cui X, Zou Y, Yang D, Hu Z. 2007. Solid- phase extraction of trace Cu(II) Fe(III) and Zn(II) with silica gel modified with curcumin from biological and natural water samples by ICP-OES. Microchem. J. 86:189–194.
• [6] Tang X, Li Z, Chen Y. 2009. Adsorption behavior of Zn(II) on Chinese loess, J. Hazard. Mater. 161:824–834.
• [7] Treybal RE. Mass Transfer Operations, third ed., Mc Graw Hill, New York, 2000: 447–522.
• [8] Aljeboree AM, Alshirif AN, Alkaim AF. 2017. Kinetics and equilibrium study for the adsorption of textile dyes on coconut shell activated carbon. Arabian J.Chem. 10: S3381–S3393
• [9] Çimen A, Bilgiç A, Kurşunlu AN, Gübbük İH, Uçan Hİ. 2014. Adsorptive removal of Co(II), Ni(II), and Cu(II) ions from aqueous media using chemically modified sporopollenin of Lycopodium clavatum as novel biosorbent. Desalination. 52: 4837–4847