Research Article
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Experiments on decolorization and reuse of wastewater using magnetic and photocatalytic polymer particles

Year 2025, Volume: 5 Issue: 1, 196 - 205

Abstract

The textile industry is an important sector for many countries due to its high employment potential and continuous opportunities for innovation and development. However, this sector is also one of the largest consumers of water. In this study, polymer particles with magnetic and photocatalytic properties were synthesized for the decolorization of colored wastewater generated in the textile industry, and wastewater treatment experiments were conducted. The polymer particles were synthesized using the suspension polymerization method and characterized by SEM, FTIR, BET and ESR. These particles were used for the decolorization of wastewater from Karesi Polyester Company, employing both adsorption and heterogeneous photocatalysis methods simultaneously. The experiments were repeated over three cycles. Following the treatments, dyeing experiments were conducted with the decolorized waters. The results demonstrated removal efficiencies of up to 99,68%. This indicates that polymer particles can be effectively utilized as an environmentally friendly and innovative method for water treatment.

Project Number

BD-44

References

  • Kant R (2012) Textile dyeing industry: An environmental hazard. Natural Science,4(1):22-26.
  • Odabaşoğlu HY, Avinç OO, Yavaş A (2013) Susuz boyama. Tekstil ve Mühendis 20(90):63-79.
  • Liang J, Ning XA, Sun J, Song J, Lu J, Cai H, Hong Y (2018) Toxicity evaluation of textile dyeing effluent and its possible relationship with chemical oxygen demand. Ecotoxicology and Environmental Safety 166: 56-62.
  • Ganjoo R, Verma C, Kumar A, Quraishi MA (2023) Colloidal and interface aqueous chemistry of dyes: Past, present and future scenarios in corrosion mitigation. Advances in Colloid and Interface Science 311, 102832.
  • Berradi M, Hsissou R, Khudhair M, Assouag M, Cherkaoui O, El Bachiri A, El Harfi A (2019) Textile finishing dyes and their impact on aquatic environs. Heliyon, 5(11).
  • Katheresan V, Kansedo J, Lau SY (2018) Efficiency of various recent wastewater dye removal methods: A review. Journal of environmental chemical engineering 6(4):4676-4697.
  • Ahmad A, Mohd-Setapar SH, Chuong CS, Khatoon A, Wani WA, Kumar R, Rafatullah M (2015) Recent advances in new generation dye removal technologies: novel search for approaches to reprocess wastewater. RSC advances 5(39):30801-30818.
  • Daneshvar N, Salari D, Khataee AR (2003) Photocatalytic degradation of azo dye acid red 14 in water: investigation of the effect of operational parameters. Journal of Photochemistry and Photobiology A: Chemistry 157(1):111-116.
  • Chen CY (2009) Photocatalytic degradation of azo dye reactive orange 16 by TiO2. Water, Air, and Soil Pollution 202(1):335-342.
  • Muruganandham M, Swaminathan M (2004). Solar photocatalytic degradation of a reactive azo dye in TiO2-suspension. Solar Energy Materials and Solar Cells 81(4):439-457.
  • Dalal C, Garg AK, Jain N, Naziruddin AR, Prajapati RK, Choudhary SK, Sonkar SK (2023) Sunlight-assisted photocatalytic degradation of azo-dye using zinc-sulfide embedded reduced graphene oxide. Solar Energy 251:315-324.
  • Khan MS, Riaz N, Rehman S, Chenhui L, Shaikh AJ, Arfan M, Zeb I, Arshad M, Hafeez F, Bilal M (2023) Improved photocatalytic decolorization of reactive black 5 dye through synthesis of graphene quantum dots–nitrogen-doped TiO2. Environmental Science and Pollution Research 30(60):124992-125005.
  • Arslan M, Günay K (2019) Application of 4-VP-g-PET fibers and its N-oxide derivative as an adsorbent for removal of cationic dye. Polymer Bulletin 76:953-965.
  • Kara A, Demirbel E, Tekin N, Osman B, Beşirli N (2015) Magnetic vinylphenyl boronic acid microparticles for Cr (VI) adsorption: kinetic, isotherm and thermodynamic studies. Journal of Hazardous Materials 286:612-623.
  • Peksöz A, Akay SK (2016) Electron Spın Resonance Response Of Bafe12o19 Nanopartıcle Embedded Polydıvınylbenzene Magnetıc Fılm. Anadolu University of Sciences & Technology A: Applied Sciences & Engineering 17(4).
  • Arslan, M, Yiğitoğlu M (2008) Adsorption behavior of Congo red from an aqueous solution on 4‐vinyl pyridine grafted poly (ethylene terephthalate) fibers. Journal of applied polymer science 107(5):2846-2853.
  • Yalçın Turan Ş, Kara A, Tekin N (2024) Removal of acid violet 7 from aqueous solution with polymer matrix composite particles by adsorption and photocatalytic decolorization methods: isotherms, kinetics, and thermodynamic studies. International Journal of Environmental Analytical Chemistry 1-26.
  • Samanta P (2022) Basic principles of colour measurement and colour matching of textiles and apparels. In Colorimetry (pp. Ch-5). Rijeka, Croatia: IntechOpen.
  • Eren S, Bayaçlı G, Özyurt İ, Deren D, Öztürk M, Özenç AA, Eren HA (2023) Tekstil Terbiye İşletmesi Dispers Boyanmış Polyester Üretim Örneklerinin Ozonla Temizlenmesinin İncelenmesi. Uluslararası Bilim Teknoloji ve Tasarım Dergisi 4(1):46-55
  • Mevzuat Bilgi Sistemi.https://www.mevzuat.gov.tr/mevzuat?MevzuatNo=7221&MevzuatTur=7&Mevzuat Tertip=5. Erişim 23 Ekim 2024

Manyetik ve fotokatalitik polimer tanecikleri ile atık suların renksizleştirilmesi ve yeniden kullanım denemeleri

Year 2025, Volume: 5 Issue: 1, 196 - 205

Abstract

Tekstil endüstrisi, yüksek istihdam potansiyeli ve sürekli yenilik ve gelişim fırsatlarıyla birçok ülke için kritik bir sektördür. Ancak, bu sektör aynı zamanda su tüketimi açısından da en büyük tüketicilerden biridir. Bu çalışmada, tekstil endüstrisinde oluşan renkli atık suyun renksizleştirilmesi için manyetik ve fotokatalitik özelliklere sahip polimer tanecikler sentezlendi ve atık su arıtma deneyleri gerçekleştirildi. Polimer tanecikler, süspansiyon polimerizasyon yöntemiyle sentezlendi ve SEM , FTIR, BET ve ESR ile karakterize edildi. Bu tanecikler, Karesi polyester şirketinden alınan atık suyun renksizleştirilmesinde adsorpsiyon ve heterojen fotokataliz yöntemleri bir arada kullanıldı. Deneyler üç döngü boyunca tekrarlandı. İşlemlerin ardından, renksizleştirilmiş sularla boyama deneyleri yapıldı. Sonuçlar, %99,68'e kadar uzanan giderim verimliliklerini gösterdi. Bu, polimer taneciklerin su arıtımı için etkili, çevre dostu ve yenilikçi bir yöntem olarak kullanılabileceğini göstermektedir.

Project Number

BD-44

References

  • Kant R (2012) Textile dyeing industry: An environmental hazard. Natural Science,4(1):22-26.
  • Odabaşoğlu HY, Avinç OO, Yavaş A (2013) Susuz boyama. Tekstil ve Mühendis 20(90):63-79.
  • Liang J, Ning XA, Sun J, Song J, Lu J, Cai H, Hong Y (2018) Toxicity evaluation of textile dyeing effluent and its possible relationship with chemical oxygen demand. Ecotoxicology and Environmental Safety 166: 56-62.
  • Ganjoo R, Verma C, Kumar A, Quraishi MA (2023) Colloidal and interface aqueous chemistry of dyes: Past, present and future scenarios in corrosion mitigation. Advances in Colloid and Interface Science 311, 102832.
  • Berradi M, Hsissou R, Khudhair M, Assouag M, Cherkaoui O, El Bachiri A, El Harfi A (2019) Textile finishing dyes and their impact on aquatic environs. Heliyon, 5(11).
  • Katheresan V, Kansedo J, Lau SY (2018) Efficiency of various recent wastewater dye removal methods: A review. Journal of environmental chemical engineering 6(4):4676-4697.
  • Ahmad A, Mohd-Setapar SH, Chuong CS, Khatoon A, Wani WA, Kumar R, Rafatullah M (2015) Recent advances in new generation dye removal technologies: novel search for approaches to reprocess wastewater. RSC advances 5(39):30801-30818.
  • Daneshvar N, Salari D, Khataee AR (2003) Photocatalytic degradation of azo dye acid red 14 in water: investigation of the effect of operational parameters. Journal of Photochemistry and Photobiology A: Chemistry 157(1):111-116.
  • Chen CY (2009) Photocatalytic degradation of azo dye reactive orange 16 by TiO2. Water, Air, and Soil Pollution 202(1):335-342.
  • Muruganandham M, Swaminathan M (2004). Solar photocatalytic degradation of a reactive azo dye in TiO2-suspension. Solar Energy Materials and Solar Cells 81(4):439-457.
  • Dalal C, Garg AK, Jain N, Naziruddin AR, Prajapati RK, Choudhary SK, Sonkar SK (2023) Sunlight-assisted photocatalytic degradation of azo-dye using zinc-sulfide embedded reduced graphene oxide. Solar Energy 251:315-324.
  • Khan MS, Riaz N, Rehman S, Chenhui L, Shaikh AJ, Arfan M, Zeb I, Arshad M, Hafeez F, Bilal M (2023) Improved photocatalytic decolorization of reactive black 5 dye through synthesis of graphene quantum dots–nitrogen-doped TiO2. Environmental Science and Pollution Research 30(60):124992-125005.
  • Arslan M, Günay K (2019) Application of 4-VP-g-PET fibers and its N-oxide derivative as an adsorbent for removal of cationic dye. Polymer Bulletin 76:953-965.
  • Kara A, Demirbel E, Tekin N, Osman B, Beşirli N (2015) Magnetic vinylphenyl boronic acid microparticles for Cr (VI) adsorption: kinetic, isotherm and thermodynamic studies. Journal of Hazardous Materials 286:612-623.
  • Peksöz A, Akay SK (2016) Electron Spın Resonance Response Of Bafe12o19 Nanopartıcle Embedded Polydıvınylbenzene Magnetıc Fılm. Anadolu University of Sciences & Technology A: Applied Sciences & Engineering 17(4).
  • Arslan, M, Yiğitoğlu M (2008) Adsorption behavior of Congo red from an aqueous solution on 4‐vinyl pyridine grafted poly (ethylene terephthalate) fibers. Journal of applied polymer science 107(5):2846-2853.
  • Yalçın Turan Ş, Kara A, Tekin N (2024) Removal of acid violet 7 from aqueous solution with polymer matrix composite particles by adsorption and photocatalytic decolorization methods: isotherms, kinetics, and thermodynamic studies. International Journal of Environmental Analytical Chemistry 1-26.
  • Samanta P (2022) Basic principles of colour measurement and colour matching of textiles and apparels. In Colorimetry (pp. Ch-5). Rijeka, Croatia: IntechOpen.
  • Eren S, Bayaçlı G, Özyurt İ, Deren D, Öztürk M, Özenç AA, Eren HA (2023) Tekstil Terbiye İşletmesi Dispers Boyanmış Polyester Üretim Örneklerinin Ozonla Temizlenmesinin İncelenmesi. Uluslararası Bilim Teknoloji ve Tasarım Dergisi 4(1):46-55
  • Mevzuat Bilgi Sistemi.https://www.mevzuat.gov.tr/mevzuat?MevzuatNo=7221&MevzuatTur=7&Mevzuat Tertip=5. Erişim 23 Ekim 2024
There are 20 citations in total.

Details

Primary Language Turkish
Subjects Wastewater Treatment Processes
Journal Section Research Articles
Authors

Şeyma Yalçın Turan 0000-0002-7633-2576

Ali Kara 0000-0003-2457-6314

Gizem Bayaçlı Uygun 0000-0001-9676-5531

İrem Özyurt 0009-0005-6630-5346

Project Number BD-44
Publication Date
Submission Date August 13, 2024
Acceptance Date November 6, 2024
Published in Issue Year 2025 Volume: 5 Issue: 1

Cite

APA Yalçın Turan, Ş., Kara, A., Bayaçlı Uygun, G., Özyurt, İ. (n.d.). Manyetik ve fotokatalitik polimer tanecikleri ile atık suların renksizleştirilmesi ve yeniden kullanım denemeleri. Journal of Innovative Engineering and Natural Science, 5(1), 196-205.


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Journal of Innovative Engineering and Natural Science by İdris Karagöz is licensed under CC BY 4.0