The Heavy Metal Effects of Mineralization and Alteration Areas with Buried Ore Deposits Potential on the Surface Waters

Year 2022, Volume: 5 Issue: 1, 21 - 33, 30.06.2022

Alaaddin Vural , Ali Gündoğdu , Fatih Saka , Volkan Numan Bulut , Mustafa Soylak , Selçuk Alemdağ

Abstract

This paper aims at elucidating the potential environmental risks associated with ore deposits and alteration areas related to these mineralizations by quantifying contamination in stream waters in the areas. For this purposes, 21 surface water samples were collected the streams and analyzed for heavy metals. Concentrations of heavy metals in surface waters reached 160 µg/L for Al, 2886,4 µg/L for Mn, 13147 µg/L for Fe, 58,18 µg/L for Co, 1644 µg/L for Zn, 100 µg/L for Cu, 2376 µg/L for Sr, 770 µg/L for Ba and 96,70 µg/L for Pb. In addition, high arsenic, cobalt, cadmium values were detected in some locations. Some other heavy metals are below the limit of detection.
As a result of the study done, alteration areas with buried ore deposits potential and ore deposit areas have been found to cause heavy metal contamination in the surface waters around these environments, therefore, more detailed studies should be done on such fields and necessary precautions should be taken in order to avert the dispersal of contamination sourced those areas.

Keywords

Heavy metal contamination, Alteration area, Surface water, Gümüşhane

Supporting Institution

Tübitak

Project Number

115Y146

Thanks

[e-mail]

References

• Arslan, M., & Aliyazicioglu, I. (2001). Geochemical and petrological characteristics of the Kale (Gümüşhane) volcanic rocks: Implications for the Eocene evolution of eastern Pontide arc volcanism, northeast Turkey. International Geology Review, 43(7), 595–610. https://doi.org/10.1080/00206810109465035
• Bird, G., Brewer, P. A., Macklin, M. G., Serban, M., Balteanu, D., & Driga, B. (2005). Heavy metal contamination in the Arieş river catchment, western Romania: Implications for development of the Roşia Montana gold deposit. Journal of Geochemical Exploration, 86(1), 26–48. https://doi.org/10.1016/j.gexplo.2005.02.002
• Güven, İ. H. (1993). Doğu Pontidlerin 1/100.000 Ölçekli Kompilasyonu. MTA Genel Müdürlüğü.
• Hölting, B., & Coldewey, W. G. (2019). Hydrogeology. Springer. https://doi.org/https://doi.org/10.1007/978-3-662-56375-5 Karataş, M., & Çevik, S. (2010). Stratejik Doğal Kaynak Olarak Su ve Türkiye’nin Konumunun Değerlendirilmesi. Akademik Araştırmalar Dergisi, 45, 1–29.
• Karslı, O., Chen, B., Aydin, F., & Şen, C. (2007). Geochemical and Sr-Nd-Pb isotopic compositions of the Eocene Dölek and Sariçiçek Plutons, Eastern Turkey: Implications for magma interaction in the genesis of high-K calc-alkaline granitoids in a post-collision extensional setting. Lithos, 98(1–4), 67–96. https://doi.org/10.1016/j.lithos.2007.03.005
• Kaya, A., & Vural, A. (2020). Investigation of Natural (226Ra, 232Th and 40K) and Artificial (137Cs) Radioactivity Concentrations of Kırkpavli and Hazine Mağara Ore Deposits (Gümüşhane). 5.Uluslararası Sağlık Bilimleri ve Yönetimi Kongresi.
• Kaya, A., Vural, A., & Çelik, N. (2021). Koza ve Karamustafa Madenlerinin (Gümüşhane ) Doğal (226 Ra , 232 Th ve 40K) ve Yapay (137 Cs) Radyoaktivite Konsantrasyonlarının Araştırılması (Gümüşhane). 73. Türkiye Jeoloji Kurultayı, 996–1001.
• Kaygusuz, A., Siebel, W., Şen, C., & Satir, M. (2008). Petrochemistry and petrology of I-type granitoids in an arc setting: the composite Torul pluton, Eastern Pontides, NE Turkey. International Journal of Earth Sciences, 97(4), 739–764. https://doi.org/10.1007/s00531-007-0188-9
• Sungur, A., Vural, A., Gundogdu, A., & Soylak, M. (2020). Effect of antimonite mineralization area on heavy metal contents and geochemical fractions of agricultural soils in Gümüşhane Province, Turkey. Catena, 184(January 2019), 104255. https://doi.org/10.1016/j.catena.2019.104255
• Sungur, A., Vural, A., Gündoğdu, A., & Soylak, M. (2018). Gümüştuğ Köyü (Torul-Gümüşhane) Tarım Topraklarında Manganın Jeokimyasal Karakterizasyonu. International Trace Analysis Congress (ITAC 2018/ES-AN 2018), 231.
• Sungur, Ali, Soylak, M., & Ozcan, H. (2019). Fractionation, Source Identification and Risk Assessments for Heavy Metals in Soils near a Small-Scale Industrial Area (Çanakkale-Turkey). Soil and Sediment Contamination, 28(2), 213–227. https://doi.org/10.1080/15320383.2018.1564735
• Topuz, G., Altherr, R., Schwarz, W. H., Dokuz, A., & Meyer, H. P. (2007). Variscan amphibolite-facies rocks from the Kurtoǧlu metamorphic complex (Gümüşhane area, Eastern Pontides, Turkey). International Journal of Earth Sciences, 96(5), 861–873. https://doi.org/10.1007/s00531-006-0138-y
• Topuz, G., Altherr, R., Siebel, W., Schwarz, W. H., Zack, T., Hasözbek, A., Barth, M., Satır, M., & Şen, C. (2010). Carboniferous high-potassium I-type granitoid magmatism in the Eastern Pontides: The Gümüşhane pluton (NE Turkey). Lithos, 116(1–2), 92–110. https://doi.org/10.1016/j.lithos.2010.01.003
• Turan, E., & Bayrakdar, E. (2020). Türkiye’nin Su Yönetim Politikaları: Ulusal Güvenlik Açısından Bir Değerlendirme. International Journal of Political Studies, 6(2), 1–19. https://doi.org/10.25272/j.2149-8539.2020.6.2.01
• Vural, A. (2013). Assessment of Heavy Metal Accumulation in the Roadside Soil and Plants of Robinia pseudoacacia, in Gumushane, Northeastern Turkey. Ekoloji, 22(89), 1–10. https://doi.org/10.5053/ekoloji.2013.891
• Vural, A. (2014). Trace/heavy metal accumulation in soil and in the shoots of acacia tree, Gümüşhane-Turkey. Bulletin of the Mineral Research and Exploration, 148, 85–106.
• Vural, A. (2015). Contamination assessment of heavy metals associated with an alteration area: Demirören Gumushane, NE Turkey. Journal of the Geological Society of India, 86(2), 215–222. https://doi.org/10.1007/s12594-015-0301-9
• Vural, A. (2017). K-Ar dating for determining the age of mineralization as alteration product: A case study of antimony mineralization vein type in granitic rocks of Gümüşhane area, Turkey. Acta Physica Polonica A, 132(3), 792–795. https://doi.org/10.12693/APhysPolA.132.792
• Vural, A. (2019). Zenginleştirilmiş Jeoturizm Güzergahlarına Dair Farkındalık Oluşturulması : Eski Gümüşhane - Dörtkonak Güzergahı [Creation of Awareness of Enhanced Geotourism Routes: Old Gümüşhane-Dörtkonak Route]. Gümüşhane Üniversitesi Sosyal Bilimler Enstitüsü Elektronik Dergisi, 10, 250–274.
• Vural, A. (2018a). Gümüshane-Zigana Zenginleştirilmiş Jeoturizm Güzergâhı. II. International Sustainable Tourism Congress, 607–617.
• Vural, A. (2018b). Zenginleştirilmiş Jeoturizm Güzergahlarına Dair Farkındalık Olusturulması: Eski Gümüshane-Dört Konak Güzergahı. II. International Sustainable Tourism Congress, 533–542.
• Vural, A. (2018c). Zenginleştirilmiş Jeoturizm Rotası: Karadağ ve Artabel Gölleri. 71. Türkiye Jeoloji Kurultayı, 481–482.
• Vural, A., Akpınar, İ., & Kaygusuz, A. (2021). Petrological characteristics of Cretaceous volcanic rocks of Demirören (Gümüşhane, NE Turkey) region. Journal of Engineering Research and Applied Science, 10(2), 1828–1842.
• Vural, A., Akpınar, İ., Kaygusuz, A., & Sipahi, F. (2021). Petrological characteristics of Eocene volcanic rocks around Demirören (Gümüşhane, NE Turkey). Journal of Engineering Research and Applied Science, 10(1), 1703–1716.
• Vural, A., & Çiçek, B. (2019). Heavy Metal Pollution in Developed Soils on Mineralization Zone. 3rd International Conference on Advanced Engineering Technologies, 3rd International Conference on Advanced Engineering Technologies (ICADET).
• Vural, A., & Erdoğan, M. (2014). Eski Gümüşhane Kırkpavli Alterasyon Sahasında Toprak Jeokimyası. Gümüşhane Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 4(1), 1–15.
• Vural, A., & Ersen, F. (2019). Geology, mineralogy and geochemistry of manganese mineralization in Gumushane, Turkey. Journal of Engineering Research and Applied Science, 8(June), 1051–1059.
• Vural, A., & Gündoğdu, A. (2014). Investigation of Heavy Metal Contamination In Harşit Brook (Gümüşhane) Arising from (Abondoned) Mining Sites in the Region: Preliminary Findings. International Environmental Sciences Symposium of Van, 170–171.
• Vural, A., & Kaya, A. (2021a). Arzular-Yitirmez-Dölek (Gümüşhane) Maden/Alterasyon Sahalarındaki Doğal (226Ra, 232Th ve 40K) ve yapay (138Cs) Radyoaktivitelerine ait ilk değerlendirmeler. Euroasia Journal of Mathematics, Engineering, Natural & Medical Sciences, 8(88), 105–120. https://doi.org/10.38065/euroasiaorg.787
• Vural, A., & Kaya, A. (2021b). Arzular-Yitirmez Maden/Alterasyon Sahalarının (Gümüşhane) Doğal (226Ra, 232Th ve 40K) ve Yapay (137Cs) Radyoaktivitelerinin Araştırılması. 1st International Conference of Physics, 315–327.
• Vural, A., Kaya, S., Başaran, N., & Songören, O. T. (2009). Anadolu Madenciliğinde İlk Adımlar. Maden Tetkik ve Arama Genel Müdürlüğü, MTA Kültür Serisi-3.
• Vural, A., & Kaygusuz, A. (2016). Avliyana (Torul-Gümüşhane) Antimonit Cevherleşmesinin Jeolojisi-Mineralojisi ve Kökeninin Araştırılması.
• Vural, A., & Kaygusuz, A. (2021a). Petrographic and geochemical characteristics of late Cretaceous volcanic rocks in the vicinity of Avliyana (Gümüşhane , NE Turkey ). Journal of Engineering Research and Applied Science, 10(2), 1796–1810.
• Vural, A., & Kaygusuz, A. (2021b). Geochronology, petrogenesis and tectonic importance of Eocene I-type magmatism in the Eastern Pontides, NE Turkey. Arabian Journal of Geosciences, 14(6), 467. https://doi.org/10.1007/s12517-021-06884-z
• Vural, A., Kaygusuz, A., & Dönmez, H. (2018). Geological, Geochemical and Geochronological Investigation of Avliyana Antimonite Mineralization. 8th Geochemistry Symposium, 123–124.
• Vural, A., & Külekçi, G. (2021a). Bahçecik (Gümüşhane) ve Yakın Civarı Zenginleştirilmiş Jeoturizm Güzergahı. UMTEB 11.Uluslararası Mesleki ve Teknik Bilimler Kongresi.
• Vural, A., & Külekçi, G. (2021b). Zenginleştirilmiş Jeoturizm Güzergahı:Gümüşhane-Bahçecik Köyü (Enriched Geotourism Route: Gümüşhane-Bahçecik Village). Euroasia Journal of Mathematics, Engineering, Natural & Medical Sciences, 8(19), 1–23. https://doi.org/10.38065/euroasiaorg.894
• Yılmaz, Y. (1972). Petrology and structure of the Gümüşhane granite and surrounding rocks, NE Anatolia.