Synthesis, characterization of new homo and heteronuclear Schiff base copper(II) complexes

Year 2018, Volume: 5 Issue: 2, 785 - 802, 01.01.2018

Tufan Topal , Emin Karapınar

https://doi.org/10.18596/jotcsa.324878

Cited By: 8

Abstract

This
article describes the synthesis of isonitrosomethyl-p-tolyl
ketone [HL] as
the starting material and then we prepared the schiff base ligand from the reactions
of the amine compounds with o-phenylenediamine [H₂L¹]. A new series of mono-, homo and heterodinuclear copper(II)/nickel(II)
complexes have been synthesized using an oxime ligand. The complexes were
characterized by IR, elemental analysis, magnetic moment measurements, molar
conductivity, mass spectra and TGA studies. The free ligand were also described
¹³C and ¹H-NMR spectra. For complexes using
stoichiometric and spectroscopic data of the metal complexes showed that metal:ligand
ratio of mononuclear copper(II) complex was found to be 1:1 while this ratio
was 2:1 in homo- and heterodinuclear copper(II) complex and 3:2 in the
trinuclear copper (II) complex and metal ions are coordinated to the imine and
oxime nitrogen atoms. 

Keywords

Schiff base, heteronuclear, trinuclear, nickel

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