Syntheses and characterization of new dithiophosphinato zinc complexes

Ertuğrul Gazi Sağlam; Nurcan Acar

doi:10.18596/jotcsa.427192

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Syntheses and characterization of new dithiophosphinato zinc complexes

Year 2018, Volume: 5 Issue: 2, 931 - 940, 01.01.2018

Ertuğrul Gazi Sağlam , Nurcan Acar

https://doi.org/10.18596/jotcsa.427192

Cited By: 3

Abstract

Four known dithiophosphinic
acids, DTPA, were synthesized and their zinc complexes were prepared as
novelties. The complexes have been proven to have the structures [Zn(µ-DTPAⁿ)₂(DTPAⁿ)₂],
([DTPAⁿ]= Rⁿ(R)P(S)H, R= 4-CH₃O-C₆H₄-;
R¹= iso-amyl-, DTPA¹; R²= iso-butyl-,
DTPA²; R³= sec-butyl-, DTPA³; R⁴=
iso-propyl-, DTPA⁴). The DTPAs were prepared by the reaction
of the Lawesson
reagent, [2,4–bis(4-methoxyphenyl)–1,3,2,4–ditiyodifosfetan–2,4–disülfür] (LR),
with the corresponding Grignard compounds. The acids formed are viscous liquids
difficult to purify and so they were converted to ammonium salts, [DTPAⁿ][NH₄],
which are easy to obtain as pure crystals. The complexes were identified to
have dimeric structures on the basis of mass spectroscopic data.

Keywords

Dithiophosphinic Acid, Dithiophosphinate, Phosphinodithioic Acid, Dithiophosphinato Zinc Complex, Lawesson’s Reagent

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