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Characterization of a bentonite and its permanent aqueous suspension

Year 2020, Volume: 7 Issue: 1, 11 - 18, 15.02.2020
https://doi.org/10.18596/jotcsa.535937

Abstract

A bentonite sample taken from Reşadiye
(Tokat/Turkey) deposite was mixed with distilled water. The formed permanent
aqueous suspension was separated by decantation from the flocculated solid
fraction. The deflocculated mass percent of the bentonite was evaluated almost
60% by weighing. The bentonite and its permanently suspended solid fraction are
examined by using X-ray diffraction, chemical, thermal, cation exchange, and particle
size analyses. Mineralogy and chemical composition of the samples were
discussed with respect to the experimental results. A sodium rich aluminum, iron
and magnesium smectite was determined as the major clay mineral in the
bentonite and also illite as minor one. Clinoptilolite, plagioclase, quartz,
opal-CT, calcite, magnesite, and dolomite are the nonclay minerals found in the
bentonite as impurities. The suspension contains large amount sodium rich
smectite and plagioclase whereas lesser opal-CT. Particle size of the bentonite
and deflocculated fraction was found to be lesser than 11 µm and 2 µm,
respectively.

Supporting Institution

Ankara University

Project Number

17H0430010

References

  • 1. Grim RE. The history of the development of clay mineralogy. Clays and Clay Minerals. 1988;36:97-101
  • 2. Grim RE, Güven N. Bentonites- Geology, Mineralogy, Properties and Uses. Developments in Sedimentology, 24. Elsevier; New York, 1978.
  • 3. Grim RE. Clay Mineralogy, McGraw-Hill; New York, 1968.
  • 4. Bergman WE and Fisher HB. Bentonite suspensions. Industrial and Engineering Chemistry. 1950;42:1895-1900.
  • 5. Luckham PL, Rossi S. The colloidal and rheological properties of bentonite suspensions. Advanced in Colloid and Interface Science. 1999;82:43-92.
  • 6. Minase M, Kondo M, Onikato M, Kawamura K. The viscosity of suspensions of bentonite. Clay Science. 2006;12:125-130.
  • 7. Rollins MB. Sealing properties of bentonite suspensions, Clays and Clay Minerals. 1969;16:415-423.
  • 8. Zhu R, Chen Q, Zhou Q, Xi Y, Zhu J, He H. Adsorbates based on montmorillonite for contaminant removal from water: a review. Applied Clay Science.2016;123: 239-258.
  • 9. Uddin MK. A review on the adsorption of heavy metals by clay minerals, with special focus on the past decade. Chemical Engineering Journal.2017;308:438-462.
  • 10. Derakhshany E, Naghizadeh A. Optimization of humic acid removal by adsorption onto bentonite and montmorillonite nanoparticles. Journal of Molecular Liquids. 2018;259:76-81.
  • 11. Noyan H, Önal M, Sarıkaya Y. The effect of heating on the surface area, porosity and surface acidity of a bentonite. Clay and Clay Minerals. 2006;54:375-381.
  • 12. Noyan H, Önal M, Sarıkaya Y. The effect of sulphuric acid activation on the crystallinity, surface acidity, and bleaching power of a bentonite. Food Chemistry. 2007;105:156-163.
  • 13. Komadel P. Acid activated clays: Materials in continuous demand. Applied Clay Science. 2016;131:84-99.
  • 14. Murray HH. Traditional and new applications for kaolin, smectite, and palygorskite: a general overview. Applied Clay Science. 2000;17:207-221.
  • 15. Çelik M, Önal M. Synthesis and characterization of poly(glycidyl methacrylate)/Na-montmorillonite nanocomposites. Journal of Applied Polymer Science. 2004;94:1532-1538.
  • 16. Çelik M, Önal M. Polymethacrylamide/Na-montmorillonite nanocomposites synthesized by free-radical polymerization. Material Letters. 2006;60:48-52.
  • 17. Silva SM, Sampaio KA, Ceriani R, Verhe R, Stevens C, De Greyt W, Meirelles JA. Effect of type of bleaching earth on the final color of refined palm oil. LTW-Food Science and Technology. 2014;59:1258-1264.
  • 18. Elzea JM, Odom IE, Miles WJ. Distinguishing well ordered opal-CT and opal-C from high temperature cristobalite by X-ray diffraction. Analytica Chimica Acta. 1994;286:107-116.
  • 19. Elzea JM, Rice SB. TEM and X-ray diffraction evidence for cristobalite and tridymite stacking sequences in opal. Clays and Clay Minerals. 1996;44:492-500.
  • 20. Önal M, Kahraman S, Sarıkaya Y. Differentiation of α- cristobalite from opals in bentonites from Turkey. Applied Clay Science. 2007;35:25-30.
  • 21. Önal M, Sarıkaya Y, Alemdaroğlu T, Bozdoğan İ. Isolation and characterization of a smectite as a micro-mesoporous material from a bentonite. Turkish Journal of Chemistry. 2003;27:683-693.
  • 22. Yener N, Biçer C, Önal M, Sarıkaya Y. Simultaneous determination of cation exchange capacity and surface area of acid activated bentonite powders by methylene blue sorption. Applied Surface Science. 2012;258: 2534-2539.
  • 23. Moore DM, Reynolds, Jr RC. X-ray diffraction and the Identification and Analysis of Clay Minerals. Oxford University Press; Oxford, 1997.
  • 24. Patterson A.The Scherrer formula for X-ray particle size determination. Physical Review. 1939;56:978–982.
Year 2020, Volume: 7 Issue: 1, 11 - 18, 15.02.2020
https://doi.org/10.18596/jotcsa.535937

Abstract

Project Number

17H0430010

References

  • 1. Grim RE. The history of the development of clay mineralogy. Clays and Clay Minerals. 1988;36:97-101
  • 2. Grim RE, Güven N. Bentonites- Geology, Mineralogy, Properties and Uses. Developments in Sedimentology, 24. Elsevier; New York, 1978.
  • 3. Grim RE. Clay Mineralogy, McGraw-Hill; New York, 1968.
  • 4. Bergman WE and Fisher HB. Bentonite suspensions. Industrial and Engineering Chemistry. 1950;42:1895-1900.
  • 5. Luckham PL, Rossi S. The colloidal and rheological properties of bentonite suspensions. Advanced in Colloid and Interface Science. 1999;82:43-92.
  • 6. Minase M, Kondo M, Onikato M, Kawamura K. The viscosity of suspensions of bentonite. Clay Science. 2006;12:125-130.
  • 7. Rollins MB. Sealing properties of bentonite suspensions, Clays and Clay Minerals. 1969;16:415-423.
  • 8. Zhu R, Chen Q, Zhou Q, Xi Y, Zhu J, He H. Adsorbates based on montmorillonite for contaminant removal from water: a review. Applied Clay Science.2016;123: 239-258.
  • 9. Uddin MK. A review on the adsorption of heavy metals by clay minerals, with special focus on the past decade. Chemical Engineering Journal.2017;308:438-462.
  • 10. Derakhshany E, Naghizadeh A. Optimization of humic acid removal by adsorption onto bentonite and montmorillonite nanoparticles. Journal of Molecular Liquids. 2018;259:76-81.
  • 11. Noyan H, Önal M, Sarıkaya Y. The effect of heating on the surface area, porosity and surface acidity of a bentonite. Clay and Clay Minerals. 2006;54:375-381.
  • 12. Noyan H, Önal M, Sarıkaya Y. The effect of sulphuric acid activation on the crystallinity, surface acidity, and bleaching power of a bentonite. Food Chemistry. 2007;105:156-163.
  • 13. Komadel P. Acid activated clays: Materials in continuous demand. Applied Clay Science. 2016;131:84-99.
  • 14. Murray HH. Traditional and new applications for kaolin, smectite, and palygorskite: a general overview. Applied Clay Science. 2000;17:207-221.
  • 15. Çelik M, Önal M. Synthesis and characterization of poly(glycidyl methacrylate)/Na-montmorillonite nanocomposites. Journal of Applied Polymer Science. 2004;94:1532-1538.
  • 16. Çelik M, Önal M. Polymethacrylamide/Na-montmorillonite nanocomposites synthesized by free-radical polymerization. Material Letters. 2006;60:48-52.
  • 17. Silva SM, Sampaio KA, Ceriani R, Verhe R, Stevens C, De Greyt W, Meirelles JA. Effect of type of bleaching earth on the final color of refined palm oil. LTW-Food Science and Technology. 2014;59:1258-1264.
  • 18. Elzea JM, Odom IE, Miles WJ. Distinguishing well ordered opal-CT and opal-C from high temperature cristobalite by X-ray diffraction. Analytica Chimica Acta. 1994;286:107-116.
  • 19. Elzea JM, Rice SB. TEM and X-ray diffraction evidence for cristobalite and tridymite stacking sequences in opal. Clays and Clay Minerals. 1996;44:492-500.
  • 20. Önal M, Kahraman S, Sarıkaya Y. Differentiation of α- cristobalite from opals in bentonites from Turkey. Applied Clay Science. 2007;35:25-30.
  • 21. Önal M, Sarıkaya Y, Alemdaroğlu T, Bozdoğan İ. Isolation and characterization of a smectite as a micro-mesoporous material from a bentonite. Turkish Journal of Chemistry. 2003;27:683-693.
  • 22. Yener N, Biçer C, Önal M, Sarıkaya Y. Simultaneous determination of cation exchange capacity and surface area of acid activated bentonite powders by methylene blue sorption. Applied Surface Science. 2012;258: 2534-2539.
  • 23. Moore DM, Reynolds, Jr RC. X-ray diffraction and the Identification and Analysis of Clay Minerals. Oxford University Press; Oxford, 1997.
  • 24. Patterson A.The Scherrer formula for X-ray particle size determination. Physical Review. 1939;56:978–982.
There are 24 citations in total.

Details

Primary Language English
Subjects Chemical Engineering
Journal Section Articles
Authors

Fatma Eda Özgüven This is me 0000-0002-7812-8165

Abdullah Devrim Pekdemir This is me 0000-0002-3347-0469

Müşerref Önal 0000-0002-1540-8389

Yüksel Sarıkaya This is me 0000-0002-2556-078X

Project Number 17H0430010
Publication Date February 15, 2020
Submission Date March 5, 2019
Acceptance Date October 14, 2019
Published in Issue Year 2020 Volume: 7 Issue: 1

Cite

Vancouver Özgüven FE, Pekdemir AD, Önal M, Sarıkaya Y. Characterization of a bentonite and its permanent aqueous suspension. JOTCSA. 2020;7(1):11-8.