Equilibrium and Kinetic Studies of a Cationic Dye Adsorption Onto Raw Clay

Year 2020, Volume: 7 Issue: 3, 713 - 726, 30.10.2020

Eda Gökırmak Söğüt , Necla Çalışkan Kılıç

https://doi.org/10.18596/jotcsa.657621

Cited By: 6

Abstract

In this study, methylene blue (MB) dye adsorption from the aqueous solution on raw clay samples collected from the Tilkitepe in the east of Lake Van was presented. Batch adsorption studies were conducted to evaluate the effect of various experimental parameters such as pH, contact time and initial concentrations on the removal of MB. The five nonlinear adsorption equations were applied to describe the equilibrium isotherms. Considering the correlation coefficients, the order of the most suitable isotherm models was Sips> Freundlich> Temkin> Dubinin- Radushkevich>Langmuir. From the data applied to the pseudo-first-second order, Elovich and intra-particle diffusion kinetic models, it can be said that the best model describing the kinetics of MB dye adsorption is the pseudo-second order (PSO) kinetic model. The results are shown that Tilkitepe / Van raw clay material could be used as an economical and effective adsorbent for dye removal.

Keywords

Methylene blue, raw clay, adsorption, kinetic, two and three parameters nonlinear isotherms

References

• 1. Chakraborty S, Chowdhury S, Das P. Artificial neural network (ANN) modeling of dynamic adsorption of crystal violet from aqueous solution using citric-acid-modified rice (Oryza sativa) straw as adsorbent. Clean Technologies and Environmental Policy. 2012;15:doi: 10.1007/s10098-012.
• 2. Errais E, Duplay J, Darragi F, M'Rabet I, Aubert A, Huber F, et al. Efficient anionic dye adsorption on natural untreated clay: Kinetic study and thermodynamic parameters. Desalination. 2011;275(1):74-81.
• 3. Deng H, Lu J, Li G, Zhang G, Wang X. Adsorption of methylene blue on adsorbent materials produced from cotton stalk. Chemical Engineering Journal. 2011;172(1):326-34.
• 4. Chunjiaozhou, Zhenwu, Wenjiezhang, Mingxiaxia, Guozhangdai, Guangmingzeng, et al. FACILE SYNTHESIS OF HUMIC ACID-COATED IRON OXIDE NANOPARTICLES AND THEIR APPLICATIONS IN WASTEWATER TREATMENT. Functional Materials Letters. 2012;04.
• 5. Mouni L, Belkhiri L, Bollinger J-C, Bouzaza A, Assadi A, Tirri A, et al. Removal of Methylene Blue from aqueous solutions by adsorption on Kaolin: Kinetic and equilibrium studies. Applied Clay Science. 2018;153:38-45.
• 6. Alvarez MT, Crespo C, Mattiasson B. Precipitation of Zn(II), Cu(II) and Pb(II) at bench-scale using biogenic hydrogen sulfide from the utilization of volatile fatty acids. Chemosphere. 2007;66(9):1677-83.
• 7. Wong C-W, Barford JP, Chen G, McKay G. Kinetics and equilibrium studies for the removal of cadmium ions by ion exchange resin. Journal of Environmental Chemical Engineering. 2014;2(1):698-707.
• 8. Sadhukhan B, Mondal N, Chattoraj S. Biosorptive removal of cationic dye from aqueous system: A response surface methodological approach. Clean Technologies and Environmental Policy. 2013;16.
• 9. Qiu Y-R, Mao L-J. Removal of heavy metal ions from aqueous solution by ultrafiltration assisted with copolymer of maleic acid and acrylic acid. Desalination. 2013;329:78-85.
• 10. Gupta VK, Jain R, Nayak A, Agarwal S, Shrivastava M. Removal of the hazardous dye—Tartrazine by photodegradation on titanium dioxide surface. Materials Science and Engineering: C. 2011;31(5):1062-7.
• 11. Shen Z, Jin F, Wang F, McMillan O, Al-Tabbaa A. Sorption of lead by Salisbury biochar produced from British broadleaf hardwood. Bioresource technology. 2015;193:553-6.
• 12. Afroze S, Sen T, Ang H, Nishioka H. Adsorption of methylene blue dye from aqueous solution by novel biomass Eucalyptus sheathiana bark: equilibrium, kinetics, thermodynamics and mechanism. Desalination and Water Treatment. 2015;57:1-21.
• 13. Mondal N, Das K, Das B, Sadhukhan B. Effective utilization of calcareous soil towards the removal of methylene blue from aqueous solution. Clean Technologies and Environmental Policy. 2015;18:1-17.
• 14. Gürses A, Doğar Ç, Yalçın M, Açıkyıldız M, Bayrak R, Karaca S. The adsorption kinetics of the cationic dye, methylene blue, onto clay. Journal of Hazardous Materials. 2006;131(1):217-28.
• 15. Fatiha M, Belkacem B. Adsorption of methylene blue from aqueous solutions using natural clay. Journal of Materials and Environmental Science. 2016;7(1):285-92.
• 16. Caliskana N, Sogutb EG, Savrana A, Kula AR, Kubilaya S. Removal of Cu (II) and Cd (II) ions from aqueous solutions using local raw material as adsorbent: a study in binary systems. DESALINATION AND WATER TREATMENT. 2017;75:132-47.
• 17. Ertaş M, Acemioğlu B, Alma MH, Usta M. Removal of methylene blue from aqueous solution using cotton stalk, cotton waste and cotton dust. Journal of Hazardous Materials. 2010;183(1):421-7.
• 18. Foo KY, Hameed BH. Insights into the modeling of adsorption isotherm systems. Chemical Engineering Journal. 2010;156(1):2-10.
• 19. Salarirad MM, Behnamfard A, editors. Modeling of equilibrium data for free cyanide adsorption onto activated carbon by linear and non-linear regression methods. International Conference on Environment and Industrial Innovation; 2011.
• 20. Rahman M, Sathasivam KV. Heavy metal adsorption onto Kappaphycus sp. from aqueous solutions: the use of error functions for validation of isotherm and kinetics models. BioMed research international. 2015;2015.
• 21. Samarghandi M, Hadi M, Moayedi S, BARJESTEH AF. Two-parameter isotherms of methyl orange sorption by pinecone derived activated carbon. 2009.
• 22. Wong YC, Szeto YS, Cheung WH, McKay G. Equilibrium Studies for Acid Dye Adsorption onto Chitosan. Langmuir. 2003;19(19):7888-94.
• 23. A.O D, Olalekan A, Olatunya A, Dada AO. Langmuir, Freundlich, Temkin and Dubinin–Radushkevich Isotherms Studies of Equilibrium Sorption of Zn 2+ Unto Phosphoric Acid Modified Rice Husk. J Appl Chem. 2012;3:38-45.
• 24. Ho Y. Adsorption of heavy metals from waste streams by peat, University of Birmingham, Birmingham, UK Ph. D: Thesis; 1995.
• 25. Al-Musawi TJ, Brouers F, Zarrabi M. Kinetic modeling of antibiotic adsorption onto different nanomaterials using the Brouers–Sotolongo fractal equation. Environmental Science and Pollution Research. 2017;24(4):4048-57.
• 26. Ahmad MA, Ahmad Puad NA, Bello OS. Kinetic, equilibrium and thermodynamic studies of synthetic dye removal using pomegranate peel activated carbon prepared by microwave-induced KOH activation. Water Resources and Industry. 2014;6:18-35.
• 27. Mohamed EA, Selim AQ, Zayed AM, Komarneni S, Mobarak M, Seliem MK. Enhancing adsorption capacity of Egyptian diatomaceous earth by thermo-chemical purification: Methylene blue uptake. Journal of Colloid and Interface Science. 2019;534:408-19.
• 28. Tarik A, Abdelmjid A, Kabbaj M, Elkouali M, Bennamara A, Charrouf M, et al. Valorization of natural clay from agadir (Morocco): Characterization and study of the isotherms adsorption of Methylene blue. Journal of Chemical and Pharmaceutical Research. 2014;6:599-606.
• 29. Feddal I, Ramdani A, Taleb S, Gaigneaux EM, Batis N, Ghaffour N. Adsorption capacity of methylene blue, an organic pollutant, by montmorillonite clay. Desalination and Water Treatment. 2014;52(13-15):2654-61.
• 30. Shahryari Z, Soltani Goharrizi A, Azadi M. Experimental study of methylene blue adsorption from aqueous solutions onto carbon nano tubes. Int J Water Resour Environ Eng. 2010;2.
• 31. Nsami N, Mbadcam J. The Adsorption Efficiency of Chemically Prepared Activated Carbon from Cola Nut Shells by ZnCl2 on Methylene Blue. Journal of Chemistry. 2013;2013.
• 32. Goyal M, Singh S, Bansal R. Equilibrium and Dynamic Adsorption of Methylene Blue from Aqueous Solutions by Surface Modified Activated Carbons. Carbon letters. 2004;5.
• 33. Gottipati R, Susmita M. Aplication of Biowaste (Waste Generated in Biodiesel Plant) as an Adsorbent for the Removal of Hazardous Dye – Methylene Blue from Aqueous Phase. Brazilian Journal of Chemical Engineering. 2010;27:357-67.
• 34. Al-Degs YS, El-Barghouthi MI, El-Sheikh AH, Walker GM. Effect of solution pH, ionic strength, and temperature on adsorption behavior of reactive dyes on activated carbon. Dyes and Pigments. 2008;77(1):16-23.
• 35. Mukherjee K, Kedia A, Korukonda JR, Dhir S, Paria S. Adsorption Enhancement of Methylene Blue Dye at Kaolinite Clay – Water Interface Influenced by Electrolyte Solutions. RSC Advances. 2015;5.
• 36. Fang Y, Zhou A, Yang W, Araya T, Huang Y, Zhao P, et al. Complex Formation via Hydrogen bonding between Rhodamine B and Montmorillonite in Aqueous Solution. Scientific Reports. 2018;8.
• 37. Patil S, Renukdas S, Patel N. Removal of methylene blue, a basic dye from aqueous solutions by adsorption using teak tree (Tectona grandis) bark powder. International Journal of Environmental Sciences. 2011;1:711-26.
• 38. Tong Ks, Azraa A, Noordin M. Isotherms and Kinetics Studies on the Removal of Methylene Blue from Aqueous Solution by Gambir. International Journal of Environmental Science and Development. 2012:232-6.
• 39. Feddal I, Ramdani A, Taleb S, Gaigneaux E, Batis N, Ghaffour N. Adsorption capacity of methylene blue, an organic pollutant, by montmorillonite clay. Desalination and water treatment. 2013;52:1–8.
• 40. Tan IAW, Ahmad AL, Hameed BH. Adsorption of basic dye on high-surface-area activated carbon prepared from coconut husk: Equilibrium, kinetic and thermodynamic studies. Journal of Hazardous Materials. 2008;154(1):337-46.
• 41. Caliskan N, Kul AR, Alkan S, Sogut EG, Alacabey İ. Adsorption of Zinc(II) on diatomite and manganese-oxide-modified diatomite: A kinetic and equilibrium study. Journal of Hazardous Materials. 2011;193:27-36.
• 42. Araújo CST, Almeida ILS, Rezende HC, Marcionilio SMLO, Léon JJL, de Matos TN. Elucidation of mechanism involved in adsorption of Pb(II) onto lobeira fruit (Solanum lycocarpum) using Langmuir, Freundlich and Temkin isotherms. Microchemical Journal. 2018;137:348-54.
• 43. Nethaji S, Sivasamy A, Mandal A. Adsorption isotherms, kinetics and mechanism for the adsorption of cationic and anionic dyes onto carbonaceous particles prepared from Juglans regia shell biomass. International Journal of Environmental Science and Technology. 2013;10(2):231-42.
• 44. Bujdák J. Adsorption kinetics models in clay systems. The critical analysis of pseudo-second order mechanism. Applied Clay Science. 2020;191:105630.
• 45. Ponnusamy SK, K K. Equilibrium and Kinetic Study of Adsorption of Nickel from Aqueous Solution onto Bael Tree Leaf Powder. Journal of Engineering Science and Technology. 2009;4.
• 46. Plazinski W, Dziuba J, Rudzinski W. Modeling of sorption kinetics: The pseudo-second order equation and the sorbate intraparticle diffusivity. Adsorption. 2013;19.
• 47. Aljeboree AM, Alshirifi AN, Alkaim AF. Kinetics and equilibrium study for the adsorption of textile dyes on coconut shell activated carbon. Arabian Journal of Chemistry. 2017;10:S3381-S93.
• 48. Cestari AR, Vieira EF, Matos JD, dos Anjos DS. Determination of kinetic parameters of Cu (II) interaction with chemically modified thin chitosan membranes. Journal of Colloid and Interface Science. 2005;285(1):288-95.
• 49. Vilvanathan S, Shanthakumar S. Ni(2+) and Co(2+) adsorption using Tectona grandis biochar: kinetics, equilibrium and desorption studies. Environmental technology. 2018;39(4):464-78.
• 50. Zhang L, Loaiciga H, Xu M, Du C, Du Y. Kinetics and Mechanisms of Phosphorus Adsorption in Soils from Diverse Ecological Zones in the Source Area of a Drinking-Water Reservoir. International Journal of Environmental Research and Public Health. 2015;12:14312-26.
• 51. Biswas S, Sen T, Yeneneh A, Meikap B. Synthesis and characterization of a novel Ca- alginate-biochar composite as efficient zinc (Zn 2+) adsorbent: Thermodynamics, process design, mass transfer and isotherm modeling. Separation Science and Technology. 2018:1-19.
• 52. Inyinbor AA, Adekola FA, Olatunji GA. Kinetics, isotherms and thermodynamic modeling of liquid phase adsorption of Rhodamine B dye onto Raphia hookerie fruit epicarp. Water Resources and Industry. 2016;15:14-27.