Voltammetric Determination of Trace Amounts of Lead With Novel Graphite/Bleaching Earth Modified Electrode

Year 2023, Volume: 10 Issue: 3, 659 - 670, 30.08.2023

Elif Tüzün

https://doi.org/10.18596/jotcsa.1283767

Abstract

Modified composite electrodes have gained considerable interest in the detection of heavy metal ions due to their excellent sensitivity, selectivity, stability, and rapid response. Generally, these sensors consist of binder, conductive substance, and modifier. This study examined into the performance of a novel modified electrode that used a graphite–bleaching earth (BE-MCPE) composite performed while detecting trace amounts of Pb(II) using a differential pulse voltammetric technique (DPASV). In order to investigate the properties of BE-MCPE, we employed several analytical techniques, including SEM, SEM-EDX, FTIR, and XRD. These techniques were used to characterize the physical, chemical, and elemental properties of BE-MCPE, as well as its Pb(II) adsorption capacity, providing a comprehensive understanding of its composition and structure. The electrochemical results showed that the modified electrode demonstrated superior sensitivity and selectivity, in detecting Pb(II) ions, with a linear response range of 2.10-7 M to 10.10-7 M, limit of detection (LOD) of 4,89x10-8 mol.L-1, and limit of quantification (LOQ) of 1,63x10-7 mol.L-1. This novel modified electrode can achieve the sensitive detection of trace amounts of Pb(II) in a wide range of wastewater applications.

Keywords

bleaching earth, voltammetry, modified electrode, clay, heavy metal

References

• 1. Wu Q, Bi H-M, Han X-J. Research Progress of Electrochemical Detection of Heavy Metal Ions. Chinese J Anal Chem [Internet]. 2021 Mar 1;49(3):330–40. Available from: <URL>.
• 2. Falina S, Syamsul M, Rhaffor NA, Sal Hamid S, Mohamed Zain KA, Abd Manaf A, et al. Ten Years Progress of Electrical Detection of Heavy Metal Ions (HMIs) Using Various Field-Effect Transistor (FET) Nanosensors: A Review. Biosensors [Internet]. 2021 Nov 25;11(12):478. Available from: <URL>.
• 3. Kumar V, Agrawal S, Bhat SA, Américo-Pinheiro JHP, Shahi SK, Kumar S. Environmental impact, health hazards, and plant-microbes synergism in remediation of emerging contaminants. Clean Chem Eng [Internet]. 2022 Jun;2:100030. Available from: <URL>.
• 4. Mitra S, Chakraborty AJ, Tareq AM, Emran T Bin, Nainu F, Khusro A, et al. Impact of heavy metals on the environment and human health: Novel therapeutic insights to counter the toxicity. J King Saud Univ - Sci [Internet]. 2022 Apr 1;34(3):101865. Available from: <URL>.
• 5. Balali-Mood M, Naseri K, Tahergorabi Z, Khazdair MR, Sadeghi M. Toxic Mechanisms of Five Heavy Metals: Mercury, Lead, Chromium, Cadmium, and Arsenic. Front Pharmacol [Internet]. 2021 Apr 13;12:643972. Available from: <URL>.
• 6. İlhan Ceylan B. Oxovanadium(IV) and Nickel(II) complexes obtained from 2,2′-dihydroxybenzophenone-S-methyl-thiosemicarbazone: Synthesis, characterization, electrochemistry, and antioxidant capability. Inorganica Chim Acta [Internet]. 2021 Mar 1;517:120186. Available from: <URL>.
• 7. Ahmad W, Alharthy RD, Zubair M, Ahmed M, Hameed A, Rafique S. Toxic and heavy metals contamination assessment in soil and water to evaluate human health risk. Sci Rep [Internet]. 2021 Aug 20;11(1):17006. Available from: <URL>.
• 8. Collin MS, Venkatraman SK, Vijayakumar N, Kanimozhi V, Arbaaz SM, Stacey RGS, et al. Bioaccumulation of lead (Pb) and its effects on human: A review. J Hazard Mater Adv [Internet]. 2022 Aug 1;7:100094. Available from: <URL>.
• 9. Penticoff HB, Fortin JS. Toxic/metabolic diseases of the nervous system. In: Neurobiology of Brain Disorders (Second Edition): Biological Basis of Neurological and Psychiatric Disorders [Internet]. Elsevier; 2023. p. 379–401. Available from: <URL>.
• 10. Romero-Estévez D, Yánez-Jácome GS, Navarrete H. Non-essential metal contamination in Ecuadorian agricultural production: A critical review. J Food Compos Anal [Internet]. 2023 Jan 1;115:104932. Available from: <URL>.
• 11. Jomova K, Makova M, Alomar SY, Alwasel SH, Nepovimova E, Kuca K, et al. Essential metals in health and disease. Chem Biol Interact [Internet]. 2022 Nov 1;367:110173. Available from: <URL>.
• 12. Li G, Qi X, Zhang G, Wang S, Li K, Wu J, et al. Low-cost voltammetric sensors for robust determination of toxic Cd(II) and Pb(II) in environment and food based on shuttle-like α-Fe2O3 nanoparticles decorated β-Bi2O3 microspheres. Microchem J [Internet]. 2022 Aug 1;179:107515. Available from: <URL>.
• 13. Mohammed H, Sadeek S, Mahmoud AR, Zaky D. Comparison of AAS, EDXRF, ICP-MS and INAA performance for determination of selected heavy metals in HFO ashes. Microchem J [Internet]. 2016 Sep 1;128:1–6. Available from: <URL>.
• 14. Fei J, Wu X, Sun Y, Zhao L, Min H, Cui X, et al. Preparation of a novel amino functionalized ion-imprinted hybrid monolithic column for the selective extraction of trace copper followed by ICP-MS detection. Anal Chim Acta [Internet]. 2021 Jun 1;1162:338477. Available from: <URL>.
• 15. Geleta GS. A colorimetric aptasensor based on two dimensional (2D) nanomaterial and gold nanoparticles for detection of toxic heavy metal ions: A review. Food Chem Adv [Internet]. 2023 Oct 1;2:100184. Available from: <URL>.
• 16. Jiang H, Lin H, Lin J, Yao-Say Solomon Adade S, Chen Q, Xue Z, et al. Non-destructive detection of multi-component heavy metals in corn oil using nano-modified colorimetric sensor combined with near-infrared spectroscopy. Food Control [Internet]. 2022 Mar 1;133:108640. Available from: <URL>.
• 17. Volynkin SS, Demakov PA, Shuvaeva O V., Kovalenko KA. Metal-organic framework application for mercury speciation using solid phase extraction followed by direct thermal release–electrothermal atomization atomic absorption spectrophotometric detection (ETA AAS). Anal Chim Acta [Internet]. 2021 Sep 8;1177:338795. Available from: <URL>.
• 18. Phan TTT, Nguyen TD, Lee JS. Vacuum plasma treatment on carbon nanoparticles for highly sensitive square wave voltammetric sensor of heavy metal ions. Synth Met [Internet]. 2022 Dec 1;291:117203. Available from: <URL>.
• 19. Lalmalsawmi J, Sarikokba, Tiwari D, Kim D-J. Simultaneous detection of Cd2+ and Pb2+ by differential pulse anodic stripping voltammetry: Use of highly efficient novel Ag0(NPs) decorated silane grafted bentonite material. J Electroanal Chem [Internet]. 2022 Aug 1;918:116490. Available from: <URL>.
• 20. Jaber L, Elgamouz A, Kawde A-N. An insight to the filtration mechanism of Pb(II) at the surface of a clay ceramic membrane through its preconcentration at the surface of a graphite/clay composite working electrode. Arab J Chem [Internet]. 2022 Dec 1;15(12):104303. Available from: <URL>.
• 21. Alabarse FG, Conceição RV, Balzaretti NM, Schenato F, Xavier AM. In-situ FTIR analyses of bentonite under high-pressure. Appl Clay Sci [Internet]. 2011 Jan 1;51(1–2):202–8. Available from: <URL>.
• 22. Shi W, Wang Z, Li F, Xu Y, Chen X. Multilayer adsorption of lead (Pb) and fulvic acid by Chlorella pyrenoidosa: Mechanism and impact of environmental factors. Chemosphere [Internet]. 2023 Jul 1;329:138596. Available from: <URL>.
• 23. Jin G, Gu P, Qin L, Li K, Guan Y, Su H. Preparation of manganese-oxides-coated magnetic microcrystalline cellulose via KMnO4 modification: Improving the counts of the acid groups and adsorption efficiency for Pb(II). Int J Biol Macromol [Internet]. 2023 Jun 1;239:124277. Available from: <URL>.
• 24. Neelaveni M, Santhana Krishnan P, Ramya R, Sonia Theres G, Shanthi K. Montmorillonite/graphene oxide nanocomposite as superior adsorbent for the adsorption of Rhodamine B and Nickel ion in binary system. Adv Powder Technol [Internet]. 2019 Mar 1;30(3):596–609. Available from: <URL>.
• 25. Huang H, Yi D, Lu Y, Wu X, Bai Y, Meng X, et al. Study on the adsorption behavior and mechanism of dimethyl sulfide on silver modified bentonite by in situ FTIR and temperature-programmed desorption. Chem Eng J [Internet]. 2013 Jun;225:447–55. Available from: <URL>.
• 26. Debye P. Zerstreuung von Röntgenstrahlen. Ann Phys [Internet]. 1915;351(6):809–23. Available from: <URL>.
• 27. Tesfaye E, Chandravanshi BS, Negash N, Tessema M. A new modified carbon paste electrode using N1-hydroxy-N1,N2-diphenylbenzamidine for the square wave anodic stripping voltammetric determination of Pb(II) in environmental samples. Sens Bio-Sensing Res [Internet]. 2022 Dec;38:100520. Available from: <URL>.
• 28. Rebolledo-Perales LE, Álvarez Romero GA, Ibarra I, Galán-Vidal CA, Flores-Aguilar JF, Pérez-Silva I. Quantitative Analysis of Pb(II) Based on Differential Pulse Anodic Stripping Voltammetry and IIP-Carbon Paste Electrodes. J Electrochem Soc [Internet]. 2022 May 1;169(5):057504. Available from: <URL>.
• 29. Yadav R, Berlina AN, Zherdev A V., Gaur MS, Dzantiev BB. Rapid and selective electrochemical detection of Pb2+ ions using aptamer-conjugated alloy nanoparticles. SN Appl Sci [Internet]. 2020 Dec 25;2(12):2077. Available from: <URL>.
• 30. Zhang Y, Li C, Su Y, Mu W, Han X. Simultaneous detection of trace Cd(II) and Pb(II) by differential pulse anodic stripping voltammetry using a bismuth oxycarbide/nafion electrode. Inorg Chem Commun [Internet]. 2020 Jan;111:107672. Available from: <URL>.
• 31. Hassan KM, Gaber SE, Altahan MF, Azzem MA. Single and simultaneous voltammetric sensing of lead(II), cadmium(II) and zinc(II) using a bimetallic Hg-Bi supported on poly(1,2-diaminoanthraquinone)/glassy carbon modified electrode. Sens Bio-Sensing Res [Internet]. 2020 Aug;29:100369. Available from: <URL>.
• 32. Phal S, Nguyễn H, Berisha A, Tesfalidet S. In situ Bi/carboxyphenyl-modified glassy carbon electrode as a sensor platform for detection of Cd2+ and Pb2+ using square wave anodic stripping voltammetry. Sens Bio-Sensing Res [Internet]. 2021 Dec;34:100455. Available from: <URL>.
• 33. Pizarro J, Segura R, Tapia D, Navarro F, Fuenzalida F, Jesús Aguirre M. Inexpensive and green electrochemical sensor for the determination of Cd(II) and Pb(II) by square wave anodic stripping voltammetry in bivalve mollusks. Food Chem [Internet]. 2020 Aug;321:126682. Available from: <URL>.
• 34. Munir A, Shah A, Nisar J, Ashiq MN, Akhter MS, Shah AH. Selective and simultaneous detection of Zn2+, Cd2+, Pb2+, Cu2+, Hg2+ and Sr2+ using surfactant modified electrochemical sensors. Electrochim Acta [Internet]. 2019 Nov 10;323:134592. Available from: <URL>.