Research Article
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Molecular Interaction Studies on Physiochemical and Derived Properties of Binary mixtures at Atmospheric Pressure

Year 2024, Volume: 11 Issue: 3, 1017 - 1024, 30.08.2024
https://doi.org/10.18596/jotcsa.1349140

Abstract

The physiochemical properties like refractive indices, densities, and static dielectric constants of binary mixtures were measured over the entire concentration range. Refractive index and densities were measured at 293.15 K, and dielectric constants at (293.15, 298.15, and 303.15 K) temperatures for the n-propanol-formamide binary system. From dielectric data, the related and excess properties were calculated and reported in this work. From experimental refractive indices and densities, various related and excess properties were estimated and reported in this study. Static dielectric constants, densities, and refractive index of the binary system increase with the increase in the mole fraction of formamide. The results obtained were discussed in terms of intermolecular interactions, structural effects, hydrogen bonding, and other possible interactions between like and unlike molecules of the binary system.

Supporting Institution

Not applicable

Project Number

NO

Thanks

The authors are thankful to the Head of the Department of Physics, Dr. Babasaheb Ambedkar Marathwada University-Aurangabad (M.S.) India for providing the experimental facility for the said work.

References

  • 1. Long B, Wang Z, Yang H, Ding Y. Intermolecular interactions of 1,2-diethoxyethane with toluene: An insight from surface and volumetric properties at different temperatures. J Mol Liq [Internet]. 2018 Jan 1;249:1–8. Available from: <URL>.
  • 2. Yilmaz H, Güler S. Excess properties of methanol-water binary system at various temperatures. Nuovo Cim D [Internet]. 1998 Dec;20(12):1853–61. Available from: <URL>.
  • 3. Jouyban A, Soltanpour S, Chan HK. A simple relationship between dielectric constant of mixed solvents with solvent composition and temperature. Int J Pharm [Internet]. 2004 Jan 28;269(2):353–60. Available from: <URL>.
  • 4. Navarkhele VV, Bhanarkar MK. High-frequency dielectric response of the binary mixture formamide–butylene glycol. Phys Chem Liq [Internet]. 2010 Feb 11;48(1):89–98. Available from: <URL>.
  • 5. Kabir MH, Motin MA, Huque ME. Densities and excess molar volumes of Methanol, Ethanol and N- Propanol in pure Water and in Water + Surf Excel solutions at different temperatures. Phys Chem Liq [Internet]. 2004 Jun 16;42(3):279–90. Available from: <URL>.
  • 6. Trivedi CM, Rana VA. Static permittivity, refractive index, density and related properties of binary mixtures of pyridine and 1-propanol at different temperatures. Indian J Pure Appl Phys [Internet]. 2014;52:183–91. Available from: <URL>.
  • 7. Navarkhele V V. Dielectric and Excess Properties of Glycols with Formamide Binary Mixtures at Different Temperatures. Russ J Phys Chem A [Internet]. 2018 Jul 8;92(7):1417–22. Available from: <URL>.
  • 8. Sengwa RJ, Sankhla S, Shinyashiki N. Dielectric Parameters and Hydrogen Bond Interaction Study of Binary Alcohol Mixtures. J Solution Chem [Internet]. 2008 Feb 14;37(2):137–53. Available from: <URL>.
  • 9. Kirkwood JG. The dielectric polarization of polar liquids. J Chem Phys [Internet]. 1939 Oct 1;7(10):911–9. Available from: <URL>.
  • 10. Kumbharkhane AC, Puranik SM, Mehrotra SC. Dielectric relaxation of tert-butyl alcohol–water mixtures using a time-domain technique. J Chem Soc, Faraday Trans [Internet]. 1991 Jan 1;87(10):1569–73. Available from: <URL>.
  • 11. Kumbharkhane AC, Puranik SM, Mehrotra SC. Dielectric relaxation studies of aqueous N,N-dimethylformamide using a picosecond time domain technique. J Solution Chem [Internet]. 1993 Mar;22(3):219–29. Available from: <URL>.
  • 12. El‐Dossoki FI. Refractive index and density measurements for selected binary protic‐protic, aprotic‐aprotic, and aprotic‐protic systems at temperatures from 298.15 K to 308.15 K. J Chinese Chem Soc [Internet]. 2007 Oct 25;54(5):1129–37. Available from: <URL>.
  • 13. Mognaschi ER, Laboranti LM. Association of pure polar liquids: dielectric properties of docosanoic acid. J Chem Soc Faraday Trans [Internet]. 1996 Jan 1;92(18):3367–9. Available from: <URL>.
  • 14. Ray SK, Rath J, Dwivedi C. Excess Molar Polarization in Binary Mixtures of Polar Liquids. Phys Chem Liq [Internet]. 2001 Mar;39(2):227–37. Available from: <URL>.
  • 15. Kim JI. A Critical Study of the Ph 4 AsPh 4 B Assumption for single ion thermodynamics in amphiprotic and dipolar-aprotic solvents; evaluation of physical parameters relevant to theoretical consideration. Zeitschrift für Phys Chemie [Internet]. 1978 Feb 1;113(2):129–50. Available from: <URL>.
  • 16. Oswal S. Studies on density, viscosity, dielectric constant, and refractive index of binary mixtures of esters in benzene and carbon tetrachloride. Can J Chem [Internet]. 1988 Jan 1;66(1):111–6. Available from: <URL>.
  • 17. González EJ, Requejo PF, Maia FM, Domínguez Á, Macedo EA. Solubility, density and excess molar volume of binary mixtures of aromatic compounds and common ionic liquids at T= 283.15 K and atmospheric pressure. Phys Chem Liq [Internet]. 2015 Jul 4;53(4):419–28. Available from: <URL>.
  • 18. Aliaj F, Syla N, Kurtishaj A, Elezaj N, Tolaj Z, Arbneshi T, et al. Densities, refractive indices, and derived properties of binary mixtures of ethanol with benzene and pyridine at various temperatures under atmospheric pressure. Int J Thermophys [Internet]. 2020 Apr 3;41(4):49. Available from: <URL>.
  • 19. Pottel R. N. E. Hill, W. E. Vaughan, A. H. Price und M. Davies: Dielectric properties and molecular behaviour D. Van Nostrand. In: Berichte der Bunsengesellschaft für physikalische Chemie [Internet]. John Wiley & Sons, Ltd; 1970. p. 176–7. Available from: <URL>.
  • 20. Navarkhele VV, Bhanarkar MK. Microwave dielectric response of binary mixture of N,N-dimethylformamide with propylene glycol using TDR method. Mol Phys [Internet]. 2009 Sep 10;107(17):1823–30. Available from: <URL>.
  • 21. Kumbharkhane AC, Puranik SM, Mehrotra SC. Structural study of amide-water mixtures using dielectric relaxation technique. J Mol Liq [Internet]. 1992 Mar 1;51(3–4):261–77. Available from: <URL>.
  • 22. Navarkhele V, Navarkhele A. Static Dielectric Constants, Densities, Refractive Indices and Related Properties of Binary Mixtures at Various Temperatures Under Atmospheric Pressure. Int J Thermodyn [Internet]. 2022 Sep 1;25(3):1–10. Available from: <URL>.
  • 23. Lone BG, Undre PB, Patil SS, Khirade PW, Mehrotra SC. Dielectric study of methanol–ethanol mixtures using TDR method. J Mol Liq [Internet]. 2008 May 30;141(1–2):47–53. Available from: <URL>.
  • 24. Hosamani MT, Fattepur RH, Deshpande DK, Mehrotra SC. Temperature- and frequency-dependent dielectric studies of p-fluorophenylacetonitrile–methanol mixtures using time-domain reflectometry. J Chem Soc, Faraday Trans [Internet]. 1995 Jan 1;91(4):623–6. Available from: <URL>.
  • 25. Navarkhele VV, Bhanarkar MK. Dielectric relaxation study of formamide–propylene glycol using time domain reflectometry. Phys Chem Liq [Internet]. 2011 Jul;49(4):550–9. Available from: <URL>.
  • 26. Navarkhele A V., Sakhare RS, Vijayendraswamy SM, Navarkhele V V. Dielectric constant, density, and refractive index in binary mixtures of ethanol with N,N-Dimethylformamide at 293.15 K. Russ J Phys Chem A [Internet]. 2022 May 25;96(5):945–53. Available from: <URL>.
  • 27. Noh HJ, Park SJ, In SJ. Excess molar volumes and deviations of refractive indices at 298.15K for binary and ternary mixtures with pyridine or aniline or quinoline. J Ind Eng Chem [Internet]. 2010 Mar 25;16(2):200–6. Available from: <URL>
  • 28. Singh S, Parveen S, Shukla D, Gupta M, Shukla JP. Volumetric, optical, acoustical and viscometric study of molecular association in binary mixtures of butylamine with 1-butanol and tert-butanol. Acta Phys Pol A [Internet]. 2007;111(6):847–58. Available from: <URL>.
  • 29. Aniya V, Kumari A, Reddy R, Satyavathi B. Measurement and modeling of phase equilibrium, volumetric properties and molar refractivity of 2-methylpropan-2-ol + ethane-1,2-diol. J Solution Chem [Internet]. 2017 Jun 6;46(6):1177–201. Available from: <URL>.
Year 2024, Volume: 11 Issue: 3, 1017 - 1024, 30.08.2024
https://doi.org/10.18596/jotcsa.1349140

Abstract

Project Number

NO

References

  • 1. Long B, Wang Z, Yang H, Ding Y. Intermolecular interactions of 1,2-diethoxyethane with toluene: An insight from surface and volumetric properties at different temperatures. J Mol Liq [Internet]. 2018 Jan 1;249:1–8. Available from: <URL>.
  • 2. Yilmaz H, Güler S. Excess properties of methanol-water binary system at various temperatures. Nuovo Cim D [Internet]. 1998 Dec;20(12):1853–61. Available from: <URL>.
  • 3. Jouyban A, Soltanpour S, Chan HK. A simple relationship between dielectric constant of mixed solvents with solvent composition and temperature. Int J Pharm [Internet]. 2004 Jan 28;269(2):353–60. Available from: <URL>.
  • 4. Navarkhele VV, Bhanarkar MK. High-frequency dielectric response of the binary mixture formamide–butylene glycol. Phys Chem Liq [Internet]. 2010 Feb 11;48(1):89–98. Available from: <URL>.
  • 5. Kabir MH, Motin MA, Huque ME. Densities and excess molar volumes of Methanol, Ethanol and N- Propanol in pure Water and in Water + Surf Excel solutions at different temperatures. Phys Chem Liq [Internet]. 2004 Jun 16;42(3):279–90. Available from: <URL>.
  • 6. Trivedi CM, Rana VA. Static permittivity, refractive index, density and related properties of binary mixtures of pyridine and 1-propanol at different temperatures. Indian J Pure Appl Phys [Internet]. 2014;52:183–91. Available from: <URL>.
  • 7. Navarkhele V V. Dielectric and Excess Properties of Glycols with Formamide Binary Mixtures at Different Temperatures. Russ J Phys Chem A [Internet]. 2018 Jul 8;92(7):1417–22. Available from: <URL>.
  • 8. Sengwa RJ, Sankhla S, Shinyashiki N. Dielectric Parameters and Hydrogen Bond Interaction Study of Binary Alcohol Mixtures. J Solution Chem [Internet]. 2008 Feb 14;37(2):137–53. Available from: <URL>.
  • 9. Kirkwood JG. The dielectric polarization of polar liquids. J Chem Phys [Internet]. 1939 Oct 1;7(10):911–9. Available from: <URL>.
  • 10. Kumbharkhane AC, Puranik SM, Mehrotra SC. Dielectric relaxation of tert-butyl alcohol–water mixtures using a time-domain technique. J Chem Soc, Faraday Trans [Internet]. 1991 Jan 1;87(10):1569–73. Available from: <URL>.
  • 11. Kumbharkhane AC, Puranik SM, Mehrotra SC. Dielectric relaxation studies of aqueous N,N-dimethylformamide using a picosecond time domain technique. J Solution Chem [Internet]. 1993 Mar;22(3):219–29. Available from: <URL>.
  • 12. El‐Dossoki FI. Refractive index and density measurements for selected binary protic‐protic, aprotic‐aprotic, and aprotic‐protic systems at temperatures from 298.15 K to 308.15 K. J Chinese Chem Soc [Internet]. 2007 Oct 25;54(5):1129–37. Available from: <URL>.
  • 13. Mognaschi ER, Laboranti LM. Association of pure polar liquids: dielectric properties of docosanoic acid. J Chem Soc Faraday Trans [Internet]. 1996 Jan 1;92(18):3367–9. Available from: <URL>.
  • 14. Ray SK, Rath J, Dwivedi C. Excess Molar Polarization in Binary Mixtures of Polar Liquids. Phys Chem Liq [Internet]. 2001 Mar;39(2):227–37. Available from: <URL>.
  • 15. Kim JI. A Critical Study of the Ph 4 AsPh 4 B Assumption for single ion thermodynamics in amphiprotic and dipolar-aprotic solvents; evaluation of physical parameters relevant to theoretical consideration. Zeitschrift für Phys Chemie [Internet]. 1978 Feb 1;113(2):129–50. Available from: <URL>.
  • 16. Oswal S. Studies on density, viscosity, dielectric constant, and refractive index of binary mixtures of esters in benzene and carbon tetrachloride. Can J Chem [Internet]. 1988 Jan 1;66(1):111–6. Available from: <URL>.
  • 17. González EJ, Requejo PF, Maia FM, Domínguez Á, Macedo EA. Solubility, density and excess molar volume of binary mixtures of aromatic compounds and common ionic liquids at T= 283.15 K and atmospheric pressure. Phys Chem Liq [Internet]. 2015 Jul 4;53(4):419–28. Available from: <URL>.
  • 18. Aliaj F, Syla N, Kurtishaj A, Elezaj N, Tolaj Z, Arbneshi T, et al. Densities, refractive indices, and derived properties of binary mixtures of ethanol with benzene and pyridine at various temperatures under atmospheric pressure. Int J Thermophys [Internet]. 2020 Apr 3;41(4):49. Available from: <URL>.
  • 19. Pottel R. N. E. Hill, W. E. Vaughan, A. H. Price und M. Davies: Dielectric properties and molecular behaviour D. Van Nostrand. In: Berichte der Bunsengesellschaft für physikalische Chemie [Internet]. John Wiley & Sons, Ltd; 1970. p. 176–7. Available from: <URL>.
  • 20. Navarkhele VV, Bhanarkar MK. Microwave dielectric response of binary mixture of N,N-dimethylformamide with propylene glycol using TDR method. Mol Phys [Internet]. 2009 Sep 10;107(17):1823–30. Available from: <URL>.
  • 21. Kumbharkhane AC, Puranik SM, Mehrotra SC. Structural study of amide-water mixtures using dielectric relaxation technique. J Mol Liq [Internet]. 1992 Mar 1;51(3–4):261–77. Available from: <URL>.
  • 22. Navarkhele V, Navarkhele A. Static Dielectric Constants, Densities, Refractive Indices and Related Properties of Binary Mixtures at Various Temperatures Under Atmospheric Pressure. Int J Thermodyn [Internet]. 2022 Sep 1;25(3):1–10. Available from: <URL>.
  • 23. Lone BG, Undre PB, Patil SS, Khirade PW, Mehrotra SC. Dielectric study of methanol–ethanol mixtures using TDR method. J Mol Liq [Internet]. 2008 May 30;141(1–2):47–53. Available from: <URL>.
  • 24. Hosamani MT, Fattepur RH, Deshpande DK, Mehrotra SC. Temperature- and frequency-dependent dielectric studies of p-fluorophenylacetonitrile–methanol mixtures using time-domain reflectometry. J Chem Soc, Faraday Trans [Internet]. 1995 Jan 1;91(4):623–6. Available from: <URL>.
  • 25. Navarkhele VV, Bhanarkar MK. Dielectric relaxation study of formamide–propylene glycol using time domain reflectometry. Phys Chem Liq [Internet]. 2011 Jul;49(4):550–9. Available from: <URL>.
  • 26. Navarkhele A V., Sakhare RS, Vijayendraswamy SM, Navarkhele V V. Dielectric constant, density, and refractive index in binary mixtures of ethanol with N,N-Dimethylformamide at 293.15 K. Russ J Phys Chem A [Internet]. 2022 May 25;96(5):945–53. Available from: <URL>.
  • 27. Noh HJ, Park SJ, In SJ. Excess molar volumes and deviations of refractive indices at 298.15K for binary and ternary mixtures with pyridine or aniline or quinoline. J Ind Eng Chem [Internet]. 2010 Mar 25;16(2):200–6. Available from: <URL>
  • 28. Singh S, Parveen S, Shukla D, Gupta M, Shukla JP. Volumetric, optical, acoustical and viscometric study of molecular association in binary mixtures of butylamine with 1-butanol and tert-butanol. Acta Phys Pol A [Internet]. 2007;111(6):847–58. Available from: <URL>.
  • 29. Aniya V, Kumari A, Reddy R, Satyavathi B. Measurement and modeling of phase equilibrium, volumetric properties and molar refractivity of 2-methylpropan-2-ol + ethane-1,2-diol. J Solution Chem [Internet]. 2017 Jun 6;46(6):1177–201. Available from: <URL>.
There are 29 citations in total.

Details

Primary Language English
Subjects Solution Chemistry
Journal Section RESEARCH ARTICLES
Authors

Vaijanath Navarkhele 0000-0002-7276-4179

Aishwarya Navarkhele 0000-0001-9040-6300

Project Number NO
Early Pub Date June 27, 2024
Publication Date August 30, 2024
Submission Date August 28, 2023
Acceptance Date May 19, 2024
Published in Issue Year 2024 Volume: 11 Issue: 3

Cite

Vancouver Navarkhele V, Navarkhele A. Molecular Interaction Studies on Physiochemical and Derived Properties of Binary mixtures at Atmospheric Pressure. JOTCSA. 2024;11(3):1017-24.