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Grafting of Cellulose: Synthesis and Characterization

Year 2018, Volume: 1 Issue: 2, 49 - 55, 30.11.2018

Abstract

In this study, cellulose
methacrylate was firstly prepared by the reaction of methacryloyl chloride with
primary OH groups on raw cellulose. The graft copolymerization of cellulose was
made with our own synthesized 2-(4-Methoxyphenylamino)-2-oxoethyl methacrylate
(MPAEMA) monomer by method of free radical polymerization. Cellulose, cellulose
methacrylate and its graft copolymer (Cell.met-g-MPAEMA) were characterized by FT-IR
spectra, elemental and thermal analysis.

References

  • 1. Çankaya N., Besci G., Synthesis, characterization, thermal properties and reactivity ratios of methacrylate copolymers including methoxy group, Journal of the Faculty of Engineering and Architecture of Gazi University, 33:3, 1155-1170, 2018. 2. Nicholson J.W., Brookman P.J., Lacy O. M., Sayers G.S., Wilson A.D., A study of the nature and formation of zinc polyacrylate cement using Fourier transform infrared spectroscopy, Journal of Biomedical Materials Research, 22, 623-631, 1988.3. Parker S., Braden M., Water absorption of methacrylate soft lining materials, Biomaterials, 10, 91-95, 1989.4. Patel J.N., Dolia M.B., Patel K.H., Patel R.M., Homopolymer of 4-chloro-3-methyl Phenyl Methacrylate and its Copolymers with Butyl Methacrylate: Synthesis, Characterization, Reactivity Ratios and Antimicrobial Activity, Journal of Polymer Research, 13, 219-228, 2006.5. Açıkbaş Y., Çankaya N., Capan R., Erdogan M., Soykan C., Swelling behavior of the 2-(4-methoxyphenylamino)-2-oxoethyl methacrylate monomer LB thin film exposed to various organic vapors by quartz crystal microbalance technique, Journal of Macromolecular Science, Part A:Pure and Applied Chemistry, 53(1), 18–25, 2016.6. Bordes P.E., Avérous P.L., Nano-biocomposites: biodegradable polyester/nanoclay systems, Progress in Polymer Science, 34:125-155, 2009.7. Petersson L., Oksman K., Biopolymer based nanocomposites: comparing layered silicates and microcrystalline cellulose as nanoreinforcement composites, Science and Technology, 66:2187-2196, 2006. 8. Çankaya N., Sökmen Ö., Chitosan-Clay Bionanocomposites, Journal of Polytechnic, 19(3), 283-295, 2016.9. Çankaya N., Sökmen Ö., Biopolymers and its montmorillonit clay nanocomposites, Journal of Polytechnic, 20(3), 663-673, 2017. 10. Kırcı H., Ateş S., Akgül M., Selüloz türevleri ve kullanım yerleri, Fen ve Mühendislik Dergisi, Cilt 4, (2): 119-130, 2001.11. Çankaya N., Cellulose grafting by atom transfer radical polymerization method, Cellulose-Fundamental Aspects and Current Trends, Chapter-3, 2015. http://www.intechopen.com/books/cellulose-fundamental-aspects-and-current-trends/cellulose-grafting-by-atom-transfer-radical-polymerization-method12. Williams P.A., Renewable resources for functional polymers and biomaterials, RSC Publishing, Glyndwr University, UK, 2011.13. Çankaya N., Sökmen Ö., Selüloz-Cloisite kili içeren biyonanokompozitler, 1st International Academic Research Congress, Antalya-Side, 2016.14. Çankaya N., Temüz M.M., Characterization and Monomer Reactivity Ratios of Grafted Cellulose with N-(4-nitrophenyl)acrylamide and Methyl Methacrylate by Atom Transfer Radical Polymerization, Cellulose Chemistry and Technology, 46 (9-10), 551-558, 2012. 15. N Çankaya N., Temüz M.M., Monomer Reactivity Ratios of Cellulose Grafted with N-cyclohexylacrylamide and Methyl Methacrylate by Atom Transfer Radical Polymerization”, Cellulose Chemistry and Technology, 48 (3-4), 209-215, 2014. 16. Çankaya N., Temüz M.M., Grafting of Some Monomers onto Cellulose and Determination of Metal and Water Uptake Properties, Cellulose Chemistry and Technology, 49 (2), 135-141, 2015. 17. Çankaya N., Temüz M.M., Yakuphanoglu F., Grafting of some monomers onto cellulose by atom transfer radical polymerization. Electrical conductivity and thermal properties of resulting copolymers, Cellulose Chemistry and Technology, 52 (1-2), 19-26, 2018.
Year 2018, Volume: 1 Issue: 2, 49 - 55, 30.11.2018

Abstract

References

  • 1. Çankaya N., Besci G., Synthesis, characterization, thermal properties and reactivity ratios of methacrylate copolymers including methoxy group, Journal of the Faculty of Engineering and Architecture of Gazi University, 33:3, 1155-1170, 2018. 2. Nicholson J.W., Brookman P.J., Lacy O. M., Sayers G.S., Wilson A.D., A study of the nature and formation of zinc polyacrylate cement using Fourier transform infrared spectroscopy, Journal of Biomedical Materials Research, 22, 623-631, 1988.3. Parker S., Braden M., Water absorption of methacrylate soft lining materials, Biomaterials, 10, 91-95, 1989.4. Patel J.N., Dolia M.B., Patel K.H., Patel R.M., Homopolymer of 4-chloro-3-methyl Phenyl Methacrylate and its Copolymers with Butyl Methacrylate: Synthesis, Characterization, Reactivity Ratios and Antimicrobial Activity, Journal of Polymer Research, 13, 219-228, 2006.5. Açıkbaş Y., Çankaya N., Capan R., Erdogan M., Soykan C., Swelling behavior of the 2-(4-methoxyphenylamino)-2-oxoethyl methacrylate monomer LB thin film exposed to various organic vapors by quartz crystal microbalance technique, Journal of Macromolecular Science, Part A:Pure and Applied Chemistry, 53(1), 18–25, 2016.6. Bordes P.E., Avérous P.L., Nano-biocomposites: biodegradable polyester/nanoclay systems, Progress in Polymer Science, 34:125-155, 2009.7. Petersson L., Oksman K., Biopolymer based nanocomposites: comparing layered silicates and microcrystalline cellulose as nanoreinforcement composites, Science and Technology, 66:2187-2196, 2006. 8. Çankaya N., Sökmen Ö., Chitosan-Clay Bionanocomposites, Journal of Polytechnic, 19(3), 283-295, 2016.9. Çankaya N., Sökmen Ö., Biopolymers and its montmorillonit clay nanocomposites, Journal of Polytechnic, 20(3), 663-673, 2017. 10. Kırcı H., Ateş S., Akgül M., Selüloz türevleri ve kullanım yerleri, Fen ve Mühendislik Dergisi, Cilt 4, (2): 119-130, 2001.11. Çankaya N., Cellulose grafting by atom transfer radical polymerization method, Cellulose-Fundamental Aspects and Current Trends, Chapter-3, 2015. http://www.intechopen.com/books/cellulose-fundamental-aspects-and-current-trends/cellulose-grafting-by-atom-transfer-radical-polymerization-method12. Williams P.A., Renewable resources for functional polymers and biomaterials, RSC Publishing, Glyndwr University, UK, 2011.13. Çankaya N., Sökmen Ö., Selüloz-Cloisite kili içeren biyonanokompozitler, 1st International Academic Research Congress, Antalya-Side, 2016.14. Çankaya N., Temüz M.M., Characterization and Monomer Reactivity Ratios of Grafted Cellulose with N-(4-nitrophenyl)acrylamide and Methyl Methacrylate by Atom Transfer Radical Polymerization, Cellulose Chemistry and Technology, 46 (9-10), 551-558, 2012. 15. N Çankaya N., Temüz M.M., Monomer Reactivity Ratios of Cellulose Grafted with N-cyclohexylacrylamide and Methyl Methacrylate by Atom Transfer Radical Polymerization”, Cellulose Chemistry and Technology, 48 (3-4), 209-215, 2014. 16. Çankaya N., Temüz M.M., Grafting of Some Monomers onto Cellulose and Determination of Metal and Water Uptake Properties, Cellulose Chemistry and Technology, 49 (2), 135-141, 2015. 17. Çankaya N., Temüz M.M., Yakuphanoglu F., Grafting of some monomers onto cellulose by atom transfer radical polymerization. Electrical conductivity and thermal properties of resulting copolymers, Cellulose Chemistry and Technology, 52 (1-2), 19-26, 2018.
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Details

Primary Language English
Journal Section Articles
Authors

Nevin Çankaya

Publication Date November 30, 2018
Submission Date November 27, 2018
Acceptance Date November 29, 2018
Published in Issue Year 2018 Volume: 1 Issue: 2

Cite

APA Çankaya, N. (2018). Grafting of Cellulose: Synthesis and Characterization. Journal of Physical Chemistry and Functional Materials, 1(2), 49-55.
AMA Çankaya N. Grafting of Cellulose: Synthesis and Characterization. Journal of Physical Chemistry and Functional Materials. November 2018;1(2):49-55.
Chicago Çankaya, Nevin. “Grafting of Cellulose: Synthesis and Characterization”. Journal of Physical Chemistry and Functional Materials 1, no. 2 (November 2018): 49-55.
EndNote Çankaya N (November 1, 2018) Grafting of Cellulose: Synthesis and Characterization. Journal of Physical Chemistry and Functional Materials 1 2 49–55.
IEEE N. Çankaya, “Grafting of Cellulose: Synthesis and Characterization”, Journal of Physical Chemistry and Functional Materials, vol. 1, no. 2, pp. 49–55, 2018.
ISNAD Çankaya, Nevin. “Grafting of Cellulose: Synthesis and Characterization”. Journal of Physical Chemistry and Functional Materials 1/2 (November 2018), 49-55.
JAMA Çankaya N. Grafting of Cellulose: Synthesis and Characterization. Journal of Physical Chemistry and Functional Materials. 2018;1:49–55.
MLA Çankaya, Nevin. “Grafting of Cellulose: Synthesis and Characterization”. Journal of Physical Chemistry and Functional Materials, vol. 1, no. 2, 2018, pp. 49-55.
Vancouver Çankaya N. Grafting of Cellulose: Synthesis and Characterization. Journal of Physical Chemistry and Functional Materials. 2018;1(2):49-55.