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EFFECT OF SILANE COUPLING AGENT CONTENT ON MECHANICAL PROPERTIES OF HYDROXYAPATITE/POLY(METHYL METHACRYLATE) DENTURE BASE COMPOSITE

Year 2021, Volume: 5 Issue: 1, 37 - 45, 15.02.2021
https://doi.org/10.26900/jsp.5.1.04

Abstract

In removable prosthodontics, poly(methyl methacrylate) (PMMA) is the most suitable for the construction of denture bases. Intra-orally, the subjected stress intensity during the function accelerate the fracture of acrylic resin denture bases. Extra-orally, fracture occurs when dentures are accidentally dropped on a hard surface. The aim of the current study was to investigate the effect of coupling agent concentration on the mechanical properties of Hydroxyapatite/Poly(methyl methacrylate) (HA/PMMA) denture base composite. The Hydroxyapatite (HA) treated with four different ratios (i.e. 0, 5, 7 and 10 wt%) of 3-(trimethoxysily) propyl methacrylate (γMPS) silane coupling agent was added into the PMMA matrix. The mechanical performance of the composite was evaluated by conducting fracture toughness, flexural and tensile tests. An improvement of 13.83% and 9.62% in the tensile and flexural strength respectively, was achieved. The tensile and flexural modulus of the composite increased by 19.04% and 12.5% respectively. A significant improvement of 29.26% in the fracture toughness was observed at 10 wt% of γ-MPS. 10 wt% of γ-MPS is the optimum amount of coupling agent for obtaining balanced mechanical properties

References

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  • CHOW, W. S., KHIM, L., ARIFFIN, A., AHMAD, Z. & ISHAK, M. (2008). Flexural Properties of Hydroxyapatite Reinforced Poly(Methyl Methacrylate) Composites. Journal of Reinforced Plastics and Composites, 27, 945-952.
  • COTTERELL, B., CHIA, J. & HBAIEB, K. (2007). Fracture mechanisms and fracture toughness in semicrystalline polymer nanocomposites. Engineering Fracture Mechanics, 74, 1054-1078.
  • DELLA BONA, Á., BENETTI, P., BORBA, M. & CECCHETTI, D. (2008). Flexural and diametral tensile strength of composite resins. Brazilian Oral Research, 22, 84-89.
  • ELSHEREKSI, N. W., GHAZALI, M., MUCHTAR, A. & AZHARI, C. H. (2017a). Review of titanate coupling agents and their application for dental composite fabrication. Dental materials journal, 2016-014.
  • ELSHEREKSI, N. W., GHAZALI, M. J., MUCHTAR, A. & AZHARI, C. H. (2017b). Studies on the effects of titanate and silane coupling agents on the performance of poly (methyl methacrylate)/barium titanate denture base nanocomposites. Journal of Dentistry, 56, 121-132.
  • FU, S.-Y., FENG, X.-Q., LAUKE, B. & MAI, Y.-W. (2008). Effects of particle size, particle/matrix interface adhesion and particle loading on mechanical properties of particulate–polymer composites. Composites Part B: Engineering, 39, 933-961.
  • FU, S., SUN, Z., HUANG, P., LI, Y. & HU, N. (2019). Some basic aspects of polymer nanocomposites: A critical review. Nano Materials Science, 1, 2-30.
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  • HAMIZAH, A., JAAFAR, M., OTHMAN, R., KAWASHITA, M. & ABDUL RAZAK, N. H. (2012). Mechanical and thermal properties of polymethylmethacrylate bone cement composites incorporated with hydroxyapatite and glass‐ceramic fillers. Journal of Applied Polymer Science, 125, 661-669.
  • KHAJE, S. & JAMSHIDI, M. (2015). The effect of aging and silanization on the mechanical properties of fumed silica-based dental composite. Journal of Dental Biomaterials, 2, 124-132.
  • KUNDIE, F., AZHARI, C. H. & AHMAD, Z. A. (2018a). Effect of nano-and micro-alumina fillers on some properties of poly (methyl methacrylate) denture base composites. Journal of the Serbian Chemical Society, 83, 75-91.
  • KUNDIE, F., AZHARI, C. H., MUCHTAR, A. & AHMAD, Z. A. (2018b). Effects of filler size on the mechanical properties of polymer-filled dental composites: A review of recent developments. Journal of Physical Science, 29, 141-165.
  • LAUKE, B. (2008). Effect of particle size on fracture toughness of polymer composites. Composites Science and Technology, 68, 3365-3372.
  • LI, Y., YANG, Z., LIU, J., LIN, C., ZHANG, J. & ZHENG, X. (2019). Enhancing fracture toughness of polymer-based functional energetic composites by filling nano-graphene in matrix. Polymer Composites, 40, E1151-E1161.
  • LIU, H. & WEBSTER, T. J. (2010). Mechanical properties of dispersed ceramic nanoparticles in polymer composites for orthopedic applications. International Journal of Nanomedicine, 5, 299-313.
  • MARGHALANI, H. Y. (2014). Resin-Based Dental Composite Materials. In: ANTONIAC, I. V. (ed.) Handbook of Bioceramics and Biocomposites. Cham: Springer International Publishing.
  • MCCABE, J. & WALLS, A. (2013). Applied Dental Materials 9th ed, John Wiley & Sons: Hoboken, New Jersey, United States.
  • MEI, Q., LIN, L., WANG, J., CAI, B., ZOU, Q., LI, J., LI, Y. & ZUO, Y. (2019). Chemical reaction kinetics and the characteristic properties of injectable adhesives of nano-hydroxyapatite/Ag3PO4/polyurethane for bone and tooth repair. SN Applied Sciences, 1, 746.
  • NAKATANI, H., IWAKURA, K., MIYAZAKI, K., OKAZAKI, N. & TERANO, M. (2011). Effect of Chemical Structure of Silane Coupling Agent on Interface Adhesion Properties of Syndiotactic Polypropylene/Cellulose Composite. Journal of Applied Polymer Science, 119, 1732-1741.
  • NILAGIRI BALASUBRAMANIAN, K. B. & RAMESH, T. (2018). Role, effect, and influences of micro and nano-fillers on various properties of polymer matrix composites for microelectronics: A review. Polymers for Advanced Technologies, 29, 1568-1585.
  • PRATAP, B., GUPTA, R. K., BHARDWAJ, B. & NAG, M. (2019). Resin based restorative dental materials: characteristics and future perspectives. The Japanese dental science review, 55, 126-138.
  • SIDERIDOU, I. & KARABELA, M. (2009). Effect of the amount of 3-methacyloxypropyltrimethoxysilane coupling agent on physical properties of dental resin nanocomposites. Dental Materials, 25, 1315-24.
  • ŠINKOVEC, R. & MUŠIČ, B. (2020). Effect of Organosilane Coupling Agents on Thermal, Rheological and Mechanical Properties of Silicate-Filled Epoxy Molding Compound. Materials, 13, 177.
  • ŠUPOVÁ, M. (2009). Problem of hydroxyapatite dispersion in polymer matrices: a review. Journal of Materials Science: Materials in Medicine, 20, 1201-1213.
  • THAM, W., CHOW, W. & ISHAK, Z. M. (2010). Simulated body fluid and water absorption effects on poly (methyl methacrylate)/hydroxyapatite denture base composites. Express Polymer Letters, 4, 517–528.
  • TURON, P., DEL VALLE, L. J., ALEMÁN, C. & PUIGGALÍ, J. (2018). Grafting of Hydroxyapatite for Biomedical Applications. Biopolymer Grafting. Elsevier: Amsterdam, Netherlands.
  • WANG, M. & BONFIELD, W. (2001). Chemically coupled hydroxyapatite-polyethylene composites: structure and properties. Biomaterials, 22, 1311-1320.
  • WANG, T., CHOW, L. C., FRUKHTBEYN, S. A., TING, A. H., DONG, Q., YANG, M. & MITCHELL, J. W. (2011). Improve the Strength of PLA/HA Composite Through the Use of Surface Initiated Polymerization and Phosphonic Acid Coupling Agent. Journal of research of the National Institute of Standards and Technology, 116, 785-796.
  • XAVIER, T. A., FRÓES-SALGADO, N. R. D. G., MEIER, M. M. & BRAGA, R. R. (2015). Influence of silane content and filler distribution on chemical-mechanical properties of resin composites. Brazilian Oral Research, 29, 1-8.
Year 2021, Volume: 5 Issue: 1, 37 - 45, 15.02.2021
https://doi.org/10.26900/jsp.5.1.04

Abstract

References

  • ALRAHLAH, A. (2018). Diametral tensile strength, flexural strength, and surface microhardness of bioactive bulk fill restorative. The Journal of Contemporary Dental Practice, 19, 13-19.
  • AMDJADI, P., GHASEMI, A., NAJAFI, F. & NOJEHDEHIAN, H. (2017). Pivotal role of filler/matrix interface in dental composites. Biomedical Research-India, 28, 1054-1065.
  • ANTONUCCI, J. M., DICKENS, S. H., FOWLER, B. O., XU, H. H. K. & MCDONOUGH, W. G. (2005). Chemistry of Silanes: Interfaces in Dental Polymers and Composites. Journal of research of the National Institute of Standards and Technology, 110, 541-558.
  • BARTCZAK, Z. & GALESKI, A. (2014). Mechanical Properties of Polymer Blends. In: UTRACKI, L. A. & WILKIE, C. A. (eds.) Polymer Blends Handbook. Dordrecht: Springer Netherlands.
  • CAMPO, E. (2008). Mechanical properties of polymeric materials. Selection of Polymeric Materials, Plastics Design Library, William Andrew Publishing, Norwich, NY.
  • CHOW, W. S., KHIM, L., ARIFFIN, A., AHMAD, Z. & ISHAK, M. (2008). Flexural Properties of Hydroxyapatite Reinforced Poly(Methyl Methacrylate) Composites. Journal of Reinforced Plastics and Composites, 27, 945-952.
  • COTTERELL, B., CHIA, J. & HBAIEB, K. (2007). Fracture mechanisms and fracture toughness in semicrystalline polymer nanocomposites. Engineering Fracture Mechanics, 74, 1054-1078.
  • DELLA BONA, Á., BENETTI, P., BORBA, M. & CECCHETTI, D. (2008). Flexural and diametral tensile strength of composite resins. Brazilian Oral Research, 22, 84-89.
  • ELSHEREKSI, N. W., GHAZALI, M., MUCHTAR, A. & AZHARI, C. H. (2017a). Review of titanate coupling agents and their application for dental composite fabrication. Dental materials journal, 2016-014.
  • ELSHEREKSI, N. W., GHAZALI, M. J., MUCHTAR, A. & AZHARI, C. H. (2017b). Studies on the effects of titanate and silane coupling agents on the performance of poly (methyl methacrylate)/barium titanate denture base nanocomposites. Journal of Dentistry, 56, 121-132.
  • FU, S.-Y., FENG, X.-Q., LAUKE, B. & MAI, Y.-W. (2008). Effects of particle size, particle/matrix interface adhesion and particle loading on mechanical properties of particulate–polymer composites. Composites Part B: Engineering, 39, 933-961.
  • FU, S., SUN, Z., HUANG, P., LI, Y. & HU, N. (2019). Some basic aspects of polymer nanocomposites: A critical review. Nano Materials Science, 1, 2-30.
  • GOYAL, S., SHYAMALA, P., MIGLANI, R. & NARAYANAN, L. (2006). Metal collars - are they serving any purpose? The Journal of Indian Prosthodontic Society, 6, 14-18.
  • HAMIZAH, A., JAAFAR, M., OTHMAN, R., KAWASHITA, M. & ABDUL RAZAK, N. H. (2012). Mechanical and thermal properties of polymethylmethacrylate bone cement composites incorporated with hydroxyapatite and glass‐ceramic fillers. Journal of Applied Polymer Science, 125, 661-669.
  • KHAJE, S. & JAMSHIDI, M. (2015). The effect of aging and silanization on the mechanical properties of fumed silica-based dental composite. Journal of Dental Biomaterials, 2, 124-132.
  • KUNDIE, F., AZHARI, C. H. & AHMAD, Z. A. (2018a). Effect of nano-and micro-alumina fillers on some properties of poly (methyl methacrylate) denture base composites. Journal of the Serbian Chemical Society, 83, 75-91.
  • KUNDIE, F., AZHARI, C. H., MUCHTAR, A. & AHMAD, Z. A. (2018b). Effects of filler size on the mechanical properties of polymer-filled dental composites: A review of recent developments. Journal of Physical Science, 29, 141-165.
  • LAUKE, B. (2008). Effect of particle size on fracture toughness of polymer composites. Composites Science and Technology, 68, 3365-3372.
  • LI, Y., YANG, Z., LIU, J., LIN, C., ZHANG, J. & ZHENG, X. (2019). Enhancing fracture toughness of polymer-based functional energetic composites by filling nano-graphene in matrix. Polymer Composites, 40, E1151-E1161.
  • LIU, H. & WEBSTER, T. J. (2010). Mechanical properties of dispersed ceramic nanoparticles in polymer composites for orthopedic applications. International Journal of Nanomedicine, 5, 299-313.
  • MARGHALANI, H. Y. (2014). Resin-Based Dental Composite Materials. In: ANTONIAC, I. V. (ed.) Handbook of Bioceramics and Biocomposites. Cham: Springer International Publishing.
  • MCCABE, J. & WALLS, A. (2013). Applied Dental Materials 9th ed, John Wiley & Sons: Hoboken, New Jersey, United States.
  • MEI, Q., LIN, L., WANG, J., CAI, B., ZOU, Q., LI, J., LI, Y. & ZUO, Y. (2019). Chemical reaction kinetics and the characteristic properties of injectable adhesives of nano-hydroxyapatite/Ag3PO4/polyurethane for bone and tooth repair. SN Applied Sciences, 1, 746.
  • NAKATANI, H., IWAKURA, K., MIYAZAKI, K., OKAZAKI, N. & TERANO, M. (2011). Effect of Chemical Structure of Silane Coupling Agent on Interface Adhesion Properties of Syndiotactic Polypropylene/Cellulose Composite. Journal of Applied Polymer Science, 119, 1732-1741.
  • NILAGIRI BALASUBRAMANIAN, K. B. & RAMESH, T. (2018). Role, effect, and influences of micro and nano-fillers on various properties of polymer matrix composites for microelectronics: A review. Polymers for Advanced Technologies, 29, 1568-1585.
  • PRATAP, B., GUPTA, R. K., BHARDWAJ, B. & NAG, M. (2019). Resin based restorative dental materials: characteristics and future perspectives. The Japanese dental science review, 55, 126-138.
  • SIDERIDOU, I. & KARABELA, M. (2009). Effect of the amount of 3-methacyloxypropyltrimethoxysilane coupling agent on physical properties of dental resin nanocomposites. Dental Materials, 25, 1315-24.
  • ŠINKOVEC, R. & MUŠIČ, B. (2020). Effect of Organosilane Coupling Agents on Thermal, Rheological and Mechanical Properties of Silicate-Filled Epoxy Molding Compound. Materials, 13, 177.
  • ŠUPOVÁ, M. (2009). Problem of hydroxyapatite dispersion in polymer matrices: a review. Journal of Materials Science: Materials in Medicine, 20, 1201-1213.
  • THAM, W., CHOW, W. & ISHAK, Z. M. (2010). Simulated body fluid and water absorption effects on poly (methyl methacrylate)/hydroxyapatite denture base composites. Express Polymer Letters, 4, 517–528.
  • TURON, P., DEL VALLE, L. J., ALEMÁN, C. & PUIGGALÍ, J. (2018). Grafting of Hydroxyapatite for Biomedical Applications. Biopolymer Grafting. Elsevier: Amsterdam, Netherlands.
  • WANG, M. & BONFIELD, W. (2001). Chemically coupled hydroxyapatite-polyethylene composites: structure and properties. Biomaterials, 22, 1311-1320.
  • WANG, T., CHOW, L. C., FRUKHTBEYN, S. A., TING, A. H., DONG, Q., YANG, M. & MITCHELL, J. W. (2011). Improve the Strength of PLA/HA Composite Through the Use of Surface Initiated Polymerization and Phosphonic Acid Coupling Agent. Journal of research of the National Institute of Standards and Technology, 116, 785-796.
  • XAVIER, T. A., FRÓES-SALGADO, N. R. D. G., MEIER, M. M. & BRAGA, R. R. (2015). Influence of silane content and filler distribution on chemical-mechanical properties of resin composites. Brazilian Oral Research, 29, 1-8.
There are 34 citations in total.

Details

Primary Language English
Subjects Dentistry
Journal Section Basic Sciences and Engineering
Authors

Jamal Moammar Aldabıb 0000-0003-2768-760X

Publication Date February 15, 2021
Published in Issue Year 2021 Volume: 5 Issue: 1

Cite

APA Aldabıb, J. M. (2021). EFFECT OF SILANE COUPLING AGENT CONTENT ON MECHANICAL PROPERTIES OF HYDROXYAPATITE/POLY(METHYL METHACRYLATE) DENTURE BASE COMPOSITE. Journal of Scientific Perspectives, 5(1), 37-45. https://doi.org/10.26900/jsp.5.1.04