Establishing Near Infra Red Spectroscopy (NIR) Calibration for Starch Analysis in Corn Grain

Year 2019, Volume: 12 Issue: 1, 7 - 14, 31.03.2019

Ercan Tomas İsmail Bayram

https://doi.org/10.30607/kvj.459701

Abstract

This
study has been carried out to calibrate the starch values of 320 corn samples
taken from Soil Products Offices (TMO) in seven different geographical regions
of by using an NIR instrument. The corn samples used in the study were selected
from the regions where corn production is intensive in Turkey and brought to
the laboratory. The corn samples brought to the laboratory were milled and then
spectra were formed. Subsequently, the starch values were determined in the
laboratory with the use of wet chemical analysis methods. The calibration
values generated were R= 0.6410; R² = 0.4109 Standard Deviation =
4.4208, R = 0.5854 from the validation set; R² = 0.3427 Standard
Deviation = 4.5662. The calibration interval in the study was 44.53 and 45.72,
respectively. This study has concluded that more samples representing the 7
different regions in Turkey for the starch contents of corn are needed in order
to generate scientifically reliable results with the FT-NIR device.  

Keywords

Corn, Starch, NIR, Calibration

Mısır Tahılında Nişasta Analizi İçin Near Infra Red Spectroscopy (NIR) Kalibrasyonu Oluşturulması

Abstract

Bu araştırma Türkiye'nin yedi
farklı coğrafi bölgesindeki TMO ofislerinden getirilen toplam 320 adet mısır
numunesindeki nişasta değerlerinin NIR cihazı kullanılarak kalibrasyonunu
yapmak amacıyla gerçekleştirilmiştir. Araştırmada kullanılan mısır numuneleri
Türkiye’de mısır üretiminin yoğun olarak yapıldığı bölgelerden seçilmiştir ve
laboratuvara getirilmiştir. Laboratuvara getirilen mısır numunelerinin
öğütülmesi işlemi yapılmış, daha sonra spektraları oluşturulmuştur. Akabinde,
laboratuarda yaş kimyasal analiz yöntemiyle nişasta değerleri bulunmuştur.
Oluşturulan kalibrasyon setinin R=0.6410; R²= 0.4109 Standart Sapma
= 4.4208 şeklinde değerleri alınmış, validasyon setinden ise R=0.5854; R²=
0.3427 Standart Sapma = 4.5662 değerleri elde edilmiştir. Araştırmada,
kalibrasyon aralığı 44.53 bulunurken, validasyon aralığı ise 45.72. olarak
bulunmuştur. Sonuç olarak bu araştırma ile Türkiye’nin 7 farklı bölgesini
temsil edebilecek mısır örneklerindeki nişasta miktarı FT-NIR cihazı
kullanılarak elde edilen kalibrasyonların bilimsel açıdan daha doğru sonuçlar
vermesi için daha fazla miktarda numune ile çalışmaların yapılması gerektiğine
kanaat getirilmiştir.

Keywords

NIR, Mısır, Nişasta, Kalibrasyon

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