Research Article
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Year 2024, , 52 - 55, 30.12.2024
https://doi.org/10.46572/naturengs.1586386

Abstract

Project Number

TÜBİTAK, KBAG-119Z608 and AU-BAP, FBA-2020-5403 and FDK-2022-6056

References

  • Al Zoubi, W., Kamil, M. P., Fatimah, S., Nashrah, N., & Ko, Y. G. (2020). Recent advances in hybrid organic-inorganic materials with spatial architecture for state-of the- art applications. Progress in Materials Science, 112, 100663.
  • Sıdır, İ., Sıdır, Y. G., Khan, N., & Berber, H. (2021). Optoelectronic and photonic properties of π-conjugated benzonitrile derivative bis-Schiff base by solution technique. Optik, 241, 166825.
  • Al Zoubi, W., Khan, M. E., & Ko, Y. G. (2022). A simple method to functionalize the surface of plasma electrolysis produced inorganic coatings for growing different organic structure. Progress in Organic Coatings, 171, 107008.
  • Mantur, S., Patil, M. K., Najare, M. S., Nadaf, A. A., Yaseen, M., Gaonkar, S., & Kamble, R. R. (2021). Design and synthesis of D-π-A form of p-nitrophenylacrylonitrile substituted triphenylamine chromophores; Photophysical, electrochemical properties, DFT and thermal studies. ChemistrySelect, 6(45), 12811-12819.
  • Gündüz, B. (2013). Effects of molarity and solvents on the optical properties of the solutions of tris [4-(5- dicyanomethylidenemethyl-2-thienyl) phenyl] amine (TDCV-TPA) and structural properties of its film. Optical Materials, 36(2), 425-436.
  • Turan, N., Buldurun, K., & Gündüz, B. (2017). Synthesis and structures of Fe (II), Zn (II) and Pd (II) complexes with a Schiff base derived from methyl 2-amino-6-methyl-4, 5, 6, 7-tetrahydrothieno [2, 3-c] pyridine-3-carboxylate and comparison of their optical constants for different solvents and molarities. Journal of Nanoelectronics and Optoelectronics, 12(9), 1028-1040.
  • Sun, H., Chen, S., Zhong, A., Sun, R., Jin, J., Yang, J.,& Lu, S. (2023). Tuning photophysical properties via positional isomerization of the pyridine ring in donor– acceptor-structured aggregation-induced emission luminogens based on phenylmethylene pyridineacetonitrile derivatives. Molecules, 28(7), 3282.
  • Zhu, L., & Zhao, Y. (2013). Cyanostilbene-based intelligent organic optoelectronic materials. Journal of Materials Chemistry C, 1(6), 1059-1065.
  • Kim, M. J., An, T. K., Kim, S. O., Cha, H., Kim, H. N., Xiofeng, T., & Kim, Y. H. (2015). Molecular design and ordering effects of alkoxy aromatic donor in a DPP copolymer on OTFTs and OPVs. Materials Chemistry and Physics, 153, 63-71.
  • Fang, J. K., Sun, T., Tian, Y., Zhang, Y., Jin, C., Xu, Z., ... & Wang, H. (2017). Novel diyne-bridged dyes for efficient dye-sensitized solar cells. Materials Chemistry and Physics, 195, 1-9.
  • Sharma, G. D., Patel, K. R., Roy, M. S., & Misra, R. (2014). Characterization of two new (A–π) 2–D–A type dyes with different central D unit and their application for dye sensitized solar cells. Organic Electronics, 15(8), 1780- 1790.
  • Jeong, H. G., Khim, D., Jung, E., Yun, J. M., Kim, J., Ku, J., & Kim, D. Y. (2013). Synthesis and characterization of a novel ambipolar polymer semiconductor based on a fumaronitrile core as an electron-withdrawing group. Journal of Polymer Science Part A: Polymer Chemistry, 51(5), 1029-1039.
  • Mao, G., Orita, A., Fenenko, L., Yahiro, M., Adachi, C., & Otera, J. (2009). Blue emitting fluorophores of phenyleneethynylenes substituted by diphenylethenyl terminal groups for organic light-emitting diodes. Materials Chemistry and Physics, 115(1), 378- 384.
  • Guillot, R., Loupy, A., Meddour, A., Pellet, M., & Petit, A. (2005). Solvent-free condensation of arylacetonitrile with aldehydes. Tetrahedron, 61(42), 10129-10137.
  • Yakalı, G., Çoban, M. B., Özen, F., Özen, L. B., Gündüz, B., & Cin, G. T. (2021). The importance of polymorphism dependent aggregation induced enhanced emission of the acrylonitrile derivative: Helical J type and antiparallel h type stacking modes. ChemistrySelect, 6(41), 11392- 11406.
  • Tripathy, S. K. (2015). Refractive indices of semiconductors from energy gaps. Optical materials, 46, 240-246.

Concentration-Driven Enhancement of Optical Properties in 3MeO-4ClAN for Advanced Photonic Applications

Year 2024, , 52 - 55, 30.12.2024
https://doi.org/10.46572/naturengs.1586386

Abstract

In this study, we investigated the photophysical properties of 2-(4-chlorophenyl)-3-(3-methoxyphenyl)acrylonitrile (3MeO-4ClAN) at various concentrations in DMSO solvent. We specifically examined the effect of different solute concentrations on the optoelectronic properties of this compound, with a focus on applications requiring a low optical band gap. The results demonstrate the potential of 3MeO-4ClAN for optoelectronic applications across a range of concentrations. Experimental optical measurements were performed at different molarities, covering wavelengths from 190 to 1100 nm, using ultraviolet-visible (UV-vis) spectral analysis at room temperature.

Supporting Institution

TÜBİTAK and Akdeniz University

Project Number

TÜBİTAK, KBAG-119Z608 and AU-BAP, FBA-2020-5403 and FDK-2022-6056

Thanks

We would like to thank the Scientific and Technological Research Council of Turkey (TÜBİTAK, KBAG-119Z608) and Akdeniz University Scientific Research Projects Unit (AU-BAP, FBA-2020-5403 and FDK-2022-6056) for their financial support.

References

  • Al Zoubi, W., Kamil, M. P., Fatimah, S., Nashrah, N., & Ko, Y. G. (2020). Recent advances in hybrid organic-inorganic materials with spatial architecture for state-of the- art applications. Progress in Materials Science, 112, 100663.
  • Sıdır, İ., Sıdır, Y. G., Khan, N., & Berber, H. (2021). Optoelectronic and photonic properties of π-conjugated benzonitrile derivative bis-Schiff base by solution technique. Optik, 241, 166825.
  • Al Zoubi, W., Khan, M. E., & Ko, Y. G. (2022). A simple method to functionalize the surface of plasma electrolysis produced inorganic coatings for growing different organic structure. Progress in Organic Coatings, 171, 107008.
  • Mantur, S., Patil, M. K., Najare, M. S., Nadaf, A. A., Yaseen, M., Gaonkar, S., & Kamble, R. R. (2021). Design and synthesis of D-π-A form of p-nitrophenylacrylonitrile substituted triphenylamine chromophores; Photophysical, electrochemical properties, DFT and thermal studies. ChemistrySelect, 6(45), 12811-12819.
  • Gündüz, B. (2013). Effects of molarity and solvents on the optical properties of the solutions of tris [4-(5- dicyanomethylidenemethyl-2-thienyl) phenyl] amine (TDCV-TPA) and structural properties of its film. Optical Materials, 36(2), 425-436.
  • Turan, N., Buldurun, K., & Gündüz, B. (2017). Synthesis and structures of Fe (II), Zn (II) and Pd (II) complexes with a Schiff base derived from methyl 2-amino-6-methyl-4, 5, 6, 7-tetrahydrothieno [2, 3-c] pyridine-3-carboxylate and comparison of their optical constants for different solvents and molarities. Journal of Nanoelectronics and Optoelectronics, 12(9), 1028-1040.
  • Sun, H., Chen, S., Zhong, A., Sun, R., Jin, J., Yang, J.,& Lu, S. (2023). Tuning photophysical properties via positional isomerization of the pyridine ring in donor– acceptor-structured aggregation-induced emission luminogens based on phenylmethylene pyridineacetonitrile derivatives. Molecules, 28(7), 3282.
  • Zhu, L., & Zhao, Y. (2013). Cyanostilbene-based intelligent organic optoelectronic materials. Journal of Materials Chemistry C, 1(6), 1059-1065.
  • Kim, M. J., An, T. K., Kim, S. O., Cha, H., Kim, H. N., Xiofeng, T., & Kim, Y. H. (2015). Molecular design and ordering effects of alkoxy aromatic donor in a DPP copolymer on OTFTs and OPVs. Materials Chemistry and Physics, 153, 63-71.
  • Fang, J. K., Sun, T., Tian, Y., Zhang, Y., Jin, C., Xu, Z., ... & Wang, H. (2017). Novel diyne-bridged dyes for efficient dye-sensitized solar cells. Materials Chemistry and Physics, 195, 1-9.
  • Sharma, G. D., Patel, K. R., Roy, M. S., & Misra, R. (2014). Characterization of two new (A–π) 2–D–A type dyes with different central D unit and their application for dye sensitized solar cells. Organic Electronics, 15(8), 1780- 1790.
  • Jeong, H. G., Khim, D., Jung, E., Yun, J. M., Kim, J., Ku, J., & Kim, D. Y. (2013). Synthesis and characterization of a novel ambipolar polymer semiconductor based on a fumaronitrile core as an electron-withdrawing group. Journal of Polymer Science Part A: Polymer Chemistry, 51(5), 1029-1039.
  • Mao, G., Orita, A., Fenenko, L., Yahiro, M., Adachi, C., & Otera, J. (2009). Blue emitting fluorophores of phenyleneethynylenes substituted by diphenylethenyl terminal groups for organic light-emitting diodes. Materials Chemistry and Physics, 115(1), 378- 384.
  • Guillot, R., Loupy, A., Meddour, A., Pellet, M., & Petit, A. (2005). Solvent-free condensation of arylacetonitrile with aldehydes. Tetrahedron, 61(42), 10129-10137.
  • Yakalı, G., Çoban, M. B., Özen, F., Özen, L. B., Gündüz, B., & Cin, G. T. (2021). The importance of polymorphism dependent aggregation induced enhanced emission of the acrylonitrile derivative: Helical J type and antiparallel h type stacking modes. ChemistrySelect, 6(41), 11392- 11406.
  • Tripathy, S. K. (2015). Refractive indices of semiconductors from energy gaps. Optical materials, 46, 240-246.
There are 16 citations in total.

Details

Primary Language English
Subjects Photonics, Optoelectronics and Optical Communications, Organic Chemical Synthesis
Journal Section Research Articles
Authors

Leyla Babali Özen 0000-0001-9023-6604

Furkan Özen 0000-0003-1178-1167

Günseli Turgut Cin 0000-0001-9658-8344

Bayram Gündüz 0000-0002-1447-7534

Project Number TÜBİTAK, KBAG-119Z608 and AU-BAP, FBA-2020-5403 and FDK-2022-6056
Publication Date December 30, 2024
Submission Date November 16, 2024
Acceptance Date December 9, 2024
Published in Issue Year 2024

Cite

APA Babali Özen, L., Özen, F., Turgut Cin, G., Gündüz, B. (2024). Concentration-Driven Enhancement of Optical Properties in 3MeO-4ClAN for Advanced Photonic Applications. NATURENGS, 5(2), 52-55. https://doi.org/10.46572/naturengs.1586386