GO@Fe3O4 Katkılı Polimerik Kompozit Membranların Hazırlanması ve Karakterizasyonu

Year 2023, Volume: 5 Issue: 2, 38 - 52, 31.12.2023

İlker Akın , Erhan Zor , Haluk Bingöl

https://doi.org/10.47112/neufmbd.2023.8

Abstract

Son zamanlarda giderek artan tarımsal ve endüstriyel faaliyetler nedeniyle sentetik organik/inorganik maddeler ve metaller gibi zararlı ve zehirli kirleticilerin su kaynaklarına salınması kamuoyunda giderek artan bir endişe yaratmaktadır. Bu zehirli ve zararlı maddelerden arsenik, bazı bölgelerde su kaynakları için önemli bir tehdit oluşturmaktadır. Arsenik zehirli, kanserojen ve her yerde bulunduğundan dünya çapında içme suyundan arseniğin giderimi önemlidir. Bu nedenle, içme suyundan arsenik giderimi için basit, daha az maliyetli ve çevre dostu tekniklerin geliştirilmesi gerekmektedir. Nanomalzemeler ile membranların güçlendirilmesi son zamanlarda yaygın olarak kullanılan bir yöntem haline gelmiştir. Ayrıca nano ölçekli inorganik katkı maddelerinin seçilip eklenmesiyle hazırlanan ince film nanokompozit hibrit malzemelerin kullanılması membran teknolojisine yeni bir boyut kazandırmıştır. Bu çalışmada, Fe3O4 nanoparçacıkları ile modifiye edilmiş grafen oksit (GO) katkılı polisülfon çözeltisinin gözenekli destek malzemesi üzerine kaplanması ile yüksek geçirgenlik ve reddetme oranına sahip nanomalzeme destekli membranlar geliştirilmiştir. Hazırlanan nanokompozit malzemeler ve membranlar taramalı elektron mikroskobu (SEM), atomik kuvvet mikroskobu (AFM), X-ışını fotoelektron spekrofotometresi (XPS) ve temas açısı (CA) teknikleri kullanılarak karakterize edilmiştir. Membran performans çalışmaları saf su geçirgenliği ve arsenik reddi çalışmaları ile gerçekleştirilmiş ve hazırlanan PSf bazlı nanokompozit membranlarda farklı GO/Fe3O4 oranlarında dahil olmak üzere yüksek performans gözlemlenmiş ve %95 arsenik reddi oranına ulaşılmıştır.

Keywords

Arsenik, Grafen oksit, Fe3O4, membran

Supporting Institution

Necmettin Erbakan Üniversitesi Bilimsel Araştırma Projeleri Koordinatörlüğü ve Selçuk Üniversitesi Bilimsel Araştırma Projeleri Koordinatörlüğü

Project Number

141710001 ve 16401085

Thanks

Necmettin Erbakan Üniversitesi Bilimsel Araştırma Projeleri (Proje No:141710001) ve Selçuk Üniversitesi Bilimsel Araştırma Projeleri (Proje No: 16401085) Koordinatörlüklerine kısmi finansal desteklerinden dolayı teşekkür ederiz.

Preparation and Characterization of GO/Fe3O4 Doped Polymeric Composite Membranes

Abstract

The release of harmful and toxic pollutants such as synthetic organic/inorganic substances and metals into water resources due to increasing agricultural and industrial activities in recent times has been creating increasing public concern.Arsenic, one of these toxic and harmful substances, poses a significant threat to water resources in some regions. Removal of arsenic from drinking water is important worldwide because arsenic is toxic, carcinogenic and ubiquitous. Therefore, it is necessary to develop simple, less costly and environmentally friendly techniques for arsenic removal from drinking water. Strengthening membranes with nanomaterials has recently become a widely used method. In addition, the use of thin-film nanocomposite hybrid materials prepared by selecting and adding nano-scale inorganic additives has added a new dimension to membrane technology. In this study, nanomaterial supported membranes with high permeability and rejection rate were developed by coating the polysulfone solution modified with Fe3O4 nanoparticles on the porous support sheet material. The prepared nanocomposite materials and membranes were characterized using scanning electron microscopy (SEM), atomic force microscopy (AFM), X-ray photoelectron spectrophotometer (XPS) and contact angle (CA) techniques.Membrane performance studies have been carried out with pure water permeability and arsenic rejection studies and prepared PSf-based including at different GO/Fe3O4 ratios in the nanocomposites membranes have been observed high performance and achieved 95% arsenic rejection rate.

Keywords

Arsenic, graphene oxide, Fe3O4, membrane

Project Number

141710001 ve 16401085

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