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Nanoteknoloji ve Geleceğin Çevreci Polimeri Nanoselüloz

Year 2018, Volume: 5 Issue: 2, 185 - 195, 01.12.2018
https://doi.org/10.17568/ogmoad.419758

Abstract











Her alanda etkin ve ilerici değişikliklerin oluşturulmasında itici bir güç olan nanoteknoloji, orman ürünleri sektöründe de kendine yer bulmaya başlamıştır. Özellikle son yıllarda nanobilimi, malzeme bilimi ve orman ürünleri biliminin multidisipliner bir yapı ile ortaklaşa çalışması yeni nesil kompozit malzemelerin, biyokompozitlerin ve nanokompozitlerin geliştirilmesinde büyük rol oynamıştır. Geliştirilen bu inovatif malzemeler geleneksel malzemelerin yerini almakta ve geleneksel üretim tekniklerinin, makinelerinin de rollerini değiştirmesini ve kendini güncellemesini sağlamaktadır. Ağaç malzemenin bileşenlerinden birisi olan selüloz kendi içerisinde birbirine bağlı nano boyutta yapıtaşlarına sahiptir. Nanoselüloz adı verilen bu yapıtaşları saç kalınlığının yaklaşık 10 binde biri küçüklüğünde lifleri ve partikülleri içermektedir. Nanoselüloz ağaç malzemeye mekaniksel gücünü veren doğal, yenilenebilir ve mucizevi bir polimerdir. Doğal polimerik yapısı birçok uygulamada kullanılmasına olanak sağlayan nanoselüloz günümüzde otomotiv, elektronik, inşaat ve ambalajlama gibi sektörlerde kullanılmaya başlanmıştır. Nanoselüloz, hafif olmasına karşın sağladığı yüksek performans özellikleri ile endüstri ve akademi tarafından ilgi gören, geleceğin değerli malzemelerinden birisi olarak kendine yer oluşturmaya başlamıştır. 

Bu çalışmada, nanoteknoloji ve geleceğin malzemesi nanoselüloz hakkında son yıllarda yapılmış çalışmalardan detaylı bilgiler derlenmiş ve söz konusu malzemelerin türleri, üretim teknolojileri, küresel üreticileri ve gelecekteki kullanım alanları hakkında teknik bilgiler paylaşılmıştır.  

References

  • Alemdar A., and Sain, M. (2008). Isolation and characterization of nanofibers from agricultural residues: wheat straw and soy hulls. Bioresour. Technol. 99;1664–1671.
  • Abitbol, T., Rivkin, A., Cao, Y., Nevo, Y., Abraham, E., Ben-Shalom, T., Lapidot, S., Shoseyov, O. (2016). Nanocellulose, a tiny fiber with huge applications. Current opinion in biotechnology. 39;76–88.
  • Bai, W., Holbery J., and Li, K. C. (2009). A technique for production of nanocrystalline cellulose with a narrow size distribution. Cellulose. 16;455-466.
  • Battista, O.A. (1950). Hydrolysis and crystallization of cellulose. J. Ind. Eng. Chem. 42;502–7.
  • Cai Z., Rudie A.W., Stark N.M., Sabo R.C. and Ralph S.A. (2013). Chapter 6: New products and product categories” In the global forest sector: Changes, practices and prospects. Edited by Hansen E., Panwar R. and Vlosky R. 129-149. Boca Raton, FL: CRC Press.
  • Campano C., Merayo N., Balea A., Tarres Q., Aguilar M. D., Mutje P., Negro C., Blanco A. (2018). Mechanical and chemical dispersion of nanocelluloses to improve their reinforcing effect on recycled paper. Cellulose. 25;269-280.
  • Chen, W. S., Yu, H., Liu, Yi., Hai, Y., Zhang, M., Chen, P. (2011). Isolation and characterization of cellulose nanofibers from four plant cellulose fibers using a chemical-ultrasonic process. Cellulose. 18;433–442.
  • Chen, Y. W., Lee, H. V., Juan, J. C., Phang S. M. (2016). Production of new cellulose material from red algae marine biomass Gelidium elegans. Carbohydr. Polym. 151;1210-1219.
  • Fleming, K., Gray, D.G., Matthews, S. (2001). Cellulose crystallites. Chemistry-A European Journal. 7;1831-1835.
  • Helbert W., Nishiyama Y., Okano T., and Sugiyama J. (1998). Molecular imaging of halocynthia papillosa cellulose. J. Struct. Biol. 124;42–50.
  • Herrick, F.W., Casebier, R.L., Hamilton, J.K., Sandberg, K.R. (1983). Microfibrillated Cellulose: Morphology and Accessibility. J. Appl. Polym. Sci. 37;797-813.
  • Hon, D. N. S. (1994). Cellulose: a random walk along its historical path. Cellulose . 1;1-25.
  • Imai, T., Boisset, C., Samejima, M., Igarashi, K., Sugiyama, J. (1998). Unidirectional processive action of cellobiohydrolase Cel7A on Valonia cellulose microcrystals. FEBS Letters. 432;113–116.
  • Johnson R. K., Zink-Sharp A., Renneckar S. H. and Glasser W.G. (2009). A new bio-based nanocomposite: fibrillated TEMPO-ozidized celluloses in hydroxypropylcellulose matrix. Cellulose. 16;227–238.
  • Jozala, A.F., de Lencastre-Novaes, L.C., Lopes, A.M., de Carvalho, S. E. V., Mazzola, P.G., Pessoa, A. Jr., Grotto, D., Gerenutti M., Chaud M. V. (2016). Appl. Microbiol Biotechnol. 100;2063-2072.
  • Keenan, J. R., Reams, G. A., Achard, F., Joberto, F. V., Grainger A., Lindquist E. (2015). Dynamics of global forest area: Results from the FAO global forest resources assessment 2015. Forest Ecology and Management. 352; 9-20.
  • Korhonen J. T., Kettunen M., Ras R. H. A., Ikkala O. (2011). Hydrophobic nanocelluose aerogels as floating, sustaniable, reusable and recyclable oil absorbents. Applied Materials and Interfaces. 3;1813-1816.
  • Kuo, C.H., Chen, J. H., Liou, B. K., Lee C. K. (2016). Utilization of acetate buffer to improve bacterial cellulose production by Gluconacetobacter xylinus. 53;98-103.
  • Lee K., Aitomaki Y., Berglund A. L., Oksman K., Bismarck A. (2014). On the use of nanocellulose as reinforcement in polymer matrix composites. Composites Science and Technology. 105;15-27.
  • Li, F., Mascheroni, E., and Piergiovanni, L. (2015) The potential of nanocellulose in the packaging field: a review. Packaging Technol. and Sci., 28;475–508.
  • Lima, M.M.D., Borsali, R. (2004). Rodlike cellulose microcrystals: Structure, Properties, and Applications, Macromolecular Rapid Communications. 25;771-87.
  • Meyabadi, T. F. and Dadashian, F. (2012). Optimization of enzymatichydrolysis ofwaste cotton fibersfor nanoparticles productionusing response surface methodology. Fibers and Polymers. 13;313–321.
  • Metreveli, G., Wagberg, L., Emmoth, E., Belak, S., Stromme, M., Mihranyan, A. (2014). A size-exclusion nanocellulose filter paper fro virus removal. Adv. Healthc. Mater. 3;1546-1550.
  • Moon, R. J. Martini, A. Nairn, J. Simonsen, J. Youngblood, J. (2010). Cellulose nanomaterials review: structure, properties and nanocomposites. Chem. Soc. Rev. 40;3941–3944.
  • Mualla, S. A., Farahat, R., Basmaji, P., de Olyveira, G. M., Costa, L. M. M., Oliveira, J. D. C., Francozo, G. B. (2016). Study on nanoskin ECM-bacterial cellulose wound healing. Journal of Biomaterials and Nanobiotechnology. 7; 9 pp.
  • Nasim, A., Kumar, A. P., James, M. D. (2014). Plant origin nanocellulose material, comprises nanocellulose particles or fibers derived from plant material having high hemicellulose content. Australian Government, Patent Publication number: AU2014353890.
  • Nimeskern, L., Martinez, A. H., Sudnberg, J., Gatenholm, P., Müller, R., Stok, K. S. (2013). Mechanical evaluation of bacterial nanocellulose as an implant material for ear cartilage replacement. J. Mech. Behav. Biomed. Mater. 22;12-21.
  • Rånby, B.G. (1949). Aqueous colloidal solutions of cellulose micelles. Acta Chemica Scandinavica. 3;649-50.
  • Rebouillat, S., and Pla, F. (2013). State of the Art Manufacturing and Engineering of Nanocellulose: A Review of Available Data and Industrial Applications. Journal of Biomaterials and Nanobiotechnology. 4;165-188.
  • Revol, J.F., Godbout, L., Dong, X.M., Gray, D.G., Chanzy, H. Maret, G. (1994). Chiral nematic suspensions of cellulose crystallites; phase separation and magnetic field orientation. Liquid Crystals, 16; 127-134.
  • Rodriguez, N. L. G., Thielemans W., Dufresne A. (2006). Sisal cellulose whiskers reinforced polyvinyl acetate nanocomposites. Cellulose. 3;261-270.
  • Saito T., Nishiyama Y., Putaux, J. L., Vignon M., Isogai A. (2006). Homogeneous suspensions of individualized microfibrils from TEMPO-catalyzed oxidation of native cellulose. Biomacromolecules. 7;1687-1691.
  • Stephanie, B. C., Roman, M., Gray, D. G. (2005). Effect of Reaction Conditions on the Properties and Behavior of Wood Cellulose Nanocrystal Suspensions. Biomacromolecules. 6;1048-1054.
  • Svagan, A.J., Samir, M.A.S.A., and Berglund, L.A. (2008), Biomimetic Foams of High Mecahanical Performance Based on Nanostructured Cell Walls Reinforced by Native Cellulose Nanofibrils. Advanced Materials, 20(7): 1263-1269. Turbak, A.F., Snyder, F.W., Sandberg, K.R. (1983). Microfibrillated cellulose, a new cellulose product: properties, uses and commercial potential. J. Appl. Polym. Sci. 37;815-27.
  • (URL-1). Gross domestic spending on R&D (Accessed: April 28, 2018). https://data.oecd.org/rd/gross-domestic-spending-on-r-d.htm.
  • (URL-2). Tunicate Nanocellulose: Preperation and Applications. (Accessed: April 28, 2018). http://bpums.ac.ir/UploadedFiles/gFiles/Tunicate__5a6f9e7f.pdf
  • (URL-3). Nanocellulose state of the industry (2015). (Accessed: April 28, 2018). http://www.tappinano.org/media/1114/cellulose-nanomaterials-production-state-of-the-industry-dec-2015.pdf
  • Wang, B., and Sain, M. (2007). Dispersion of Soybean StockBased Nanofiber in a Plastic Matrix. Polymer International. 56;538-546.
  • Wicklein, B., Kocjan, A., Salazar-Alvarez, G., Carosio, F., Camino, G., Antonietti M., Bergström, L. (2014). Thermally insulating and fire-retardant lightweight anisotropic foams based on nanocellulose and graphene oxide. Nature Nanotechnology. 10;277-283.
  • Yildirim, N. Shaler, S. M. Gardner, D. J. Rice, R. Bousfield D. W. (2014). Cellulose nanofibrils (CNFs) Reinforced Starch Insulating Foams. Cellulose. 21;4337-4347.
  • Yildirim, N. (2018). Developing fire-retardant and water-repellent bio-structural panels using nanocellulose. MRS Communications, 8;1-9.

Nanotechnology and the Futurist Green Polymer, Nanocellulose

Year 2018, Volume: 5 Issue: 2, 185 - 195, 01.12.2018
https://doi.org/10.17568/ogmoad.419758

Abstract

The nanotechnology that produced innovative changes in many industries has been getting attention in the forest products industry as well. Especially, the increase in multidisciplinary studies motivated researchers to work and study on new-generation nanocomposites and biocomposites that will be a strong alternative to traditional materials with the value-added properties. The cellulose, a crucial component of the trees, is made of small blocks. These blocks which are called nanocellulose contain fibrils and particles. Nanocelluloses are green polymers that have received considerable attention in materials science, engineering research, and research & product development fields in the industry. Nanocellulose is a bio-nano polymer that is widely used as reinforcing materials and added to polymer matrices to create innovative nanocomposites for use in many industries. Today, nanocellulose materials have been used in automotive, packaging, pharmaceutical, insulation and construction industries. The enhancements in the nanocellulose manufacturing processes, the increase in the number of global producers, and the increased demand for green and eco-friendly materials have made the nanocellulose more attractive for the industry and the institutions. 

In this study, a concise, critical state-of-the-art review on nanocellulose materials, manufacturing technologies, global producers and their current and future applications were studied and reported. 

References

  • Alemdar A., and Sain, M. (2008). Isolation and characterization of nanofibers from agricultural residues: wheat straw and soy hulls. Bioresour. Technol. 99;1664–1671.
  • Abitbol, T., Rivkin, A., Cao, Y., Nevo, Y., Abraham, E., Ben-Shalom, T., Lapidot, S., Shoseyov, O. (2016). Nanocellulose, a tiny fiber with huge applications. Current opinion in biotechnology. 39;76–88.
  • Bai, W., Holbery J., and Li, K. C. (2009). A technique for production of nanocrystalline cellulose with a narrow size distribution. Cellulose. 16;455-466.
  • Battista, O.A. (1950). Hydrolysis and crystallization of cellulose. J. Ind. Eng. Chem. 42;502–7.
  • Cai Z., Rudie A.W., Stark N.M., Sabo R.C. and Ralph S.A. (2013). Chapter 6: New products and product categories” In the global forest sector: Changes, practices and prospects. Edited by Hansen E., Panwar R. and Vlosky R. 129-149. Boca Raton, FL: CRC Press.
  • Campano C., Merayo N., Balea A., Tarres Q., Aguilar M. D., Mutje P., Negro C., Blanco A. (2018). Mechanical and chemical dispersion of nanocelluloses to improve their reinforcing effect on recycled paper. Cellulose. 25;269-280.
  • Chen, W. S., Yu, H., Liu, Yi., Hai, Y., Zhang, M., Chen, P. (2011). Isolation and characterization of cellulose nanofibers from four plant cellulose fibers using a chemical-ultrasonic process. Cellulose. 18;433–442.
  • Chen, Y. W., Lee, H. V., Juan, J. C., Phang S. M. (2016). Production of new cellulose material from red algae marine biomass Gelidium elegans. Carbohydr. Polym. 151;1210-1219.
  • Fleming, K., Gray, D.G., Matthews, S. (2001). Cellulose crystallites. Chemistry-A European Journal. 7;1831-1835.
  • Helbert W., Nishiyama Y., Okano T., and Sugiyama J. (1998). Molecular imaging of halocynthia papillosa cellulose. J. Struct. Biol. 124;42–50.
  • Herrick, F.W., Casebier, R.L., Hamilton, J.K., Sandberg, K.R. (1983). Microfibrillated Cellulose: Morphology and Accessibility. J. Appl. Polym. Sci. 37;797-813.
  • Hon, D. N. S. (1994). Cellulose: a random walk along its historical path. Cellulose . 1;1-25.
  • Imai, T., Boisset, C., Samejima, M., Igarashi, K., Sugiyama, J. (1998). Unidirectional processive action of cellobiohydrolase Cel7A on Valonia cellulose microcrystals. FEBS Letters. 432;113–116.
  • Johnson R. K., Zink-Sharp A., Renneckar S. H. and Glasser W.G. (2009). A new bio-based nanocomposite: fibrillated TEMPO-ozidized celluloses in hydroxypropylcellulose matrix. Cellulose. 16;227–238.
  • Jozala, A.F., de Lencastre-Novaes, L.C., Lopes, A.M., de Carvalho, S. E. V., Mazzola, P.G., Pessoa, A. Jr., Grotto, D., Gerenutti M., Chaud M. V. (2016). Appl. Microbiol Biotechnol. 100;2063-2072.
  • Keenan, J. R., Reams, G. A., Achard, F., Joberto, F. V., Grainger A., Lindquist E. (2015). Dynamics of global forest area: Results from the FAO global forest resources assessment 2015. Forest Ecology and Management. 352; 9-20.
  • Korhonen J. T., Kettunen M., Ras R. H. A., Ikkala O. (2011). Hydrophobic nanocelluose aerogels as floating, sustaniable, reusable and recyclable oil absorbents. Applied Materials and Interfaces. 3;1813-1816.
  • Kuo, C.H., Chen, J. H., Liou, B. K., Lee C. K. (2016). Utilization of acetate buffer to improve bacterial cellulose production by Gluconacetobacter xylinus. 53;98-103.
  • Lee K., Aitomaki Y., Berglund A. L., Oksman K., Bismarck A. (2014). On the use of nanocellulose as reinforcement in polymer matrix composites. Composites Science and Technology. 105;15-27.
  • Li, F., Mascheroni, E., and Piergiovanni, L. (2015) The potential of nanocellulose in the packaging field: a review. Packaging Technol. and Sci., 28;475–508.
  • Lima, M.M.D., Borsali, R. (2004). Rodlike cellulose microcrystals: Structure, Properties, and Applications, Macromolecular Rapid Communications. 25;771-87.
  • Meyabadi, T. F. and Dadashian, F. (2012). Optimization of enzymatichydrolysis ofwaste cotton fibersfor nanoparticles productionusing response surface methodology. Fibers and Polymers. 13;313–321.
  • Metreveli, G., Wagberg, L., Emmoth, E., Belak, S., Stromme, M., Mihranyan, A. (2014). A size-exclusion nanocellulose filter paper fro virus removal. Adv. Healthc. Mater. 3;1546-1550.
  • Moon, R. J. Martini, A. Nairn, J. Simonsen, J. Youngblood, J. (2010). Cellulose nanomaterials review: structure, properties and nanocomposites. Chem. Soc. Rev. 40;3941–3944.
  • Mualla, S. A., Farahat, R., Basmaji, P., de Olyveira, G. M., Costa, L. M. M., Oliveira, J. D. C., Francozo, G. B. (2016). Study on nanoskin ECM-bacterial cellulose wound healing. Journal of Biomaterials and Nanobiotechnology. 7; 9 pp.
  • Nasim, A., Kumar, A. P., James, M. D. (2014). Plant origin nanocellulose material, comprises nanocellulose particles or fibers derived from plant material having high hemicellulose content. Australian Government, Patent Publication number: AU2014353890.
  • Nimeskern, L., Martinez, A. H., Sudnberg, J., Gatenholm, P., Müller, R., Stok, K. S. (2013). Mechanical evaluation of bacterial nanocellulose as an implant material for ear cartilage replacement. J. Mech. Behav. Biomed. Mater. 22;12-21.
  • Rånby, B.G. (1949). Aqueous colloidal solutions of cellulose micelles. Acta Chemica Scandinavica. 3;649-50.
  • Rebouillat, S., and Pla, F. (2013). State of the Art Manufacturing and Engineering of Nanocellulose: A Review of Available Data and Industrial Applications. Journal of Biomaterials and Nanobiotechnology. 4;165-188.
  • Revol, J.F., Godbout, L., Dong, X.M., Gray, D.G., Chanzy, H. Maret, G. (1994). Chiral nematic suspensions of cellulose crystallites; phase separation and magnetic field orientation. Liquid Crystals, 16; 127-134.
  • Rodriguez, N. L. G., Thielemans W., Dufresne A. (2006). Sisal cellulose whiskers reinforced polyvinyl acetate nanocomposites. Cellulose. 3;261-270.
  • Saito T., Nishiyama Y., Putaux, J. L., Vignon M., Isogai A. (2006). Homogeneous suspensions of individualized microfibrils from TEMPO-catalyzed oxidation of native cellulose. Biomacromolecules. 7;1687-1691.
  • Stephanie, B. C., Roman, M., Gray, D. G. (2005). Effect of Reaction Conditions on the Properties and Behavior of Wood Cellulose Nanocrystal Suspensions. Biomacromolecules. 6;1048-1054.
  • Svagan, A.J., Samir, M.A.S.A., and Berglund, L.A. (2008), Biomimetic Foams of High Mecahanical Performance Based on Nanostructured Cell Walls Reinforced by Native Cellulose Nanofibrils. Advanced Materials, 20(7): 1263-1269. Turbak, A.F., Snyder, F.W., Sandberg, K.R. (1983). Microfibrillated cellulose, a new cellulose product: properties, uses and commercial potential. J. Appl. Polym. Sci. 37;815-27.
  • (URL-1). Gross domestic spending on R&D (Accessed: April 28, 2018). https://data.oecd.org/rd/gross-domestic-spending-on-r-d.htm.
  • (URL-2). Tunicate Nanocellulose: Preperation and Applications. (Accessed: April 28, 2018). http://bpums.ac.ir/UploadedFiles/gFiles/Tunicate__5a6f9e7f.pdf
  • (URL-3). Nanocellulose state of the industry (2015). (Accessed: April 28, 2018). http://www.tappinano.org/media/1114/cellulose-nanomaterials-production-state-of-the-industry-dec-2015.pdf
  • Wang, B., and Sain, M. (2007). Dispersion of Soybean StockBased Nanofiber in a Plastic Matrix. Polymer International. 56;538-546.
  • Wicklein, B., Kocjan, A., Salazar-Alvarez, G., Carosio, F., Camino, G., Antonietti M., Bergström, L. (2014). Thermally insulating and fire-retardant lightweight anisotropic foams based on nanocellulose and graphene oxide. Nature Nanotechnology. 10;277-283.
  • Yildirim, N. Shaler, S. M. Gardner, D. J. Rice, R. Bousfield D. W. (2014). Cellulose nanofibrils (CNFs) Reinforced Starch Insulating Foams. Cellulose. 21;4337-4347.
  • Yildirim, N. (2018). Developing fire-retardant and water-repellent bio-structural panels using nanocellulose. MRS Communications, 8;1-9.
There are 41 citations in total.

Details

Primary Language Turkish
Journal Section Forest Products
Authors

Nadir Yıldırım 0000-0003-2751-9593

Publication Date December 1, 2018
Submission Date April 30, 2018
Published in Issue Year 2018 Volume: 5 Issue: 2

Cite

APA Yıldırım, N. (2018). Nanoteknoloji ve Geleceğin Çevreci Polimeri Nanoselüloz. Ormancılık Araştırma Dergisi, 5(2), 185-195. https://doi.org/10.17568/ogmoad.419758
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Turkish Journal of Forestry Research is licensed under a Creative Commons Attribution-NoDerivatives 4.0 International License.