Kloro[1-Allil-3-(2-diizopropilaminoetil)benzimidazol-2-iliden]gümüş(I)’in sentezi ve yapısal karakterizasyonu

Year 2020, Volume: 10 Issue: 2, 66 - 75, 31.12.2020

Ebru Şahin-yıldırım Neslihan Şahin

Abstract

N-heterosiklik karben-metal kompleksleri, biyolojik özelliklere sahip olmaları ve organik sentez tepkimelerinde katalizör olarak kullanılmaları nedeni ile koordinasyon kimyasının en önemli çalışma konularından biridir. Bu çalışmada potansiyel katalizör ve biyolojik ajan olabilecek bir yeni benzimidazolyum tuzu ve bu tuzun Ag(I)-NHC kompleksi sentezlendi. Elde edilen her iki yeni bileşiğin yapısı FT-IR, 1H NMR ve 13C{1H} NMR spektroskopileri ile tam olarak karakterize edildi.

Keywords

N-heterosiklik karben, benzimidazolyum, gümüş, NMR, FT-IR

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