Ftalosiyanin esaslı boyarmaddelerin kimyasal yapıları ve fonksiyonel tekstillerin üretilmesinde kullanımı

Year 2017, Volume: 23 Issue: 7, 809 - 817, 27.12.2017

Pınar Saral Özdemir , Arif Taner Özgüney

Abstract

Ftalosiyaninler
keskin mavi-yeşil renkli, oldukça sağlam, iki boyutlu 18 π-elektron konjuge
sistemine sahip aromatik makrosiklik bileşiklerdir. Makrohalka yapının merkezi
koordinasyon boşluğuna periodik tablonun birçok elementinin; aromatik yapının
periferal ve non-periferal konumlarına ise çeşitli fonksiyonel sübstitüentlerin
bağlanmasıyla ftalosiyaninlere katalitik, elektrokromik, elektriksel iletkenlik,
fotovoltaik, fotoiletkenlik, ışık absorbsiyonu, foto uyarıcı gibi çeşitli
özellikler kazandırmak mümkündür. Geleneksel bakır ftalosiyanin pigmenti
dışında farklı ftalosiyanin türevlerinin de tekstil materyallerinin
renklendirilmesinde kullanılmasıyla; farklı fonksiyonel özellikli (güç tutuşur,
antibakteriyel…vs) teknik tekstillerin elde edilebileceği düşünülmektedir. Bu
sebeple bu araştırmada ftalosiyaninler hakkında genel bilgi verilip, tekstil
materyallerinin renklendirilmesi ve antibakteriyel özellik kazandırılması üzerine
yapılmış bazı çalışmalar anlatılmıştır.

Keywords

Ftalosiyanin, Tekstil, Pigment, Boya

Chemical structures of phthalocyanine based dyestuffs and their useage in production of functional textiles

Abstract

Phthalocyanines
are intensely blue-green-coloured, quite stable aromatic macrocyclic compounds
having a two-dimensional 18-π electron conjugated system. Phthalocyanines are
acquired various properties such as catalytic, electrochromic, electrical
conductivity, photovoltaic, photo-conductivity, photo-absorbtion,
photosensitizer by bonding most elements of the periodic table to central
coordination cavity of macrocylic structure and by linking various functional
substituents to peripheral or non-peripheral position of aromatic structure. It
is thought that technical textiles having different functional properties,
e.g.; antibacterial, fire retardant, can be obtained by also using various
phthalocyanine derivatives except traditional copper phthalocyanine pigment in
colouration of textile materials. For this reason, in this research general
knowledge about phthalocyanines were given then some studies about their usage
in textile material colouration and being achieved antibacterial
properties   were told.

Keywords

Phthalocyanine, Textile, Pigment, Dye

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