Methylene Blue Removal of Fixed-Bed Column Reactor with Pumice and nZVI-Pumice: Experimental and Modeling Study

Year 2019, Volume: 23 Issue: 2, 574 - 581, 25.08.2019

Mesut Genişoğlu , Ayşegül Yağmur Gören , Esin Balcı Yaşar Kemal Recepoğlu , Hatice Eser Ökten

https://doi.org/10.19113/sdufenbed.538084

Cited By: 2

Abstract

Nano
zero-valent iron (nZVI) emerges as a low cost and eco-friendly adsorbent to
treat textile wastewater, which is rich in dye content. However nZVI particles
can easily agglomerate in aqueous environment due to electrostatic interaction,
decreasing their treatment efficiency. Therefore pumice, a low-cost and naturally
found porous material with lower specific surface area (2m²/gr), can
be used as support material to reduce agglomeration of nZVI. Treatment
efficiencies of pumice/nZVI packing (10:0 and 9:1 (w/w)) in column reactor for specified
initial methylene blue concentrations (25, 50, 75 and 100 mg/L) were
investigated in this study. Adsorption capacities of the adsorbents were calculated
as 2.8 and 4.2 mg/g-adsorbent, respectively at 100 mg/L initial methylene blue
concentration. Mixed bed column performed significantly better than its pumice-only
counterpart for low initial concentrations. Thomas adsorption model was applied
to  experimental results with a moderate to
high predictive power.

Keywords

Fixed bed column, Methylene blue, nZVI, Pumice, Thomas model

Pomza ve nSDD-Pomza ile Sabit Yataklı Kolon Reaktörde Metilen Mavisi Giderimi: Deneysel ve Modelleme Çalışması

Abstract

Nano
sıfır değerlikli demir (nSDD) yüksek renk konsantrasyonlarına sahip tekstil
atıksularının arıtımında ekonomik ve çevre dostu bir adsorban olarak ortaya
çıkmaktadır. Ancak nSDD partikülleri sulu çözeltilerde elektrostatik
etkileşimler sebebiyle kolayca topaklaşmakta ve bu da arıtma veriminin
düşmesine neden olmaktadır. Dolayısıyla düşük maliyetli, doğal poröz yapıda ve
ortalama 2m²/gr spesifik yüzey alanına sahip pomza, nSDD
topaklaşmasını önleyici bir malzeme olarak kullanılabilir. Bu çalışmada sadece
pomza ve pomza-nSDD (ağırlıkça 9:1) karışımının kullanıldığı kolon reaktörde
25, 50, 75 ve 100 mg/L metilen mavisi konsantrasyonları için arıtma verimleri
incelenmiştir. Pomzanın ve pomza-nSDD karışımının 100 mg/L metilen mavisi
deneyindeki toplam kapasiteleri sırasıyla 2,8 ve 4,2 mg/g-adsorban olarak bulunmuştur.
Özellikle düşük konsantrasyonlarda, pomza-nSDD karışımının arıtma performansını
önemli ölçüde arttırdığı görülmüştür. Thomas modeli deneysel verilere
uygulanmış ve modelin öngörü gücünün düşük konsantrasyonda yüksekken, yüksek
konsantrasyonlarda ortalama olduğu kanısına varılmıştır.

Keywords

Thomas modeli, Sabit yataklı kolon, Metilen mavisi, nZVI, Pomza, Thomas modeli

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