The Effect of Synthesis Conditions on Calcium Silicate Bioceramic Materials

Year 2019, Volume: 23 Issue: 3, 727 - 737, 25.12.2019

Yasin Arslan , Erdal Kenduzler , Vahide Tuğçe Adıgüzel Fatma Tomul

https://doi.org/10.19113/sdufenbed.527602

Cited By: 4

Abstract

In
this study, calcium silicate bioceramic materials of various Ca/Si ratios were
prepared using tetraethyl orthosilicate and calcium nitrate by a hydrothermal
synthesis method, taking into consideration cost-effective and environmentally
friendly, ‘green’, synthesis rules. For comparison purposes, sol-gel synthesis
method was also used. Calcium silicate bioceramic materials produced by both
methods were calcined at 600°C and 950°C. Fourier Transform Infrared
Spectroscopy, Thermogravimetric Thermal Analysis, Field Emission Scanning
Electron Microscopy and X-ray Diffraction methods were used to characterize calcium
silicate bioceramic materials. The characterization results validated the
formation of calcium silicate materials.

Keywords

Calcium silicate bioceramic, Materials, Hydrothermal synthesis, Calcination, X-ray diffraction

Sentez Koşullarının Kalsiyum Silikat Biyoseramik Malzemelere Etkisi

Abstract

Bu
çalışmada, çeşitli Ca/Si oranlarındaki kalsiyum silikat biyoseramik
malzemeleri, düşük maliyetli ve çevre dostu "yeşil" sentez kuralları
göz önünde bulundurularak, bir hidrotermal sentez yöntemi ile hazırlanmıştır.
Karşılaştırma amacıyla sol-gel sentez metodu da kullanılmıştır. Başlangıç
materyali olarak tetraetil ortosilikat ve kalsiyum nitrat kullanılmıştır. Her
iki yöntemle üretilen kalsiyum silikat biyoseramik malzemeleri 600 °C ve 950
°C'de kalsine edilmiştir. Fourier Dönüşümü Kızılötesi Spektroskopisi,
Termogravimetrik Termal Analiz, Alan Emisyon Taramalı Elektron Mikroskobu ve X-Işını
Kırınımı metodları kalsiyum silikat biyoseramik malzemeleri karakterize etmek
için kullanılmıştır. Karakterizasyon sonuçları kalsiyum silikat malzemelerinin
oluşumunu doğrulamıştır.

Keywords

Kalsiyum silikat biyoseramik, Malzemeler, Hidrotermal sentez, Kalsinasyon, X ışını kırınımı

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