OPTIMIZATION OF SYNTHESIS PARAMETERS FOR LEAD OXIDE NANOPARTICLES USING RESPONSE SURFACE METHODOLOGY

Year 2019, Volume: 7 Issue: 2, 298 - 308, 01.06.2019

İsmail Kutlugün Akbay , Ahmet Güngör , Rükan Genç , Tonguç Özdemir

https://doi.org/10.15317/Scitech.2019.200

Abstract

Nano-sized lead oxide has useful applications
that can be used in industry. In this study, the synthesis parameters were
optimized using response surface methodology and ANOVA study was also carried
out. Reaction temperature, sodium hydroxide and lead (II) acetate concentration
were studied as the factors and the particle size was selected as the response
variable. The modification was lead to increase the adequate precision of the
model. Close results between R² (correlation coefficient) and R²_adj
showed the accuracy of the model. The optimum results of the study were found
14.89 M NaOH concentration, 0.87 M Pb(II)Ac and reaction temperature of 88.56
°C. The particle size of lead II oxide was found to be 19.75 nm under optimum parameters.

Keywords

Central Composite Design, Lead Oxide, Nanoparticle, Optimization, RSM

Yüzey Cevap Metodolojisi Kullanilarak Kurşun Oksit Nanoparçaciklarinin Sentez Parametrelerinin Optimizasyonu

Abstract

Nano boyutlu kurşun oksit, endüstride kullanılabilecek
faydalı uygulamalara sahiptir. Bu çalışmada, sentez parametreleri cevap yüzey
metodolojisi kullanılarak optimize edilmiş ve ANOVA çalışması da yapılmıştır. Sentez
parametreleri olarak reaksiyon sıcaklığı, sodyum hidroksit ve kurşun (II) asetat
konsantrasyonu incelenmiştir ve parçacık boyutu cevap değişkeni olarak
seçilmiştir. Optimizasyon sonucunda modelin hassasiyeti artmıştır. R²
(korelasyon katsayısı) ile R²_adj arasındaki yakın sonuç,
modelin doğruluğunu göstermiştir.  Çalışmanın sonucunda, 14.89 M NaOH konsantrasyonu,
0.87 M Pb (II)Ac konsantrasyonu ve 88.56 ° C reaksiyon sıcaklığı optimum sentez
koşulları olarak belirlenmiştir. Kurşun (II) oksidin parçacık büyüklüğü,
optimum parametreler altında 19.75 nm olarak bulunmuştur. 

Keywords

RSM, Merkezi Kompozit Dizayn, Kurşun Oksit, Nanoparçacık, Optimizasyon, RSM

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