Production and Characterization of N-Halamine Based Polyvinyl Chloride (PVC) Nanowebs

Year 2021, Volume: 31 Issue: 3, 147 - 155, 30.09.2021

Batuhan Çobanoğlu Fatma Nur Parın , Kenan Yıldırım

https://doi.org/10.32710/tekstilvekonfeksiyon.717601

Cited By: 2

Abstract

Antibakteriyel ajan N-halamin, 7,7,9,9-tetrametil-1,3,8-triazaspiro [4.5]-Dekan-2,4-Dion (TTDD) sentezlenmiştir ve Polivinil klorür (PVC) nanoweb üretiminde kullanılmıştır. Sürekli ve düzenli yapıdaki nanowebleri üretmek için nispetern kolay ve elverişli bir yöntem olan elektroçekim kullanılmıştır. Toksik ve tahriş edici olmayan, yenilenebilir ve yüksek stabiliteye sahip PVC'ye N-halaminlerin eklenmesi tercih edilmiştir. Üretilen web yapılara klorlama işlemi, seyreltik hipoklorit çözeltisi kullanılarak uygulanmıştır. Nanoweblerin antibakteriyal aktiviteleri farklı hipoklorit konsantrasyonuna ve zamana göre aynı pH değerinde değerlendirilmiştir. Weblerdeki Morfolojik ve ısıl değişimler FTIR, TGA ve SEM ile karakterize edilmiştir. Taramalı elektron mikroskobu (SEM), weblerin ortalama çapının N-halamin konsantrasyonu ile azaldığını göstermiştir. Klorlanmış yapıdaki tüm nanowebler hem Staphylococcus aureus hem de Escherichia coli'ye karşı üstün inaktivasyon ile oldukça etkili antibakteriyel aktiviteler göstermiştir. Nanoweblerin antibakteriyel etkinliğinin yeniden klorlama işlemi ile geliştiği gözlenmiştir.

Keywords

Antibacterial property, N-halamine, nanoweb, polyvinylchloride (PVC), electrospinning

Thanks

The authors acknowledge Dr. Mehmet Orhan for his help with the antibacterial testing.

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