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Impedance Spectroscopy and Dielectric Relaxation in Phthalocyanine Thin Film

Year 2017, Volume: 22 Issue: 3, 145 - 152, 28.12.2017

Nursel Can , Ahmet Altındal

https://doi.org/10.17482/uumfd.372447
Cited By: 1

Abstract

Dielectric
relaxation behavior of spin coated thin film of novel ball-type binuclear
zinc(II) phthalocyanine were studied using impedance spectroscopy technique
over a frequency range of 5–13x106 Hz and temperatures (298 – 468
K).
Simulation of the obtained impedance data indicated that the dielectric
behaviour of the system can
be modeled by a parallel RC electrical equivalent circuit. A frequency
dependence in the form of ωm,
where the index m is
found strongly temperature dependent,
was observed for the ac conductivity σac. Ac conductivity
data were analyzed in terms two different models. The observed temperature
dependence of the m indicate that the ac charge transport in Pc film take place
via hopping process.



 

Keywords

Phthalocyanine Impedance Relaxation Ac conductivity CBH model

References

  • Altındal, A. Abdurrahmanoğlu, Ş. Bulut, M. Bekaroğlu, Ö. (2005) Charge transport mechanism in bis(double-decker lutetium(III) phthalocyanine) (Lu2Pc4) thin film. Synthetic Metals, 150, 181–187. doi: 10.1016/j.synthmet.2005.02.006
  • Altındal, A. Kurt, Ö. Şengül, A. Bekaroğlu, Ö. (2014) Kinetics of CO2 adsorption on ball-type dicopper phthalocyaninethin film. Sensors and Actuators B, 202, 373–381. doi: 10.1016/j.snb.2014.05.107
  • Anthopoulos, T.D. Shafai, T.S. (2003) Electrical properties of a-nickel phthalocyanine/aluminium interfaces: effects of oxygen doping and thermal annealing. Journal of Physics and Chemistry of Solids, 64, 1217–1223. doi: 10.1016/S0022-3697(03)00062-3
  • Bao, Z. Lovinger, A.J. Dodabalapur, A. (1996) Organic field‐effect transistors with high mobility based on copper phthalocyanine. Appl. Phys. Lett., 69(20), 3066-3068. doi: 10.1063/1.116841
  • Ceyhan, T. Altındal, A. Erbil, M.K. Bekaroğlu, Ö. (2006) Synthesis, characterization, conduction and gas sensing properties of novel multinuclear metallo phthalocyanines (Zn, Co) with alkylthio substituents. Polyhedron, 25, 737–746. doi: 10.1016/j.poly.2005.07.046
  • Ceyhan, T. Altındal, A. Özkaya, A.R. Çelikbıcak, Ö. Salih, B. Kemal Erbil, M. Bekaroğlu, Ö.( 2007) Synthesis, characterization and electrochemical properties of novel metal free and zinc(II) phthalocyanines of ball and clamshell types. Polyhedron, 26, 4239–4249. doi: 10.1016/j.poly.2007.05.028
  • Eliot, S.R. (1977) A theory of a.c. conduction in chalcogenide glasses. Philos. Mag., 36 (6), 1291-1304. doi: 10.1080/14786437708238517
  • Garcia-Belmonte, G. Boix, P.P. Bisquert, J. Sessolo, M. Bolink, H.J. (2010) Simultaneous determination of carrier lifetime and electron density- of-states in P3HT:PCBM organic solar cells under illumination by impedance spectroscopy. Solar Energy Materials & Solar Cells, 94, 366–375. doi: 10.1016/j.solmat.2009.10.015
  • Jonscher, A.K. (1983) Dielectric Relaxation in Solids. Chelsea Dielectric Press, London
  • Khrishnakumar, K.P. Menon, C.S. (2001) Determination of the thermal activation energy and grain size of iron phthalocyanine thin films. Materials Letters, 48(2001), 64–73. doi: 10.1016/S0167-577X(00)00281-0
  • Kimura, M. Horai, T. Hanabusa, K. Shirai, H. (1997) Electrochromic polymer derived from oxidized tetrakis(2-hydroxyphenoxy)phthalocyaninatocobalt(II) complex. Chem. Lett., 7, 653-654. doi: 10.1246/cl.1997.653
  • Kumar, A. Murari, N.M. Katiyar, R.S. (2009) Investigation of dielectric and electrical behavior in Pb(Fe0.66 W0.33)0.50Ti0.50O3 thin films by impedance spectroscopy.J. Alloys. Compd., 469, 433–440. doi: 10.1016/j.jallcom.2008.01.130
  • Leon, C. Lucıa, M.L. Santamarıa, J. (1997) Correlated ion hopping in single-crystal yttria-stabilized zirconia. Phys. Rev. B., 55, 882-887. doi: 10.1103/PhysRevB.55.882
  • MacDonald,J.R. (1987) Impedance Spectroscopy: Emphasizing Solid Materials and Systems, Wiley-Interscience, New York
  • Manaka, T. Iwamoto, M. (2003) Electrical properties of unsubstitutedyfluorine-substituted phthalocyanine interface investigated by Kelvin probe method. Thin Solid Films, 438–439, 157–161. doi: 10.1016/S0040-6090(03)00726-0
  • Pandey, R. Zou, Y. Holmes, R.J. (2012) Efficient, bulk heterojunction organic photovoltaic cells based on boron subphthalocyanine chloride-C70. Applied Physics Letters, 101, 033308-1-033308-4. doi: 10.1063/1.4737902
  • Piasecki, T. Nitsch, K. (2010) Study of sprayed coatings and compound materials by impedance spectroscopy. Surface & Coatings Technology, 205, 1009-1014. doi: 10.1016/j.surfcoat.2010.07.074
  • Shafai, T.S. Anthopoulos, T.D. (2001) Junction properties of nickel phthalocyanine thin film devices utilising indium injecting electrodes. Thin Solid Films, 398–399, 361–367. doi: 10.1016/S0040-6090(01)01345-1
  • Shan Do, J. Jen Chen, P. (2007) Amperometric sensor array for NOx, CO, O2 and SO2 detection. Sensors and Actuators B., 122, 165–173. doi: 10.1016/j.snb.2006.05.030
  • Vidadi, Y.A. Rozenshtein, L.D. Chistyakov, E.A. (1969) Hopping and band conductivities in organic semiconductors. Sov. Phys. Solid State, 11, 173-175.
  • Waclawek, W. Kulesza, M. Zabkowska, M. (1981) Mater. Sci. (Poland), 7, No:2-3, 385.

FTALOSIYANIN İNCE FILMDE EMPEDANS SPEKTROSKOPI VE DIELEKTRIK DURULMA

Year 2017, Volume: 22 Issue: 3, 145 - 152, 28.12.2017

Nursel Can , Ahmet Altındal

https://doi.org/10.17482/uumfd.372447
Cited By: 1

Abstract

Döndürerek
kaplama yöntemiyle hazırlanan top tipi çinko (II) ftalosiyanin ince filmlerin
dielektrik durulma davranışları 5 Hz. ile 13x106
Hz frekans aralığında sıcaklığa bağlı olarak (298 K – 468 K sıcaklık
aralığında) empedans spektroskopi yöntemiyle incelenmiştir. Elde edilen
verilerin modellenmesinde sistemin dielektrik davranışının paralel RC eşdeğer
devre ile temsil edilebileceği görülmüştür. Filmlerde ac iletkenliğin frekansa
bağlılığının ωm
şeklinde olduğu ve frekansın üssü olan m parametresinin kuvvetle sıcaklığa
bağlı olduğu gözlemlenmiştir. Deneysel olarak elde edilen ac iletkenlik
verileri iki farklı model kullanılarak analiz edilmiştir. Frekansın üssü olan m
parametresinin sıcaklığa bağlılığının incelenmesinde çinko (II) ftalosiyanin
ince filmlerde ac yük iletiminin hoplama mekanizması sayesinde gerçekleştiği
sonucuna varılmıştır.

Keywords

Ftalosiyanin Empedans Durulma Ac iletkenlik CBH model

References

  • Altındal, A. Abdurrahmanoğlu, Ş. Bulut, M. Bekaroğlu, Ö. (2005) Charge transport mechanism in bis(double-decker lutetium(III) phthalocyanine) (Lu2Pc4) thin film. Synthetic Metals, 150, 181–187. doi: 10.1016/j.synthmet.2005.02.006
  • Altındal, A. Kurt, Ö. Şengül, A. Bekaroğlu, Ö. (2014) Kinetics of CO2 adsorption on ball-type dicopper phthalocyaninethin film. Sensors and Actuators B, 202, 373–381. doi: 10.1016/j.snb.2014.05.107
  • Anthopoulos, T.D. Shafai, T.S. (2003) Electrical properties of a-nickel phthalocyanine/aluminium interfaces: effects of oxygen doping and thermal annealing. Journal of Physics and Chemistry of Solids, 64, 1217–1223. doi: 10.1016/S0022-3697(03)00062-3
  • Bao, Z. Lovinger, A.J. Dodabalapur, A. (1996) Organic field‐effect transistors with high mobility based on copper phthalocyanine. Appl. Phys. Lett., 69(20), 3066-3068. doi: 10.1063/1.116841
  • Ceyhan, T. Altındal, A. Erbil, M.K. Bekaroğlu, Ö. (2006) Synthesis, characterization, conduction and gas sensing properties of novel multinuclear metallo phthalocyanines (Zn, Co) with alkylthio substituents. Polyhedron, 25, 737–746. doi: 10.1016/j.poly.2005.07.046
  • Ceyhan, T. Altındal, A. Özkaya, A.R. Çelikbıcak, Ö. Salih, B. Kemal Erbil, M. Bekaroğlu, Ö.( 2007) Synthesis, characterization and electrochemical properties of novel metal free and zinc(II) phthalocyanines of ball and clamshell types. Polyhedron, 26, 4239–4249. doi: 10.1016/j.poly.2007.05.028
  • Eliot, S.R. (1977) A theory of a.c. conduction in chalcogenide glasses. Philos. Mag., 36 (6), 1291-1304. doi: 10.1080/14786437708238517
  • Garcia-Belmonte, G. Boix, P.P. Bisquert, J. Sessolo, M. Bolink, H.J. (2010) Simultaneous determination of carrier lifetime and electron density- of-states in P3HT:PCBM organic solar cells under illumination by impedance spectroscopy. Solar Energy Materials & Solar Cells, 94, 366–375. doi: 10.1016/j.solmat.2009.10.015
  • Jonscher, A.K. (1983) Dielectric Relaxation in Solids. Chelsea Dielectric Press, London
  • Khrishnakumar, K.P. Menon, C.S. (2001) Determination of the thermal activation energy and grain size of iron phthalocyanine thin films. Materials Letters, 48(2001), 64–73. doi: 10.1016/S0167-577X(00)00281-0
  • Kimura, M. Horai, T. Hanabusa, K. Shirai, H. (1997) Electrochromic polymer derived from oxidized tetrakis(2-hydroxyphenoxy)phthalocyaninatocobalt(II) complex. Chem. Lett., 7, 653-654. doi: 10.1246/cl.1997.653
  • Kumar, A. Murari, N.M. Katiyar, R.S. (2009) Investigation of dielectric and electrical behavior in Pb(Fe0.66 W0.33)0.50Ti0.50O3 thin films by impedance spectroscopy.J. Alloys. Compd., 469, 433–440. doi: 10.1016/j.jallcom.2008.01.130
  • Leon, C. Lucıa, M.L. Santamarıa, J. (1997) Correlated ion hopping in single-crystal yttria-stabilized zirconia. Phys. Rev. B., 55, 882-887. doi: 10.1103/PhysRevB.55.882
  • MacDonald,J.R. (1987) Impedance Spectroscopy: Emphasizing Solid Materials and Systems, Wiley-Interscience, New York
  • Manaka, T. Iwamoto, M. (2003) Electrical properties of unsubstitutedyfluorine-substituted phthalocyanine interface investigated by Kelvin probe method. Thin Solid Films, 438–439, 157–161. doi: 10.1016/S0040-6090(03)00726-0
  • Pandey, R. Zou, Y. Holmes, R.J. (2012) Efficient, bulk heterojunction organic photovoltaic cells based on boron subphthalocyanine chloride-C70. Applied Physics Letters, 101, 033308-1-033308-4. doi: 10.1063/1.4737902
  • Piasecki, T. Nitsch, K. (2010) Study of sprayed coatings and compound materials by impedance spectroscopy. Surface & Coatings Technology, 205, 1009-1014. doi: 10.1016/j.surfcoat.2010.07.074
  • Shafai, T.S. Anthopoulos, T.D. (2001) Junction properties of nickel phthalocyanine thin film devices utilising indium injecting electrodes. Thin Solid Films, 398–399, 361–367. doi: 10.1016/S0040-6090(01)01345-1
  • Shan Do, J. Jen Chen, P. (2007) Amperometric sensor array for NOx, CO, O2 and SO2 detection. Sensors and Actuators B., 122, 165–173. doi: 10.1016/j.snb.2006.05.030
  • Vidadi, Y.A. Rozenshtein, L.D. Chistyakov, E.A. (1969) Hopping and band conductivities in organic semiconductors. Sov. Phys. Solid State, 11, 173-175.
  • Waclawek, W. Kulesza, M. Zabkowska, M. (1981) Mater. Sci. (Poland), 7, No:2-3, 385.
There are 21 citations in total.

Details

Subjects Engineering
Journal Section Research Articles
Authors

Nursel Can

Ahmet Altındal

Publication Date December 28, 2017
Submission Date October 11, 2016
Acceptance Date October 16, 2017
Published in Issue Year 2017 Volume: 22 Issue: 3

Cite

APA Can, N., & Altındal, A. (2017). FTALOSIYANIN İNCE FILMDE EMPEDANS SPEKTROSKOPI VE DIELEKTRIK DURULMA. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi, 22(3), 145-152. https://doi.org/10.17482/uumfd.372447
AMA Can N, Altındal A. FTALOSIYANIN İNCE FILMDE EMPEDANS SPEKTROSKOPI VE DIELEKTRIK DURULMA. UUJFE. December 2017;22(3):145-152. doi:10.17482/uumfd.372447
Chicago Can, Nursel, and Ahmet Altındal. “FTALOSIYANIN İNCE FILMDE EMPEDANS SPEKTROSKOPI VE DIELEKTRIK DURULMA”. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi 22, no. 3 (December 2017): 145-52. https://doi.org/10.17482/uumfd.372447.
EndNote Can N, Altındal A (December 1, 2017) FTALOSIYANIN İNCE FILMDE EMPEDANS SPEKTROSKOPI VE DIELEKTRIK DURULMA. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi 22 3 145–152.
IEEE N. Can and A. Altındal, “FTALOSIYANIN İNCE FILMDE EMPEDANS SPEKTROSKOPI VE DIELEKTRIK DURULMA”, UUJFE, vol. 22, no. 3, pp. 145–152, 2017, doi: 10.17482/uumfd.372447.
ISNAD Can, Nursel - Altındal, Ahmet. “FTALOSIYANIN İNCE FILMDE EMPEDANS SPEKTROSKOPI VE DIELEKTRIK DURULMA”. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi 22/3 (December 2017), 145-152. https://doi.org/10.17482/uumfd.372447.
JAMA Can N, Altındal A. FTALOSIYANIN İNCE FILMDE EMPEDANS SPEKTROSKOPI VE DIELEKTRIK DURULMA. UUJFE. 2017;22:145–152.
MLA Can, Nursel and Ahmet Altındal. “FTALOSIYANIN İNCE FILMDE EMPEDANS SPEKTROSKOPI VE DIELEKTRIK DURULMA”. Uludağ Üniversitesi Mühendislik Fakültesi Dergisi, vol. 22, no. 3, 2017, pp. 145-52, doi:10.17482/uumfd.372447.
Vancouver Can N, Altındal A. FTALOSIYANIN İNCE FILMDE EMPEDANS SPEKTROSKOPI VE DIELEKTRIK DURULMA. UUJFE. 2017;22(3):145-52.

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