Evaluation of Green Chickpea Shell Waste in Pb (II) Biosorption from Aqueous Solution

Year 2021, Volume: 26 Issue: 3, 143 - 154, 31.12.2021

Kübra Korkmaz , Hasan Sayğılı

https://doi.org/10.53433/yyufbed.960478

Abstract

In this study, removal of lead Pb(II) ion known as a toxic heavy metal from the aqueous media using green chickpea shell (YNK) as a new alternative has been investigated. Biosorption studies were carried out according to the batch method. The necessary conditions for optimum Pb(II) removal have been determined and temperature dependent kinetic and isotherm studies have been carried out. The kinetic data obtained as a result of the studies have been evaluated in pseudo-first, pseudo-second and intra-particle diffusion models to determine kinetic model. Isotherm data have been evaluated in Langmuir and Freundlich isotherm models. Optimum conditions have been determined for Pb(II) ion biosorption with YNK as 0.1 g biosorbent dose and at 40 oC temperature . In the study, the maximum biosorption capacity has been found to be 30.8 mg/g for Pb(II) ion. In addition, the isotherm data have been found to be favorable to Langmuir isotherm model (R2 = 0.99) and the most appropriate kinetic model has been determined to be the pseudo first order reaction model (R2 =0.99). The study showed that YNK waste, has a certain biosorption capacity and this waste can be used as a low-cost and environmentally friendly alternative

Keywords

Green chickpea shell, Biosorption, Lead, İsotherm, Kinetics

Yeşil Nohut Kabuğu Atıklarının Sulu Çözeltiden Pb+2 Biyosorpsiyonunda Değerlendirilmesi

Abstract

Bu çalışmada, toksik bir ağır metal olarak bilinen kurşun Pb(II) iyonunun, yeni bir alternatif olarak yeşil nohut kabuğu (YNK) kullanılarak sucul ortamdan giderimi araştırılmıştır. Biyosorpsiyon çalışmaları kesikli yönteme göre yürütülmüştür. Optimum Pb(II) giderimi için gerekli koşullar belirlenerek sıcaklığa bağlı kinetik ve izoterm çalışmaları yapılmıştır. Çalışmalar sonucunda elde edilen kinetik veriler, yalancı birinci, yalancı ikinci ve parçacık içi difüzyon modellerinde değerlendirilerek kinetik model tespiti yapılmıştır. İzoterm verileri ise Langmuir ve Freundlich izoterm modellerinde değerlendirilmiştir. Pb(II) iyonunun YNK ile biyosorpsiyonunda, optimum koşullar biyosorbent dozu 0,1 g ve sıcaklık 40 oC olarak saptanmıştır. Çalışmada, maksimum biyosorpsiyon kapasitesi Pb(II) iyonu için 30,8 mg/g olarak bulunmuştur. Ayrıca izoterm verilerinin Langmuir izoterm modeline uygun olduğu (R2 =0,99) bulunmuş olup, yalancı birinci derece reaksiyon modelinin ise kinetik açıdan en uygun model olduğu (R2 =0,99) tespit edilmiştir. Çalışma, YNK atığının belli bir biyosorplama kapasitesinin olduğunu ve bu atığın düşük maliyetli çevreci bir alternatif olarak kullanılabileceğini ortaya koymuştur.

Keywords

Yeşil nohut kabuğu, Biyosorpsiyon, Kurşun, İzoterm, Kinetik

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