Perovskit Güneş Hücrelerinde Li-TFSI Katkılı TiO2 Elektron Transfer Tabakasının Optimizasyonu

Muhittin Ünal; Seçkin Akın; Murat Ebiç; Bekir Baynal

doi:10.35414/akufemubid.1403743

Araştırma Makalesi

Optimization of Li-TFSI Doped TiO2 Electron Transfer Layer in Perovskite Solar Cells

Yıl 2024, Cilt: 24 Sayı: 4, 921 - 930, 20.08.2024

Muhittin Ünal , Seçkin Akın , Murat Ebiç , Bekir Baynal

https://doi.org/10.35414/akufemubid.1403743

Öz

Optimized electron transfer layer (ETL) play a crucial role in achieving higher performance in perovskite solar cells (PSCs). The optoelectronic properties of ETL, such as band energy and trap density, significantly influence the performance of PSCs. However, the low electron mobility of commonly used titanium dioxide (TiO2) ETL in PSCs remains a challenge that needs improvement. In this study, lithium bis(trifluoromethanesulfonyl)imide (Li-TFSI) salt is added to TiO2-based ETL at different concentrations (x: 0, 5, 10, 15 mg/ml) by spin-coating technique. Photovoltaic and optoelectronic properties of Li-TFSI-modified PSCs were compared with bare PSCs using the FTO/c-TiO2/mp-TiO2:Li-TFSI/CsFAMAPbI2Br/spiro-OMeTAD/Ag cell architecture. The TiO2:Li-TFSI modification shows a significant enhancement in the morphological, structural, and optical properties of the PSCs. The Li-TFSI contribution significantly improved the electron transfer. While bare PSC achieves a power conversion efficiency (PCE) of 18,16%, the 10 mg/ml Li-TFSI-modified PSCs reached the highest PCE of 19,98%. This study signifies a promising step towards the development and commercialization of highly efficient PSCs by optimizing the optoelectronic properties of TiO2 ETL through Li-TFSI salt modification.

Anahtar Kelimeler

Perovskite solar cells, Electron transfer layer, TiO2, Doping; Li-TFSI

Kaynakça

Abd Mutalib, M.; Ahmad Ludin, N.; Su’ait, M.S.; Davies, M.; Sepeai, S.; Mat Teridi, M.A.; Mohamad Noh, M.F.; Ibrahim, M.A., 2022. Performance-enhancing sulfur-doped TiO2 photoanodes for perovskite solar cells. Applied Sciences, 12(1), 429. https://doi.org/10.3390/app12010429
Afzali, M., Mostafavi, A., & Shamspur, T., 2020. Performance enhancement of perovskite solar cells by rhenium doping in nano-TiO2 compact layer. Organic Electronics, 86, 105907. https://doi.org/10.1016/j.orgel.2020.105907
Akin, S., Arora, N., Zakeeruddin, S. M., Grätzel, M., Friend, R. H., & Dar, M. I., 2020. New strategies for defect passivation in high‐efficiency perovskite solar cells. Advanced Energy Materials, 10(13), 1903090. https://doi.org/10.1002/aenm.201903090
Akman, E., & Akin, S., 2021. Poly (N, N′‐bis‐4‐butylphenyl‐N, N′‐bisphenyl) benzidine‐based interfacial passivation strategy promoting efficiency and operational stability of perovskite solar cells in regular architecture. Advanced Materials, 33(2), 2006087. https://doi.org/10.1002/adma.202006087
Akman, E., Shalan, A. E., Sadegh, F., Akin, S., 2021. Moisture‐resistant FAPbI3 perovskite solar cell with 22.25% power conversion efficiency through pentafluorobenzyl phosphonic acid passivation. Chemistry Sustainability Energy Materials, 14(4), 1176-1183. https://doi.org/10.1002/cssc.202002707
Arshad, Z., Shakir, S., Khoja, A. H., Javed, A. H., Anwar, M., Rehman, A., Farrukh, S., 2022. Performance analysis of calcium-doped titania (TiO2) as an effective electron transport layer (ETL) for perovskite solar cells. Energies, 15(4), 1408. https://doi.org/10.3390/en15041408
Bu, T., Liu, X., Zhou, Y., Yi, J., Huang, X., Luo, L., Xiao, J., Ku, Z., Peng, Y., Huang, F., Zhong, J., 2017. A novel quadruple-cation absorber for universal hysteresis elimination for high efficiency and stable perovskite solar cells. Energy & Environmental Science, 10(12), 2509-2515. https://doi.org/10.1039/C7EE02634J
Bidaki, A. Z., Abdizadeh, H., Pourshaban, E., Shadabroo, M. S., & Golobostanfard, M. R., 2022. Comparing the planar and porous Nb-doped TiO2 photoanode of triple cation perovskite solar cells. Materials Science in Semiconductor Processing, 138, 106259. https://doi.org/10.1016/j.mssp.2021.106259
Caprioglio, P., Cruz, D. S., Caicedo-Dávila, S., Zu, F., Sutanto, A. A., Peña-Camargo, F., Neher, D., 2021. Bi-functional interfaces by poly (ionic liquid) treatment in efficient pin and nip perovskite solar cells. Energy & Environmental Science, 14(8), 4508-4522. https://doi.org/10.1039/D1EE00869B
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Perovskit Güneş Hücrelerinde Li-TFSI Katkılı TiO2 Elektron Transfer Tabakasının Optimizasyonu

Yıl 2024, Cilt: 24 Sayı: 4, 921 - 930, 20.08.2024

Muhittin Ünal , Seçkin Akın , Murat Ebiç , Bekir Baynal

https://doi.org/10.35414/akufemubid.1403743

Öz

Perovskit güneş hücrelerinin (PGH) performansını arttırmak için optimize edilmiş elektron transfer tabakaları (ETT) kritik bir rol oynamaktadır. ETT'nin optoelektronik özellikleri, bant enerjisi ve tuzak yoğunluğu, PGH'nin performansını belirleyici bir şekilde etkilemektedir. Ancak, genellikle PGH'lerinde kullanılan titanyum dioksit (TiO2) ETT'nin düşük elektron hareketliliği iyileştirilmesi gereken bir sorundur. Bu çalışmada, farklı konsantrasyonlarda (x: 0, 5, 10, 15 mg/ml) lityum bis(triflorometansülfonil)imid (Li-TFSI) tuzu döndürerek-kaplama tekniği ile TiO2 tabanlı ETT'ye katkılanmıştır. TiO2:Li-TFSI katkısının morfolojik, yapısal ve optik özellikler üzerindeki etkileri araştırılmıştır. FTO/c-TiO2/mp-TiO2:Li-TFSI/CsFAMAPbI2Br/spiro-OMeTAD/Ag hücre mimarisi kullanılarak elde edilen Li-TFSI katkılı PGH'nin fotovoltaik ve optoelektronik özellikleri katkısız hücreler ile karşılaştırılmıştır. Li-TFSI katkısı, hücrelerdeki elektron transferini önemli ölçüde iyileştirmiştir. Saf PGH'de %18,16'lık bir güç dönüşüm verimliliği (GDV) elde edilirken, 10 mg/ml Li-TFSI katkılı PGH'de %19,98'lik en yüksek GDV değeri elde edilmiştir. Bu çalışma, Li-TFSI katkısıyla TiO2 ETT'nin optoelektronik özelliklerinin optimize edildiği ve yüksek verimli PGH'lerin geliştirilmesi için umut vadeden bir çalışma olarak değerlendirilmektedir.

Anahtar Kelimeler

Perovskit, güneş hücreleri, Elektron transfer tabakası, TiO2, Katkılama, Li-TFSI

Kaynakça

Abd Mutalib, M.; Ahmad Ludin, N.; Su’ait, M.S.; Davies, M.; Sepeai, S.; Mat Teridi, M.A.; Mohamad Noh, M.F.; Ibrahim, M.A., 2022. Performance-enhancing sulfur-doped TiO2 photoanodes for perovskite solar cells. Applied Sciences, 12(1), 429. https://doi.org/10.3390/app12010429
Afzali, M., Mostafavi, A., & Shamspur, T., 2020. Performance enhancement of perovskite solar cells by rhenium doping in nano-TiO2 compact layer. Organic Electronics, 86, 105907. https://doi.org/10.1016/j.orgel.2020.105907
Akin, S., Arora, N., Zakeeruddin, S. M., Grätzel, M., Friend, R. H., & Dar, M. I., 2020. New strategies for defect passivation in high‐efficiency perovskite solar cells. Advanced Energy Materials, 10(13), 1903090. https://doi.org/10.1002/aenm.201903090
Akman, E., & Akin, S., 2021. Poly (N, N′‐bis‐4‐butylphenyl‐N, N′‐bisphenyl) benzidine‐based interfacial passivation strategy promoting efficiency and operational stability of perovskite solar cells in regular architecture. Advanced Materials, 33(2), 2006087. https://doi.org/10.1002/adma.202006087
Akman, E., Shalan, A. E., Sadegh, F., Akin, S., 2021. Moisture‐resistant FAPbI3 perovskite solar cell with 22.25% power conversion efficiency through pentafluorobenzyl phosphonic acid passivation. Chemistry Sustainability Energy Materials, 14(4), 1176-1183. https://doi.org/10.1002/cssc.202002707
Arshad, Z., Shakir, S., Khoja, A. H., Javed, A. H., Anwar, M., Rehman, A., Farrukh, S., 2022. Performance analysis of calcium-doped titania (TiO2) as an effective electron transport layer (ETL) for perovskite solar cells. Energies, 15(4), 1408. https://doi.org/10.3390/en15041408
Bu, T., Liu, X., Zhou, Y., Yi, J., Huang, X., Luo, L., Xiao, J., Ku, Z., Peng, Y., Huang, F., Zhong, J., 2017. A novel quadruple-cation absorber for universal hysteresis elimination for high efficiency and stable perovskite solar cells. Energy & Environmental Science, 10(12), 2509-2515. https://doi.org/10.1039/C7EE02634J
Bidaki, A. Z., Abdizadeh, H., Pourshaban, E., Shadabroo, M. S., & Golobostanfard, M. R., 2022. Comparing the planar and porous Nb-doped TiO2 photoanode of triple cation perovskite solar cells. Materials Science in Semiconductor Processing, 138, 106259. https://doi.org/10.1016/j.mssp.2021.106259
Caprioglio, P., Cruz, D. S., Caicedo-Dávila, S., Zu, F., Sutanto, A. A., Peña-Camargo, F., Neher, D., 2021. Bi-functional interfaces by poly (ionic liquid) treatment in efficient pin and nip perovskite solar cells. Energy & Environmental Science, 14(8), 4508-4522. https://doi.org/10.1039/D1EE00869B
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Toplam 61 adet kaynakça vardır.

Ayrıntılar

Birincil Dil	Türkçe
Konular	Malzeme Mühendisliği (Diğer)
Bölüm	Makaleler
Yazarlar	Muhittin Ünal 0000-0003-2431-6870 Seçkin Akın 0000-0001-9852-7246 Murat Ebiç 0000-0002-1280-4052 Bekir Baynal 0009-0000-2563-696X
Erken Görünüm Tarihi	23 Temmuz 2024
Yayımlanma Tarihi	20 Ağustos 2024
Gönderilme Tarihi	18 Aralık 2023
Kabul Tarihi	22 Haziran 2024
Yayımlandığı Sayı	Yıl 2024 Cilt: 24 Sayı: 4

Kaynak Göster

APA	Ünal, M., Akın, S., Ebiç, M., Baynal, B. (2024). Perovskit Güneş Hücrelerinde Li-TFSI Katkılı TiO2 Elektron Transfer Tabakasının Optimizasyonu. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, 24(4), 921-930. https://doi.org/10.35414/akufemubid.1403743
AMA	Ünal M, Akın S, Ebiç M, Baynal B. Perovskit Güneş Hücrelerinde Li-TFSI Katkılı TiO2 Elektron Transfer Tabakasının Optimizasyonu. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. Ağustos 2024;24(4):921-930. doi:10.35414/akufemubid.1403743
Chicago	Ünal, Muhittin, Seçkin Akın, Murat Ebiç, ve Bekir Baynal. “Perovskit Güneş Hücrelerinde Li-TFSI Katkılı TiO2 Elektron Transfer Tabakasının Optimizasyonu”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 24, sy. 4 (Ağustos 2024): 921-30. https://doi.org/10.35414/akufemubid.1403743.
EndNote	Ünal M, Akın S, Ebiç M, Baynal B (01 Ağustos 2024) Perovskit Güneş Hücrelerinde Li-TFSI Katkılı TiO2 Elektron Transfer Tabakasının Optimizasyonu. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 24 4 921–930.
IEEE	M. Ünal, S. Akın, M. Ebiç, ve B. Baynal, “Perovskit Güneş Hücrelerinde Li-TFSI Katkılı TiO2 Elektron Transfer Tabakasının Optimizasyonu”, Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, c. 24, sy. 4, ss. 921–930, 2024, doi: 10.35414/akufemubid.1403743.
ISNAD	Ünal, Muhittin vd. “Perovskit Güneş Hücrelerinde Li-TFSI Katkılı TiO2 Elektron Transfer Tabakasının Optimizasyonu”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi 24/4 (Ağustos 2024), 921-930. https://doi.org/10.35414/akufemubid.1403743.
JAMA	Ünal M, Akın S, Ebiç M, Baynal B. Perovskit Güneş Hücrelerinde Li-TFSI Katkılı TiO2 Elektron Transfer Tabakasının Optimizasyonu. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. 2024;24:921–930.
MLA	Ünal, Muhittin vd. “Perovskit Güneş Hücrelerinde Li-TFSI Katkılı TiO2 Elektron Transfer Tabakasının Optimizasyonu”. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi, c. 24, sy. 4, 2024, ss. 921-30, doi:10.35414/akufemubid.1403743.
Vancouver	Ünal M, Akın S, Ebiç M, Baynal B. Perovskit Güneş Hücrelerinde Li-TFSI Katkılı TiO2 Elektron Transfer Tabakasının Optimizasyonu. Afyon Kocatepe Üniversitesi Fen Ve Mühendislik Bilimleri Dergisi. 2024;24(4):921-30.

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