Potasyum Borhidrit Hidroliz Reaksiyonu İçin Ni-B-P Katalizörünün Kinetik Özellikleri
Yıl 2020,
Cilt: 9 Sayı: 2, 599 - 608, 15.06.2020
Mehmet Salih Keskin
,
Mehmet Salih Ağırtaş
,
Orhan Baytar
,
Mehmet Sait İzgi
,
Ömer Şahin
Öz
For
the production of hydrogen in the hydrolysis of potassium boron hydride of this
product, a high performance Ni-B-P catalyst was synthesized. Catalysts in the
unknown state of the chemical industry FTIR, EDS, XRD and SEM analyzes of the
catalysts were used to determine the characteristics of the catalysts. Also for
potassium boron hydrolysis of Ni2P catalyst; The best Ni / P ratio, optimum KOH
concentration, KBH4 concentration, catalyst capacity and kinetic parameters
were investigated at different temperatures. The hydrogen production rate of
the catalyst was determined to be 665 mL / min * g and the best Ni / P ratio
was 0.184. In addition, the reaction rate range n was determined to be 0.2
degrees, so the activation energy value in the arhenius equation was 58,528 kJ
/ mol.
Destekleyen Kurum
Yüzüncü Yıl Üniversitesi
Proje Numarası
FDK-2017-6256
Teşekkür
Bu çalışma Van YYÜ Bilimsel Araştırma Projeleri Başkanlığı tarafından FDK-2017-6256 projesi kapsamında desteklenmiştir.
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