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Etkili Aktif Karbon Destekli CdS Fotokatalizörlerin Fotokatalitik Uygulamaları

Yıl 2020, Cilt: 9 Sayı: 2, 662 - 670, 15.06.2020
https://doi.org/10.17798/bitlisfen.642608

Öz

Farklı
aktif karbon konsantrasyonları ( %5, %10 ve %20) kullanılarak aktif karbon
destekli CdS fotokatalizörler hidrotermal tekniği kullanılarak sentezlenmiştir.
Sentezlenen %5, %10 ve %20 aktif karbon destekli CdS fotokatalizörler sırasıyla
CdS_1, CdS_2 ve CdS_3 şeklinde isimlendirilmiştir. Fotokatalitik deneylerin
birinci aşamasında metilen mavisinin fotokatalitik bozundurulmasında en iyi
fotokatalitik aktiviteye sahip olan fotokatalizör belirlendi. Daha sonra bu
fotokatalizör varlığında, katalizör miktarı ve boya konsantrasyonu gibi farklı
parametrelerin metilen mavisinin fotokatalitik bozundurulmasını nasıl
etkilediği incelenmiştir. Çalışmanın son kısmından en iyi fotokatalitik
aktiviteye sahip olan fotokatalizörün yapısal, morfolojik ve elementsel
özellikleri sırasıyla x-ışını difraksiyonu (XRD), taramalı elektron mikroskobu
(SEM) ve enerji dağıtıcı x-ışını (EDX) cihazları ile karakterize edilmiştir.

Destekleyen Kurum

Siirt Üniversitesi

Proje Numarası

2019-SİÜFEB-005

Teşekkür

Bu çalışma Siirt Üniversitesi Bilimsel Araştırma Projeleri Başkanlığı tarafından 2019-SİÜFEB-005 projesi kapsamında desteklenmiştir.

Kaynakça

  • [1] Baytar, O., et al., Synthesis, structural, optical and photocatalytic properties of Fe-alloyed CdZnS nanoparticles. 2018. Journal of Materials Science: Materials in Electronics, 29(6): 4564-4568.
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  • [3] Horoz, S., et al., 2018. Photocatalytic degradation of methylene blue with Co alloyed CdZnS nanoparticles. Journal of Materials Science: Materials in Electronics, 29(2): 1004-1010.
  • [4] Das, S. and H. Mahalingam, 2019. Dye degradation studies using immobilized pristine and waste polystyrene-TiO2/rGO/g-C3N4 nanocomposite photocatalytic film in a novel airlift reactor under solar light. Journal of Environmental Chemical Engineering, 7(5): p. 103289.
  • [5] Hussein, A.A., M. Alzuhairi, and N.H. Aljanabi, 1968. Degradation and depolymerization of plastic waste by local bacterial isolates and bubble column reactor. AIP Conference Proceedings, 2018. (1): p. 030081.
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  • [9] Abbasi, S. and M. Hasanpour, 2017. The effect of pH on the photocatalytic degradation of methyl orange using decorated ZnO nanoparticles with SnO2 nanoparticles. Journal of Materials Science: Materials in Electronics, 28(2): 1307-1314.
  • [10] Horoz, S. and O. Sahin, 2017. Synthesis, characterizations and photovoltaic properties of Cr-doped CdS QDs. Journal of Materials Science: Materials in Electronics, 28(23):17784-17790.
  • [11] Park, H., W. Choi, and M.R. Hoffmann, 2008. Effects of the preparation method of the ternary CdS/TiO2/Pt hybrid photocatalysts on visible light-induced hydrogen production. Journal of Materials Chemistry, 18(20):2379-2385.
  • [12] Jia, X., et al., 2016. Direct Z-scheme composite of CdS and oxygen-defected CdWO4: An efficient visible-light-driven photocatalyst for hydrogen evolution. Applied Catalysis B: Environmental, 198:154-161.
  • [13] Neelgund, G.M. and A. Oki, 2011. Photocatalytic activity of CdS and Ag(2)S quantum dots deposited on poly(amidoamine) functionalized carbon nanotubes. Applied catalysis. B, Environmental, 110: 99-107.
  • [14] Li, Q., et al., 2011. Highly Efficient Visible-Light-Driven Photocatalytic Hydrogen Production of CdS-Cluster-Decorated Graphene Nanosheets. Journal of the American Chemical Society, 133(28): 10878-10884.
  • [15] Cai, Q., et al., 2017. Fullerene (C60)/CdS nanocomposite with enhanced photocatalytic activity and stability. Applied Surface Science, 403:151-158.[16] Wang, Q., et al. 2017. Preparation of carbon spheres supported CdS photocatalyst for enhancement its photocatalytic H2 evolution. Catalysis Today, 281: 662-668.
  • [17] Liu, S.X., X.Y. Chen, and X. Chen, 2007. A TiO2/AC composite photocatalyst with high activity and easy separation prepared by a hydrothermal method. Journal of Hazardous Materials, 143(1): 257-263.
  • [18] Wang, X., et al., 2009. Degradation of methyl orange by composite photocatalysts nano-TiO2 immobilized on activated carbons of different porosities. Journal of Hazardous Materials, 169(1): 1061-1067.
  • [19] Laohhasurayotin, K. and S. Pookboonmee, 2013. Multifunctional properties of Ag/TiO2/bamboo charcoal composites: Preparation and examination through several characterization methods. Applied Surface Science, 282: 236-244.
  • [20] Huang, H.-B., et al., 2017. Photodegradation of Rhodamine B over Biomass-Derived Activated Carbon Supported CdS Nanomaterials under Visible Irradiation. Frontiers in Chemistry, 5(123).
  • [21] Guo, J., et al., 2016. CdS loaded on coal based activated carbon nanofibers with enhanced photocatalytic property. Chemical Physics Letters, 659: 66-69.
  • [22] Hu, Y., et al., 2010. Coating Colloidal Carbon Spheres with CdS Nanoparticles: Microwave-Assisted Synthesis and Enhanced Photocatalytic Activity. Langmuir, 26(23): 18570-18575.
  • [23] Balushi, B., et al., 2018. Hydrothermal synthesis of CdS sub-microspheres for photocatalytic degradation of pharmaceuticals. Applied Surface Science, 457.
  • [24] Tian, Z., et al., 2017. Hydrothermal synthesis of graphene/TiO2/CdS nanocomposites as efficient visible-light-driven photocatalysts. Materials Letters, 194: 172-175.
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Toplam 24 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Konular Mühendislik
Bölüm Araştırma Makalesi
Yazarlar

Mehmet Sait Izgi 0000-0003-3685-3219

Cihan Zörer Bu kişi benim 0000-0002-7620-6529

Orhan Baytar 0000-0002-2915-202X

Ömer Şahin 0000-0003-4575-3762

Sabit Horoz 0000-0002-3238-8789

Proje Numarası 2019-SİÜFEB-005
Yayımlanma Tarihi 15 Haziran 2020
Gönderilme Tarihi 20 Kasım 2019
Kabul Tarihi 8 Nisan 2020
Yayımlandığı Sayı Yıl 2020 Cilt: 9 Sayı: 2

Kaynak Göster

IEEE M. S. Izgi, C. Zörer, O. Baytar, Ö. Şahin, ve S. Horoz, “Etkili Aktif Karbon Destekli CdS Fotokatalizörlerin Fotokatalitik Uygulamaları”, Bitlis Eren Üniversitesi Fen Bilimleri Dergisi, c. 9, sy. 2, ss. 662–670, 2020, doi: 10.17798/bitlisfen.642608.



Bitlis Eren Üniversitesi
Fen Bilimleri Dergisi Editörlüğü

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